2
votes
1answer
37 views

Why does the raising and lowering operator not affect total angular momentum?

My notes define: $$ L_{\pm} = L_{x} \pm i L_{y} $$ and states: $$ [L_{z},L_{\pm}] = \pm \hbar L_{\pm} $$ I'm fine with this as it's easy to show the result with some ugly algebra. It then says: ...
3
votes
1answer
131 views

Directional derivatives in the multivariable Taylor expansion of the translation operator

Let $T_\epsilon=e^{i \mathbf{\epsilon} P/ \hbar}$ an operator. Show that $T_\epsilon\Psi(\mathbf r)=\Psi(\mathbf r + \mathbf \epsilon)$. Where $P=-i\hbar \nabla$. Here's what I've gotten: ...
1
vote
1answer
88 views

Creation and Annihilation Operators

Let $\widehat{a}^{+}_{i}$ and $\widehat{a}_{i}$ be the usual bosonic creation and annihilation operators. Consider $$\widehat{q}_{i} = \sqrt{\frac{\hbar}{2m_{i}w_{i}}}(\widehat{a}_{i}+ ...
4
votes
0answers
43 views

How can I write a Gaussian state as a squeezed, displaced thermal state

I would like to write a Gaussian state with density matrix $\rho$ (single mode) as a squeezed, displaced thermal state: \begin{gather} \rho = \hat{S}(\zeta) \hat{D}(\alpha) \rho_{\bar{n}} ...
2
votes
1answer
64 views

Approach to expressing $|n\rangle\langle n| $ as a polynomial when eigenvalues are degenerate?

If ${|n\rangle}$ are eigenvectors of an operator $A$ then $|n\rangle\langle n| $ can be expressed in terms of a finite order polynomial $$|n\rangle\langle n| =\prod_{m\ne n} \frac{A-a_m}{a_n-a_m}$$ ...
1
vote
1answer
66 views

Different mathematical methods in quantum mechanics?

My understanding is that in quantum mechanics the wavefunction may be expressed as a function or as a ket vector (composed of many orthogonal ket vectors). I'm not too sure about the further ...
0
votes
1answer
43 views

Sums of operators in practice

Consider a one dimensional harmonic oscillator. We have: $$\hat{n} = \hat{a}^{\dagger} \hat{a} = \frac{m \omega}{2 \hbar} \hat{x}^2 + \frac{1}{2 \hbar m \omega} \hat{p}^2 - \frac{1}{2}$$ And: ...
2
votes
1answer
56 views

Motivating the ansatz for the infinitesimal translation operator

I'm reading Sakurai's Modern QM right now and in the first chapter he states a number of conditions required for a translation operator: unitarity, ...
4
votes
3answers
410 views

Intuitive meaning of the exponential form of an unitary operator in Quantum Mechanics

I'm an undergraduate student in Chemistry currently studying quantum mechanics and I have a problem with unitary transformations. Here in my book, it is stated that Every unitary operator ...
2
votes
1answer
65 views

Does the momentum operator commute with the Pauli matrix?

I tried to calculate the effect of spin orbit coupling $H_s=\alpha(\sigma_xp_y-\sigma_yp_x)$ as in the Rashba effect. But I just found out that it is not hermitian. Some paper propose some way by ...
2
votes
1answer
45 views

How does Dirac show that $\langle B|\bar{\bar{\alpha}}|P\rangle\;=\; \overline{\langle P|{\bar{\alpha}}|B\rangle}\;=\; \langle B|{\alpha}|P\rangle$?

Dirac shows that the conjugate imaginary of $\langle \!P|\alpha$ is $\bar{\alpha} |P\!\rangle$ and then starts with the identity on page 27 in his book: $$\langle B|\bar{{\alpha}}|P\rangle\;=\; ...
3
votes
5answers
341 views

Commutator algebra in exponents

Considering $X$ and $Y$ such that $[X,Y]=\lambda$, which is complex, and $\mu$ is another complex number, prove: $$e^{\mu(X+Y)}=e^{\mu X} e^{\mu Y} e^{-\mu^2\lambda/2}$$ My attempt (so far) is: ...
2
votes
1answer
55 views

Measurement of observables with continuous spectrum: State of the system afterwards

Suppose my system, described by a separable Hilbert space $H$, is in the state $\Psi$ when I measure an observable that has only continuous spectrum. What is the state of the system after the ...
3
votes
0answers
105 views

Convention in physics for [],{} and operators (QM)

I got a little mixed up with the convention in physics. Usually a hat means an operator. For a given electron-ion Hamiltonian $\hat{H}_{e-n}$, what are the difference between these: 1) ...
2
votes
1answer
70 views

Making an Incomplete Set of Observables Complete

In quantum mechanics, it seems a standard procedure that if you have an incomplete set of observables, then one can make this set complete by adding more commuting observables until the set becomes ...
1
vote
1answer
40 views

Prove the solution of von Neumann equation will never stabilize if Hamiltonian and initial density matrix commutes

Given von Neumann equation $$\frac{d}{dt} \rho(t) = -i [H, \rho(t)] = -i e^{-iHt}[H, \rho(0)]e^{iHt}.$$ If we know that $[H, \rho(0)] \neq 0$, how do we prove in details the solution of von Neumann ...
2
votes
3answers
92 views

Measuring position and momentum at the same time?

In a non-relativistic quantum mechanical system in an infinite potential well. I try to measure the energy and the position of the system simultaneously. Since, the respective operators do commute ...
0
votes
0answers
52 views

What does QM observable operator actually DO?

I know, that each observable is represented by some linear operator, while it's eigenvalues represent probability amplitudes of possible observable values. But what if I ACT with this operator on ...
0
votes
1answer
25 views

How to write “postselection” operator?

Suppose, I wish to know an operator, which eigenvalue is 1 if state is exactly F and 0 ...
1
vote
1answer
59 views

How to write QM operator if I know all of it's eigenfunctions?

Suppose I have selected enough orthogonal functions in representation of operator A and I want to derive operator B which has ...
2
votes
0answers
68 views

Symmetry and Algebra

I'm trying to get a more concrete idea how symmetry is understood in quantum theories, as broad as possible. Consider a infinitesimal transformation of states in quantum physics of the form: $$ ...
2
votes
2answers
79 views

Eigenstates of a shifted harmonic oscillator

Let's say I have a quantum harmonic oscillator $H = \omega a^\dagger a$, where $a^\dagger$ is the raising operator and $a$ is the lowering operator and $H |n\rangle = \omega n |n\rangle$. Now assume ...
6
votes
5answers
461 views

Differences between probability density and expectation value of position

The expression $\int | \Psi\left(x\right)|^2dx$ gives the probability of finding a particle at a given position. If wave function gives the probabilities of positions, why do we calculate ...
0
votes
2answers
61 views

Differentiation operator with respect to observable acting as a function of the observable?

In his Principles of Quantum Mechanics Dirac writes: $$\int \langle \phi \frac{d}{dq}|q'\rangle dq' \psi(q')=\int \phi(q') dq' \frac{d\psi(q')}{dq'}.$$ To me it is rather strange, and it seems as if ...
2
votes
2answers
70 views

Can we correctly define momentum operator only by means of position operator and their commutation relation?

In "J.M. Ziman. Electrons and Phonons: The Theory of Transport Phenomena in Solids" the author formally introduces the position (displacement) operator and then defines the momentum operator with the ...
0
votes
1answer
48 views

Observables in Quantum Mechanics

Studying on own quantum mechanics I came across: Preceeding text: A basic postulate of quantum mechanics tells us how to set up the operator corresponding to a given observable. Observables, ...
1
vote
1answer
68 views

How to get the time derivative of an expectation value in quantum mechanics?

The textbook computes the time derivative of an expectation value as follows: $$\frac{d}{dt}\langle Q\rangle=\frac{d}{dt}\langle \Psi|\hat Q\Psi\rangle=\langle \frac{\partial\Psi}{\partial t}|\hat ...
3
votes
5answers
229 views

About the definition of expectation value in quantum mechanics

In quantum mechanics, the expectation value of a observable $A$ is defined as $$\int\Psi^*\hat A\Psi$$ But in probability theory the expectation is a property of a random variable, with respect to a ...
0
votes
1answer
76 views

Are operators in quantum mechanics linear transformations?

Observables in quantum mechanics correspond to self-adjoint linear operators. If $\psi$ is an eigenvector of $\hat A$, then $\hat A\psi=\alpha\psi$ where $\alpha$ is the eigenvalue of $\psi$. ...
1
vote
1answer
73 views

The Eigenstate Existence Problem in Dirac's 'Principles of Quantum Mechanics'

In Chapter II of Dirac's Principles of Quantum Mechanics, Dirac explains that in general it is very difficult to know whether, for a given real linear operator, that any eigenvalues/eigenvectors exist ...
3
votes
2answers
125 views

What is the analogy of $|x\rangle$ in quantum field theory?

Let me start from path integral formulation in quantum mechanics and quantum field theory. In QM, we have $$ U(x_b,x_a;T) = \langle x_b | U(T) |x_a \rangle= \int \mathcal{D}q e^{iS} \tag{1} $$ ...
2
votes
1answer
64 views

What are the proper domains of the position and squared angular momentum operator?

I am looking at the position operator on a compact set $K \subset \mathbb{R}^n$ and the squared angular momentum operator (so essentially the Laplace-Beltrami operator where I just look at the angular ...
3
votes
4answers
459 views

Is the potential in Schrödinger equation an operator?

In the Schrödinger equation in the position representation $$ i\hbar\frac{\partial}{\partial t}\Psi(x,t) ~=~[\frac{-\hbar^2}{2m}\nabla^2+V(x,t)]\Psi(x,t), $$ is the potential $V(x,t)$ an operator ...
6
votes
3answers
315 views

Basis in quantum mechanics

My quantum mechanics textbook (Primer of Quantum Mechanics, by Marvin Chester) says that both the momentum space and the position space are basis spaces. It also says that the momentum space is ...
0
votes
2answers
63 views

Eigenstates of an observable

Can we use eigenstates of ANY observable as base of the Hilbert space? If we can, is this equal to the statement that those eigenstates are orthogonal to each other and normalizable?
1
vote
1answer
33 views

Why does the probability of obtaining a value of a measurement follow from Dirac's general assumption?

In Dirac's The Principle of Quantum Mechanics he makes the general assumption that "if the measurement of the observable $\xi$ for the system in the state corresponding to $|x\rangle$ is made a large ...
3
votes
2answers
175 views

Position Representation in Quantum Mechanics

How does the 3d position operator look like in position representation? I know that in 1d the position operator $\hat{x}$ is just multiplication by $x$.
3
votes
2answers
67 views

Quantum Mechanics: Time dependence of an expectation value

In Griffiths's Introduction to Quantum Mechanics, he says that the time dependence of an expectation value is $$\frac{d\langle Q\rangle}{dt}=\frac{i}{\hbar}\langle [H,Q]\rangle+\langle \frac{\partial ...
3
votes
1answer
199 views

Explanation of Dirac's proof of arbitrary ket being expressible with eigenkets of observable

In P.A.M. Dirac's The Principles of Quantum Mechanics, Chapter 10 (Observables), pp. 40, at the end of the chapter there is a proof that I don't understand at all. Here is a pdf link to the book ...
1
vote
0answers
33 views

How can I take the Wigner transform of an operator with an absolute value?

I want to be able to find the Wigner transforms of operators of the form $\Theta(\hat{O})$, where $\Theta$ is the Heaviside function and $\hat{O}$ in general depends on both $x$ and $p$. For the ...
7
votes
0answers
109 views

Role of physics in the zeta function $\zeta$ and the Riemann hypothesis

Hilbert and Polya suggested a physical way to verify the Riemann hypotesis about $\zeta(x)$. If the Riemann hypotesis is true, we can state all eigenvalues of physical problems are real. What is the ...
7
votes
4answers
248 views

Does Heisenberg equation of motion imply the Schrodinger equation for evolution operator?

Let us choose to postulate (e.g. considering the analogy of the Hamiltonian being a generator of time evolution in classical mechanics) $$ i\hbar \frac{d\hat{U}}{dt}=\hat{H}\hat{U}\tag{1} $$ where ...
1
vote
2answers
78 views

Idempotent Operators

If $P$ is an idempotent operator, $P^2 = P$ and we have a vector $|\psi\rangle$, $P\neq1$, and the relation $$PL |\psi\rangle = L|\psi\rangle,$$ what conclusions can we draw about $L$, which is a ...
1
vote
2answers
54 views

What is the energy operator and from where do we get it?

I am trying to learn Quantum mechanics from MIT OCW Videos about quantum mechanics. I have reached the 5th lecture. Please help me in understanding this: In the middle (At 32:08), the professor wrote ...
1
vote
1answer
82 views

I am trying to calculate how $<r>$ in the hydrogen atom evolves with time

I am working on the Hydrogen atom and I was trying to calculate $\frac{d<r>}{dt}$ using $$\frac{d<r>}{dt} = \frac{i}{\hbar} <[\hat{H} , \hat{r}]>.$$ Here $r = \sqrt(x^2 + y^2 + z^2)$ ...
9
votes
2answers
202 views

Deriving the expectation of $[\hat X,\hat H]$

For a free particle of mass $m$, with Hamiltonian $$\hat{H} = \frac {\hat{P}^2} {2m},$$ where $$\hat{P} = -i \hbar \frac{\partial} {\partial x}.$$ The commutative relation is given by $$[\hat{X}, ...
0
votes
1answer
91 views

Matrix elements of the operator $\hat{x} \hat{p}$ in position and momentum basis

I want to calculate the matrix elements of the operator $\hat{x} \hat{p}$ in momentum and position basis, that is the two quantities ($p,q$ - momenta, $x,y$ - positions): $$\langle p|\hat{x} ...
1
vote
2answers
63 views

Angular momentum for 3D harmonic oscillator in two different bases

I know that the energy eigenstates of the 3D quantum harmonic oscillator can be characterized by three quantum numbers: $$ | n_1,n_2,n_3\rangle$$ or, if solved in the spherical coordinate system: ...
14
votes
4answers
532 views

Density matrix formalism

The density matrix $\hat{\rho}$ is often introduced in textbooks as a mathematical convenience that allows us to describe quantum systems in which there is some level of missing information. ...
11
votes
4answers
378 views

Applying an operator to a function vs. a (ket) vector

I have a question regarding the effect of quantum mechanical operators. The definition that I'm familiar with says that an operator $A$ acts on a vector from a Hilbert space, $|\psi\rangle$, and the ...