Quantum mechanics describes the microscopic properties of nature in a regime where classical mechanics no longer applies. It explains phenomena such as the wave-particle duality, quantization of energy and the uncertainty principle and is generally used in single body systems. Use the ...

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62 views

Quantum Mechanics in Electric Field

I am working on a problem which looks like this. Consider a charged particle with charge $q$ trapped in a box of length $L$ with finite constant potential $ V_0 $ on both ends. A constant (static) ...
2
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1answer
121 views

Can two electrons have the same momentum and spin directions?

I am trying to understand the Pauli exclusion principle. Here is an except from Feynman Lectures on Physics It just isn’t possible at all for two Fermi particles—such as two electrons—to get into ...
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2answers
74 views

Interpreting some domain issues of (potential) momentum operators

In the context of mathematical quantum mechanics, a well known no-go theorem known as Hellinger-Töplitz tells us that an unbounded, symmetric operator cannot be defined everywhere on the Hilbert space ...
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26 views

Simple questions on the symmetric eigenstate and time-reversal (TR) breaking eigenstate?

Followings are two independent questions as implied by the title: (1) Considering a quantum Hamiltonian $H$ possesses some symmetries described by a symmetry group $G=\left \{ g_1,g_2,...,g_n \right ...
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19 views

What is the physical interpretation of time-energy uncertainty? [duplicate]

I have a question. What is the physical interpretation of time-energy uncertainty?
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1answer
41 views

Proof of inability to obtain global phase

I'm curious if there's a quick proof of the inability to obtain global phase from a quantum state, since they're supposedly indistinguisable. I suppose to measure this, you would need a Hermitian ...
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43 views

Problem with commutator [on hold]

My area is mathematics; however, told me about a problem that can solve with simple math, it says: Using $[\hat{J_{z}},\hat{O}]$, show that $\langle\alpha,j,m|\hat{O}|\beta,j',m'\rangle$ can be ...
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0answers
27 views

How does independence of the basic bras affect the choice of numbers used to represent a ket?

On page 54 of Dirac's book, The Principles of Quantum Mechanics, he states: Take an orthogonal representation with basic bras $\langle\lambda_1\lambda_2...\lambda_u|$, labelled by parameters ...
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1answer
46 views

Quantum mechanics: Finite square well problem

What will happen if the potential is less than 0, for instance $V(x)=-10eV$. Is this means there will be no bound states? Since solution to the time independent Schrodinger equation (those discrete ...
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1answer
92 views

What is the physical meaning of anti-commutator in quantum mechanics?

I gained a lot of physical intuition about commutators by reading this topic. What is the physical meaning of commutators in quantum mechanics? I have similar questions about the anti-commutators. ...
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1answer
66 views

Interaction pictures of Quantum Mechanics

I want to understand the Schrödinger, Heisenberg and interaction picture and have a few questions about them: So in general you have a time-dependent Hamiltonian $H$, as for example the potential may ...
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0answers
22 views

Atom in a box and collapse of the wave-function

Suppose I have an atom trapped in an optically transparent box. I'm assuming the atom is bouncing off of the walls and not bonding, i.e. the center of mass of the atom experiences a square well. Now ...
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4answers
254 views

Having trouble understanding some stuff about delta functions [on hold]

I was going through one of the examples in Griffith's Quantum book and there was a few things in Example 3.3 that I didn't understand that I was hoping to get some clarification on. For instance, we ...
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0answers
39 views

SUSY QM - working out energy spectrum and wavefunctions from a given superpotential

I'm currently self-studying F. Cooper and al.'s Supersymmetry in Quantum Mechanics, and I need help working out a particular case on shape-invariance. From a given superpotential of the form ...
2
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0answers
60 views

What is discrete phase space?

I've been reading a little about the usual, continuous Wigner functions and phase space quasi-distributions in general, and I believe I understand the idea behind them. The Wigner function arises when ...
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0answers
26 views

Charge Conjugation Operator in Supermultiplet

Consider an $\mathcal{N}=1$ left-handed chiral supermultiplet. The particle content is $$L = (\phi\quad e_L) $$ where $\phi$ is a complex scalar and $e_L$ a left handed Weyl fermion. People usually ...
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1answer
53 views

Second Qubit Not Flipped in Hadamard Gate

I'm very new to QM and Quantum Computing and I have a likely simple question, It may simply stem from my lack of knowledge of vector calculus. We have a 2-qubit quantum state: $$ \mid\psi\rangle = ...
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18 views

Leptons slide between quarks? [on hold]

I wonder if one of particles (maybe quarks?) are constructors of highways in 3d field for others floating around re/distributing energy by some (leptons?), restricted to laws set by (bosons?). If ...
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1answer
39 views

Two Particle System with Identical Particles

I'm studying for an exam in quantum mechanics and tried to calculate the ground state and the first two excited states of two identical bosons (spin 0) in an infinite one dimensional potential well. ...
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3answers
89 views

Variational Theorem proof

I have been trying to prove variational theorem in quantum mechanics for a couple of days but I can't understand the logic behind certain steps. Here is what I have so far: \begin{equation} ...
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0answers
16 views

How to calculate the $g$ degeneracy factor for alkali metals and their singly ionized species?

The Saha ionization equation is $$\frac{n(X_{i+1})}{n(X_{i})} = \frac{(2\pi m k T)^{1.5}}{n_e h^3}\frac{2g_{i+1}}{g_{i}}e^{-\chi/kT}$$ where $\chi$ is the energy difference between the two ...
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2answers
780 views

These two operators commute…but their eigenvectors aren't all the same. Why?

The Hamiltonian $$H = \left[ \begin{array}{cccc} a & 0 & 0 & -b \\ 0 & 0 & -b & 0\\ 0 & -b & 0 & 0\\ -b & 0 & 0 & -a \end{array} \right] $$ commutes ...
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1answer
14 views

J-coupling constants and nuclei with zero total angular momentum

The Wikipedia page on J-couplings states that Scalar or J-couplings (also called indirect dipole dipole coupling) are mediated through chemical bonds connecting two spins. It is an indirect ...
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0answers
21 views

Discrepancy in introducing Schottky barrier

I have a problem regarding introduction of Schottky barrier in metal-semiconductor junction. Because of this barrier the energies of conduction band vary discontinuously and hence the potential is ...
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0answers
34 views

Quantum Mechanics: Eigenstates for Quantum operators [on hold]

1. The problem statement, all variables and given/known data Suppose that a state |Ψ> is an eigenstate of operator B, with eigenvalue bi. 2. Relevant equations i. What is the expectation value of ...
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2answers
64 views

Minimum information necessary to represent a pure quantum state

I was thinking about how quantum states are represented for various types of systems, and how the amount of classical information (bits) required to represent a state depends on its basis. Let's take ...
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0answers
33 views

Is it sensible to speak of the parity operator in 4 dimensional Hilbert space?

So I'm dealing with a system of two qubits, with the hamiltonian given by $$H = \left[ \begin{array}{cccc} a & 0 & -b & 0 \\ 0 & 0 & 0 & -b\\ -b & 0 & 0 & 0\\ 0 ...
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1answer
70 views

Inconsistency in the delta potential

I encountered an inconsistency in the one-dimensional delta potential. Suppose we have a one-dimensional infinitely deep square well from $-L$ to $+L$. We know the eigenstates are sine and cosine ...
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1answer
38 views

Few particle fermion system wavefuction

Suppose I have 3 fermions($\left|\psi_1\right\rangle$, $\left|\psi_2\right\rangle$, $\left|\psi_3\right\rangle$) and a system with 3 states ( $\left|1\right\rangle$, $\left|2\right\rangle$, ...
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0answers
24 views

Dynamics of modifing a Hamiltonian

I am working on quantum mechanics right now, and I am wondering if there is a qualitative way to think about off diagonal term of a Hamiltonian matrix? I know that we can diagonalize a matrix, then ...
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0answers
21 views

Local unitary transformation that maximizes overlap

Could anyone point me in the right direction (reference to papers would suffice) regarding the following: Given two quantum states $|\psi\rangle ,|\phi\rangle \in (\mathbb{C}^d)^{\otimes n}$, where ...
2
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2answers
36 views

How can we tell if a molecule is in thermodynamic equilibrium from scattering data?

We have a molecule that is emitting/absorbing photons. We know the Hamiltonian and that there are several levels. We count the emitted photons at different angles and frequencies. We can also do ...
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1answer
78 views

Why do we believe in a “force” driven universe? [closed]

Why do we not believe in the potential for a "unified force field" universe, to the exclusion of the belief in the potential for a mechanical, gear driven universe, if the correct shape for the gear ...
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41 views

Is Ballentine's description of the Berry phase (in his book _Quantum Mechanics_) flawed?

Ok, so I'm looking at Ballentine's Quantum Mechanics right now, 7th reprint (2010). On page 363, he starts with 12.7 Adiabatic Approximation and quickly moves on to explain Berry's phase on page 365. ...
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41 views

Quantum decoherence and Schrodinger's equation

In non-relativistic quantum mechanics, the equation of evolution of the quantum state is given by Schrodinger's equation and measurement of a state of particle is itself a physical process. Thus, ...
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2answers
37 views

Number of Orbitals - Hydrogen Orbital just one, but why can we plot also higher states e.g. SPDF orbits?

I am confused, hydrogen just has one electron in the 1s orbit. but why can we plot all kind of orbitals (higher energy eigenstates for that atom)? My assumption: So physically spoken these orbits ...
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29 views

Wannier Hamiltonian in Momentum Space

In connection to a previous question, We can write the one-particle Hamiltonian in the Wannier basis working on a general vector $v$ as : $$ \langle\vec{R},\,\lambda|\hat{H}|v\rangle = ...
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1answer
29 views

Correlation between Bohr-model and quantum physics

If you're looking at the probability of finding the electron of a hydrogen atom at a distance $r$ from the nucleus, it turns out that the Bohr model for the radius of the orbit only correlates with ...
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69 views

A new interpretation of QM [closed]

Do you think that this new interpretation of quantum mechanics has solved the measurement problem completely as it claims? http://article.sapub.org/10.5923.j.ijtmp.20140405.04.html
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4answers
2k views

How can one derive Schrödinger equation?

The Schrödinger equation is the basis to understanding quantum mechanics, but how can one derive it? I asked my instructor but he told me that it came from the experience of Schrödinger and his ...
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0answers
27 views

Interpretation of angular momentum in semi-classical vector model

My Professor said that when we calculate the total angular momentum of multiparticles, in this case i.e. 2 particles, we can add total angular momentum by thinking this way, if both spins allign they ...
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1answer
52 views

Finding the spectrum of a curious hamiltonian

I wish to analyse the following hamiltonian, i.e. find its eigenvalues and eigenstates. $$H = \frac{1}{2}\epsilon(\sigma _z \otimes \mathbb{1} + 1\otimes \sigma _z) - \Delta (\sigma _x \otimes \sigma ...
3
votes
2answers
211 views

1D Infinite Square Box Discrete Energy levels but Continous Momenta?

In the 1d particle in the box the energy of the particle should be completely determined by the momentum of the particle that you observe correct? So how can you have discrete energy levels and a ...
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1answer
29 views

Example of a state which is positive but its partial transpose is not positive

Could any one give me an example of a state whose density matrix is positive semidefinnite but partial transpose is not positive semidefinnite?
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0answers
95 views

Momentum operator in Dirac formalism

Could you derive the momentum operator as follows: Since $\mathcal{T}(\Delta x)=\exp(-ip_{x} \Delta x/ \hslash)$, if we set $\Delta x=x-0$ then it follows that $\left \langle x\right | ...
3
votes
1answer
69 views

Where does the partial derivative come from in Sakurai's derivation of the momentum operator?

How is the momentum operator derived in Dirac formalism? I am reading Quantum Mechanics by Sakurai and he gives the following derivation. But I don't understand how he goes from the third equation to ...
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45 views

Wannier Functions as Discrete Basis

In solid state physics, using Bloch's theorem we know that the one-electron energy eigen-function can be written as $\psi_{\lambda,\vec{k}}(\vec{r})$ where $\lambda$ indexes eigenvalues of $\hat{H}$ ...
2
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2answers
111 views

Why do electrons orbit protons? [duplicate]

I was wondering why electrons orbited protons rather than protons orbiting electrons. My first thought was that it was due to the small amount of gravitational attraction between them that would ...
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0answers
41 views

Bell's inequality

For a project, I'm planning to study Bell's inequality, which as far as I can gather is taken to rule out hidden variable theories of QM. I'm looking for recommendations of decent sources which derive ...
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1answer
48 views

Diffraction to be explained without Huygens principle

Can we explain diffraction without using Huygens principle?