Study of macroscopic and microscopic phenomena in chemical systems in terms of physical laws and concepts [thermodynamics, statistical mechanics, kinetic theory, quantum mechanics...].

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1answer
119 views

Apparent color of flame as superposition of spectral lines?

In some cases one can identify a substance by the color emitted as it burns in a flame. A green flame might indicate the presence of copper. So here is the question. If we know wavelength and ...
2
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2answers
105 views

How do you know which atoms are in a specific piece of matter?

If you have a piece of matter in front of you, how can you know of which atoms it consists? And starting from nothing, how can I discover all the elements (or just a lot of them) of the periodic table?...
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1answer
106 views

Change of heat capacity fluid when you add solvent

I am considering a liquid for which I know $C_p$ or $C_v$. I am wondering how this changes when you add a (minor) amount of solvent to the liquid. Is there a general theory around describing how a ...
2
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1answer
618 views

How specifically do emulsifiers work?

I'd like to understand better how emulsifiers prevent droplet coalescence. There must be something more they do than just lower the surface tension between the droplet and the ambient substance. I ...
2
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1answer
212 views

Is it possible to mechanically isomerize an sp3 hybridized carbon center?

Imagine I have an sp3 hybridized carbon attached to four separate polyethylene chains. By pulling on the polyethylene chains in some manner, is it possible for me to mechanically isomerize the chiral ...
2
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3answers
3k views

Air Regeneration in Closed Systems [closed]

I wonder what's the way to regenerate O2 in air without using consumable chemicals (where one can use electricity through electrolisis or using UV lamps)? We can dissolve water into O2 & H2, but ...
2
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2answers
106 views

Boyle's Law-$ PV= nRT.$ What equation should be used to find pressure if n is not constant, like in an elastic system?

When air is added to an elastic system, like a balloon, the volume and pressure change. Would use Boyle's Law- $PV=nRT,$ but n does not remain constant in this situation. Known: $V_1$ is at ...
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1answer
37 views

“Carbon capture into fuel” - where does the energy come from?

I recently found an article titled "Scientists find a way to convert Carbon Dioxide from air into fuel" (here), and my immediate reaction was "surely not - the energy balance would kill you right away"...
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1answer
49 views

Why do randomly flying gas molecules have a distribution of energies?

Why do randomly flying gas molecules have a distribution of energies? This is a question from my chemistry textbook (not homework, just questions to help us think about and understand the concepts). ...
2
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1answer
93 views

Why does sunlight cause colors to fade?

If you leave something outside, its colors seem to inevitably fade or bleach due to exposure. Is this due to UV absorption? What sort of mechanism causes this - is it that man-made dyes deform on a ...
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3answers
1k views

Melting and Boiling Points of Odd Materials

In Chemistry, I was taught that there are three main states of matter: solid, liquid, and gas, and that heat and pressure determine that state. For some substances, the line is blurry between them. ...
2
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1answer
80 views

Would other intelligent life in the Universe be likely to construct the same periodic table of the elements? [closed]

Is the structure of the periodic table fundamental enough that other forms of intelligent life would likely structure their own listing of the elements in the same way (i.e. are there other ways of ...
2
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1answer
168 views

Why is a wine glass shaped the way it is? [closed]

Why is a wine glass shaped the way it is? And why are there different shapes for different wines? Is this a tradition, or is there any scientific reason behind it?
2
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1answer
263 views

What happens to gas molecules after ionization?

I know that gas molecules conduct electricity after they get ionized but what will happen if we keep increasing the voltage even after ionization? Will it explode? If it will then how much energy ...
2
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3answers
504 views

What force creates ions out of neutral atoms?

Consider the reaction between Na and Cl to form NaCl. Na loses an electron and "gives" it to Cl because this makes both atoms more stable. But what forces "pulls" the electron from Na to Cl? Both ...
2
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1answer
607 views

Absorption of a gas into a solid

When a gas interacts with a (crystalline) solid, some scenarios may happen: scattering: gas atoms will not stick or penetrate (do not interact with the solid) Adsorption: gas atoms stick to the ...
2
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2answers
386 views

Temperature of thermochemical reaction between propane and nitrous oxide

I'm trying to calculate the properties of the combustion process using propane and nitrous oxide. When I tried to nail down the combustion temperature, the result looks just off to me. I went through ...
2
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1answer
93 views

Why does bringing N 1-orbital atoms together yield N levels?

A common example of this is that when bringing N hydrogen atoms together into a ring. Far apart, assume each electron exists in the 1s state. As we bring them together, instead of each electron ...
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1answer
125 views

What are the state functions telling me or how are they related to total energy?

I am quite new to thermodynamics and statistical mechanics so this might be an easy question: In thermodynamics you get a bunch of thermodynamics potentials, so as for example enthalpy, internal ...
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1answer
620 views

Reason behind cohesive and adhesive force

What is the real cause behind the cohesive and adhesive forces?
2
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2answers
151 views

Driving a solution of optical isomer molecules with the resonant frequency

What happens when we drive a solution of optical isomer molecules (enantiomers) with a microwave radiation in resonance with the tunneling frequency of the molecules (the frequency of the transition ...
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5answers
13k views

Why does burning magnesium explode when sprinkled with water?

Magnesium powder burns extremely well and reaches temperatures of 2500°C. However, attempts to extinguish such a magnesium fire with conventional water (e.g. from a garden hose) only make it worse: ...
2
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1answer
14k views

List of immiscible liquids

I'm looking for a list of immiscible (and miscible) liquids. I currently developing a game that will use the property of differents liquid, some of them will mix, other will not (positioning in the ...
2
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1answer
299 views

Vapor pressure higher than equilibrium vapor pressure

Is there any mechanism by which the vapor pressure of a liquid substance (lets say in a vacuum) is measured to be greater than the expected saturated vapor pressure at that temperature? Specifically, ...
2
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1answer
414 views

Equations describing the liquifaction of gases

I would like to find out how much energy is required to liquify gases (oxygen or nitrogen, for example). What are some relevant equations? I'm curious whether creating small quantities of dry ice or ...
2
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0answers
67 views

How to calculate the minimum kinetic energy required by a surface molecule to escape the liquid (during evaporation)?

Evaporation occurs when surface molecules have enough Kinetic Energy to escape the surface of the liquid. Given a certain volume of liquid at a certain temperature, is it possible to determine this ...
2
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1answer
76 views

Electronic spectroscopy question in a more physics oriented view. What is the operator that describes relaxation pathways?

Recently I was studying spectroscopy in Symmetry and Spectroscopy: An Introduction to Vibrational and Electronic Spectroscopy p.357-358 as shown in the image http://i.stack.imgur.com/LSLyZ.jpg The ...
2
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1answer
72 views

Do antiparticles exhibit different chemical properties?

In my physics class today. My teacher mentioned anti-helium and since I had never heard of anti-atoms (if you get what I mean by that) just antiparticles, this made me think: If we could produce anti-...
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0answers
47 views

The underlying chemical interactions behind torque

I did some searching around, and didn't find any previous topics that address torque in this specific way -- here goes: Say I just have a plain ol' piece of wood -- relatively long in one axis, so it ...
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0answers
92 views

Why is the activation energy of combustion so large compared with regular bonding?

I wanted to know why combustion requires an activation energy and I found this article (see this too). It says that molecular oxygen ground state is a triplet state (according to Hund's rules), and ...
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0answers
66 views

Why is the water diamagnetic?

I checked using my permanent magnet that water is diamagnetic. But why is it like that? Does this have any important consequence for life?
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0answers
197 views

Confusing Chemical potential of mixtures

I feel that there are very few textbook that treat the chemical potential of mixtures in an understandable clear way, which is why I wanted to ask here about certain things? Although I do not have a ...
2
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0answers
52 views

Approach to model solvent in a lattice: e.g. H2O in NaCl

If a lattice contains a solvent, lets say NaCl and water of crystallisation, what is the condition for a solvent molecule to change it's location? From my current point of view I assume that such a ...
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0answers
48 views

Electrochemical cell potential - Prigogine book

I'm trying to understand equation 10.2.14 from Prigogine book "Moder thermodynamics": $V=\frac{\tilde{A}}{nF}=\frac{1}{nF}\left(\mu_X^R+\mu_Y^L-\mu_{Xred}^R-\mu_{Yox}^L\right) - \left( \phi^R-\phi^L \...
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0answers
172 views

High Young's Modulus and Tensile Strength of Carbon Nanotubes

I was recently reading about Carbon Nanotubes having extremely high Young's moduli, as well as high Tensile Strength, making them very interesting fibers. However, when I read this I wondered what was ...
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0answers
65 views

generation / destruction of fermions by phonons

my Hamiltonian consists of 1D free fermions coupled to a bosonic bath. The interaction is dictated both by scattering terms $H^{scatt}=\sum_{kq}\alpha^S_{kq}c^\dagger_kc_{k+q}X_q+h.c.$ as well as ...
2
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0answers
95 views

Are metal modes mixed with molecular modes during surface enhanced Raman effect?

This question is dedicated to Martin Fleischmann (1927-2012). When a molecule is adsorbed on a metal surface, the Raman scattering amplitude from the molecule is enhanced. According to Wikipedia, the ...
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0answers
185 views

Dissipation when the temperature is not constant

Consider a process where some chemical species diffuses from one part of a system (which I'll call $A$) to another ($B$) at a rate $r$ $\text{mol}\cdot \mathrm s^{-1}$. If the system's temperature is ...
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3answers
271 views

Solving the simplest coupled nonlinear ODES for chemical kinetics [closed]

I am just trying to get the integrated form for the kinetics of the reaction $A + B \rightarrow C + D$ characterized by: $$ -\dfrac{d[A]}{dt} = -\dfrac{d[B]}{dt} = k[A][B] \; . $$ As you note, ...
1
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2answers
164 views

Is it possible to mix a luminescent drink? [closed]

Is it possible to create a drink that glows? In other words, is it possible to create a non-poisonous drink that fluoresces? Are there known compounds suitable for that? If not, then what about a ...
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2answers
2k views

Why Does Air Hold More Water When the Air is Warmer?

I know that when the temperature of the air rises, the maximum amount of Water it can hold before the water condenses to water droplets increases. But why is this - has it got something to do with ...
1
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5answers
573 views

What laws (formulas) govern forces between atoms?

What laws (formulas) govern the fundamental forces of nature? For example, gravity is governed by the inverse-square law. I am thinking about how particles attract each other, but also repel. All ...
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4answers
147 views

The impatient hot tub owner [closed]

An impatient man owns a 300 gallon hot tub. He comes home from a hard day of work and sees that his hot tub is currently simmering at 90F. For maximum relaxation, he wants it at 104F. However, the hot ...
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2answers
291 views

What's up in this SPAWAR video?

Here is a video presentation of infrared recordings of anomalous heating in a deuterium palladium cell: ( youtube video) (see also this presentation if you want more detail, and have time). There are ...
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3answers
411 views

Can endergonic reactions occur outside of living organisms?

If the Gibbs free energy equation is defined as: ∆G = ∆H - T∆S And the amount of energy/work released from a reaction is: ...
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2answers
2k views

How do I integrate the Poisson equation to determine the electric potential along a particular direction (e.g., $z$)?

This question is a sequel of sorts to my earlier (resolved) question about a recent paper. In the paper, the authors performed molecular dynamics (MD) simulations of parallel-plate supercapacitors, ...
1
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1answer
178 views

Gas permeation through solid metal?

if i make a box from aluminum ( 0,5 mm thickness ) and put air in it ( about 2 bar or 3 bar). would the box lose the air over time (10 years period) or not ? assuming the temperature will change ...
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2answers
105 views

How do we represent 'smell' and 'taste' as signals?

I was wondering if we could represent 'smell' and 'taste' as signals like we do for audio. How do we mathematically represent them? Is there any research papers related to it? Can someone give me ...
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4answers
185 views

Solids: is energy expended in some fashion by, say, a table to keep the top from sinking down against gravity?

A friend and I were discussing this, and couldn't decide. Since it takes energy to physically raise something up above the planet's surface, does it continue to require energy in order to keep it ...
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1answer
2k views

Will the “Vacuum Wine Saver” suck the bubbles out of Champagne?

The "Vacuum Wine Saver" comes with the following "warning": Not for sparkling wines Intuitively and naively, I imagine that the bubbles (or the "bubble-potential"—my made-up terminology) will be ...