Study of macroscopic and microscopic phenomena in chemical systems in terms of physical laws and concepts [thermodynamics, statistical mechanics, kinetic theory, quantum mechanics...].

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Calculate the required water for humidity [closed]

I'm not sure if this is the right place to ask. I have a humidifier, and a closed room. Basically, I want to know the required water to reach a certain level of humidity. My room volume is 42 meter ...
7
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3answers
473 views

What is the quantum mechanical explanation of the octet rule?

What is the quantum mechanical explanation of the octet rule? In other words, what makes the octet rule be true from a quantum mechanical view? How we explain what makes some atoms don't follow the ...
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0answers
73 views

Calculating molal depression constant from latent heat of fusion

Calculate molal depression constant of water if latent heat of fusion of ice at $0^\circ \text C$ is $80 \text{ cal/g}$. All I could find was the equation $K_f=\frac{0.002T^2}{L_f(\text{in ...
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1answer
97 views

Why does Relativity effect the melting point of mercury?

I know there is a related question, that references the Dirac Equation, that relies on relativity, but I've just watched this video: http://www.youtube.com/watch?v=NtnsHtYYKf0 Which seems to say ...
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2answers
99 views

Can a liquid shrink as something is dissolved into it?

Not much more to add. By shrink, I mean become more dense at the same pressure and temperature. And I don't mean vol(A+B) < vol(A) + vol(B). I'm sure this is possible. Is it possible to ...
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54 views

reactions in molecular dynamics simulations

EDIT: Apparently this is called reactive molecular dynamics. It seems that the ReaxFF potential function is used for some reactions like this. I am interested in adding support for reactions to a ...
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3answers
96 views

Should a polyatomic crystal behave similarly to the bulk of each/either of its constituent elements?

Generally, metals are usually fairly conductive, but their oxides aren't. I know conductivity is just one attribute, but in general, should you expect a, say, diatomic bulk crystal's properties to be ...
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2answers
237 views

First principle calculation of boiling point of water

How can we theoretically calculate the boiling point of water at given pressure (other subtle parameters as well, if any)? What is the most accurate (minimum discrepancy with experimental value) ...
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0answers
90 views

Leakage rate Calculation

I have to calculate leak rate for helium/air from an enclosure which is made of fabric. This is similar to helium balloons. There are small holes in the fabric. How should i proceed ?
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1answer
102 views

What are the state functions telling me or how are they related to total energy?

I am quite new to thermodynamics and statistical mechanics so this might be an easy question: In thermodynamics you get a bunch of thermodynamics potentials, so as for example enthalpy, internal ...
3
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1answer
273 views

What is a chemical potential good for?

I read that the definition of the chemical potential is, that it is the partial derivative of the Free energy with respect to the number of particles, $$\mu=\frac{\partial F}{\partial N}.$$ ...
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62 views

What is the physical property of metal nanoparticles?

I am a Math student but now I have to deal with gold nanoparticles in aqueous solution. Now I was wondering whether the physical properties of gold nanoparticles are the same as the properties of gold ...
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1answer
51 views

Slicing a surface concentration from a volumetric number concentration

Assume I have a given volumetric concentration $c$ of $N=10000$ particles in a qubic box of volume V: $$c = \frac{N}{V}$$ The units of $c$ are $$[c] = \frac{[\#]}{[m^3]}$$ Now if I introduce an ...
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2answers
529 views

Where does the Pauli Repulsive Force come from that counteracts the attraction between atoms and ions? [duplicate]

I'm learning about such things as ionic and covalent bonds, and the reason given for the ionic bonds is electrostatic attraction. However, if that were true, then the two ions would accelerate toward ...
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2answers
68 views

Aggregating daily readings with units of parts per million

I have a series of daily readings (NOx emissions) measured in parts per million. I need to aggregate the daily readings into a monthly measure. Clearly a sum operation will be incorrect (parts per ...
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2answers
110 views

In which direction does the electron move during an electronic transition?

Let's imagine a molecule and put it in a 3D space. Let's also imagine an electronic transition for this molecule. I know how an electronic transition works, how to value if it is possible (using the ...
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4answers
219 views

Dissolving oxygen into water

I was wondering how one would actually calculate how much oxygen would dissolve into water given the necessary initial conditions, and what those initial conditions would need to be. I assume they ...
2
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2answers
2k views

How to estimate the physical size of a molecule?

I'm reading some chemistry-related papers that employ concepts of droplet evaporation. Since I am no chemist, I am wondering: How can I estimate the actual size of a molecule, say succinic acid? An ...
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2answers
251 views

Vaporizing ethanol from liquid

What is going on here http://youtu.be/LQFmKPA-iAg Is ethanol leaving the liquid? If so, why? Does the pressure add energy to the ethanol molecules causing them to gasify and move rapidly near border ...
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0answers
23 views

Solution of multiple materials

Introduction I'm trying to make some strawberry liqueur. The recipe I got says I should put alcohol, strawberries and sugar in a bowl and leave it soaking for 4-5 weeks. I read that making liqueur is ...
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2answers
2k views

what is the density of natural gas at 293K and 700 kPa? [closed]

I am trying to calculate the density of natural gas to define the amount of natural gas flow through an orifice. I am coming up with 5.45 kg/m3 Is this correct?
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2answers
53 views

A question on lewis model [closed]

Electron affinity of chlorine = -349 kJ per mole. And, first ionization energy of sodium = 496 kJ per mole while energy required for combining= 147 kJ per mole. Isn't it a contradiction against ...
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1answer
184 views

What is tricritical point?

Critical point is the transition temperature of a second order phase transition. But what does tricritical point mean? WIki says that a tricritical point is a point in the phase diagram of a system at ...
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1answer
118 views

How fair is it to say that all chemistry arises from failures of the ideal gas law?

I was reading here about how the ideal gas law assumes point masses and non-interaction. Is it fair to say that all chemistry arises from failures of that? Of course, such a sweeping generalization ...
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2answers
272 views

How much Bicarbonate of Soda and Vinegar would I need to reach space?

So here is my problem - as part of my job I present some science demonstrations to children and one of the tricks I regularly use is the bicarb/acetic acid rocket. I thought the other day that a ...
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1answer
97 views

How fast will I get if I burn a comet? [closed]

Assuming I have a spacecraft which is $30,000\,\mathrm{kg}$ (roughly the size of the Apollo spacecraft). If I take a comet and (theoretically) electrolize it perfectly to hydrogen and oxygen. I know ...
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2answers
266 views

Solidification by the application of heat

When you add heat to a liquid (or a fluid), can it be solidified? If not, why in the world does an egg's stuffs become solid (or at least no more a liquid) when you 'boil' it in water?
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2answers
78 views

What is “species” in the context of an electrochemical cell?

From the Wikipedia entry on Electrochemical cell (http://en.wikipedia.org/wiki/Electrochemical_cell): An electrochemical cell consists of two half-cells. Each half-cell consists of an electrode, ...
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1answer
214 views

Difference between Non-Polar and Dipole moment $\vec\mu$=0

Is there any difference between a molecule having $\vec\mu=0$ and being Non-Polar?
2
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1answer
194 views

Reason behind cohesive and adhesive force

What is the real cause behind the cohesive and adhesive forces?
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2answers
231 views

Carbon in the form of graphite a conductor?

Well, it happens a I have a glucose test strip (One Touch Ultra) which has three electrodes (Counter, Working and Reference) and I'm guessing this electrodes are made from graphite mixed with a ...
3
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1answer
147 views

What's the underlying particle physics of endothermic reactions?

I don't just mean reactions that require heat to proceed, storing surplus energy in chemical bonds. I wonder about strongly endothermic reactions that suck heat out of environment. You take some ...
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1answer
264 views

Chemical Equilibrium - Why do changes in pressure cause a shift in the ratio of products and reactants?

I understand Le Chatelier's principle and how every change to an equilibrium system causes an opposing reaction from the system. I also understand how, when pressure is increased, the equilibrium ...
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1answer
245 views

What's the vapor pressure and evaporation enthalpy of a saline solution?

Suppose you dissolve an amount of salt in water. Because of the attraction between the ions and the water molecules, you'd expect lower vapor pressure and higher enthalpie, both depending on the ...
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2answers
11k views

Why does a salt solution conduct electrical current?

How does e.g. sodium chloride (aq) conduct electricity? By accepting electrons (unlikely since they already have a full outer shell)? But they can't be hopping around themselves, can they? I mean, if ...
4
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3answers
249 views

Do electrons in multi-electron atoms really have definite angular momenta?

Since the mutual repulsion term between electrons orbiting the same nucleus does not commute with either electron's angular momentum operator (but only with their sum), I'd assume that the electrons ...
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3answers
249 views

Can endergonic reactions occur outside of living organisms?

If the Gibbs free energy equation is defined as: ∆G = ∆H - T∆S And the amount of energy/work released from a reaction is: ...
4
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3answers
4k views

is it possible to flow current in open circuit?

First , i don't know much about chemistry and physics. I'm just a graphic designer but i have this question in my mind. I'm sorry if this question is too basic and use 'generic' language. As i know ...
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0answers
29 views

Half-Life Question [duplicate]

Possible Duplicate: How do we know that some radioactive materials have a half life of millions or even billions of years? I understand how to calculate decay, but it seems to me that the ...
6
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7answers
2k views

Is there any reproducible tested evidence for Ni-H cold fusion?

The main replications of cold fusion, the ones that are beyond reproach, used Pd/d as the system. But commercial developers have often claim to use Ni-H to achieve similar effects. The claims include ...
2
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0answers
77 views

Are metal modes mixed with molecular modes during surface enhanced Raman effect?

This question is dedicated to Martin Fleischmann (1927-2012). When a molecule is adsorbed on a metal surface, the Raman scattering amplitude from the molecule is enhanced. According to Wikipedia, the ...
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2answers
234 views

Where does Computer Science background students fit in Theoretical Physics [closed]

I am basically an Electronics student - background in computer science (that's where I want to work). I applied for an internship in USA in a research institute where the group is focused in ...
3
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2answers
2k views

Widom-Larsen Theory

Does the Widom-Larsen theory pose a credible underpinning for Low Energy Nuclear Reactions, often incorrectly referred to as "Cold Fusion"? http://arxiv.org/abs/cond-mat/0505026
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2answers
2k views

How does one calculate the volume of a nucleus and the volume of an atom (in this case hydrogen)?

The hydrogen atom contains 1 proton and 1 electron. The radius of the proton is approximately 1.0 fm (femtometers), and the radius of the hydrogen atom is approximately 53 pm (picometers).
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1answer
52 views

Action on Lard Oil

If water is mixed with lard oil and heated (creating some super-critical liquid with water), how does this affect the volatility of the mixture in comparison with its purity..? So, My question is: ...
12
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3answers
316 views

Chemical reaction as state transition?

When considering diffusion of chemicals, the reaction part is business of chemical kinetics, where the relevant characteristics of different substances come from collision theory together with some ...
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1answer
302 views

What's the common consensus on the meaning of “physical change”?

I'm doing a textbook problem that shows a "molecular level" view of some matter, little colored balls, before and after, and there are, among the four questions, two that say: 1) Did a physical change ...
14
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3answers
20k views

Why do grapes in a microwave oven produce plasma?

Some of you may know this experience (Grape + Microwave oven = Plasma video link): take a grape that you almost split in two parts, letting just a tiny piece of skin making a link between each ...
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1answer
188 views

Electrical Resistance and chemistry

Can some one describe or explain what happens when too much current is passed through lets say a copper wire, I am looking for an explanation to do with physics and chemistry. For instance we have ...