Study of macroscopic and microscopic phenomena in chemical systems in terms of physical laws and concepts [thermodynamics, statistical mechanics, kinetic theory, quantum mechanics...].

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Copper vs Tungsten (Diffusion)

I've been studying on how to compare the activation energy for (void-) diffusivity of Copper versus Tungsten. I ended up finding $E_a[cu] = 1.1[eV]$ and $E_a[W] = 5.2[eV]$ in literature where the ...
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21 views

how does voltage sensitive dye determine the membrane potential?

There are so many papers about VSDs and how to use them, but i can not find anything about what exactly is happening in the cell membrane that leads to the change in VSD's light intensity as a sign of ...
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47 views

Interparticular space

We say that the inter-particular space in solids is small,in liquid is intermediate and in gas it is huge.So,how small is that space.there must be parameters for the amount of space.Like when the ...
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49 views

salt water conductivity

my book says the following on conductivity in water with ions. I am confused about why electrons from the zinc (anode) repel positive ions. Because zinc becomes negative, shouldn't it attract it? ...
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36 views

Quantum Mechanism Dipole Moment Magnetic Field Problem [closed]

I figured 1a out pretty easily. For 1b I am a bit stuck. So far i have that in the field: $$ \Delta z = v_0t + (1/2) a_zt $$ $$ F_z = ma_z $$ so $$ a_z = F_z/m $$ We know $$ F_z=\mu_z(\partial(B_z)/\...
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Bimolecular and Isomerization reactions

Is it possible to describe a reaction of the $$ A+B \rightleftharpoons AB $$ exactly using the solution of an isomerization reaction? $$A \rightleftharpoons B$$ I just can not figure it out the ...
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48 views

Humidification Problem [closed]

Humidification Imagine that water is evaporating into initially dry air in the closed vessel shown schematically in Fig. 8.1-1(a). The vessel is isothermal at 25 C, so the water’s vapor ...
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442 views

Ranking bond types from strongest to weakest

Note: I've already handed this in for homework and got the question wrong but don't understand why. Not looking for someone to do my homework for me, just trying to flesh out an area where I'm not yet ...
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95 views

Why has a molecule less energy than the uncombined atoms?

My book says, A molecule as compared to the atoms from which it is formed is more stable because it possesses energy lower than the energy of the uncombined atoms. This difference in energy is due ...
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2answers
106 views

Boyle's Law-$ PV= nRT.$ What equation should be used to find pressure if n is not constant, like in an elastic system?

When air is added to an elastic system, like a balloon, the volume and pressure change. Would use Boyle's Law- $PV=nRT,$ but n does not remain constant in this situation. Known: $V_1$ is at ...
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54 views

Physics behind blowing soap bubbles

Is it possible, using the surface tension of a soap bubble, to calculate the maximum pressure (created by the air flow) it can withstand while still attached to the orifice to prevent it from bursting?...
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45 views

calculating with quantum numbers and shape of nodal shells

I'm attending in a chemistry course now, and in the beginning we scratch the surface of the quantum physics, which have led me to some problems. Mostly I understand all what we get until now, but ...
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84 views

How does electromagnetic radiations penetrate?

I am reading about the discovery of subatomic structure which includes all these things radioactivity, alpha rays, gamma rays, x rays et cetera. I read that electromagnetic radiations are energy ...
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34 views

What happens when a semipermeable membrane allows only one solute to pass through?

I'm essentially a medical student where we deal a lot with osmosis. But when we are taught, it is done generally with only a single solute in consideration. What if two different solutes are used on ...
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10 views

What would be a suitable textbook of first semester physical chemistry? [duplicate]

I am going to take PChem I in my biochem dept next sem, which is a watered down version of the PChem course in Chem dept. It basically covers thermodynamics and a little bit of quantum stuff. The ...
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1answer
38 views

What is the relation of particle velocity, temperature, and reaction activation energy

So, this curiosity has arisen for a fun project I thought I'd tackle, where I'm attempting create a crude simulation of an internal combustion cylinder. I wanted to explore the particle level ...
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70 views

Constant Temperature Cooling

In my thermodynamics textbook there is part of a question that seems to be a contradiction. ...Superheated refrigerant R-134a at 20 C, 0.5 MPa is cooled in a piston/cylinder arrangement at constant ...
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Gibbs isotherm and calculating interfacial tension change from first principles

Question: Is it possible for a solid particle to change the surface tension between two phases? (or: Does a solid particle have a chemical potential?) This question stems from the more fundamental:...
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4answers
147 views

The impatient hot tub owner [closed]

An impatient man owns a 300 gallon hot tub. He comes home from a hard day of work and sees that his hot tub is currently simmering at 90F. For maximum relaxation, he wants it at 104F. However, the hot ...
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1answer
37 views

“Carbon capture into fuel” - where does the energy come from?

I recently found an article titled "Scientists find a way to convert Carbon Dioxide from air into fuel" (here), and my immediate reaction was "surely not - the energy balance would kill you right away"...
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82 views

Calculate how many photons hitting a sample that are absorbed

In the determination of the quantum yield of a photoisomerization, $\Phi,$ the following is needed $$ \Phi = \frac{\mbox{Number of "reactions"}}{\mbox{Number of absorbed photons}} $$ The photon flux ...
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1answer
62 views

Atoms attraction [closed]

Do atoms attract to atoms of same element? And would atoms attract to another atom for forming ionic or covalent bond? I basically want to know what would an atom be attracted to? (Except for ...
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280 views

In a Monte Carlo NVT simulation How do I determine equilibration

I'm running an NVT (constant number of particles, volume and temperature) Monte Carlo simulation (Metropolis algorithm) of particles in two dimensions interacting via Lennard-Jonse potential ($U = 4(\...
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Do (or can) hydrogen bonds between water molecules neutralize their own polarity? [closed]

Do (or can) hydrogen bonds between water molecules neutralize their own polarity as indicated here: Hydrogen bonding as the mechanism that neutralizes $\mathrm{H_2 O}$ polarity https://groups.google....
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87 views

Do sodium chloride(ions) melt the ice or not?

My question is this, In European countries, they use NaCl or KCl to melt ice during the winter season. In Asian Countries, they use NaCl to keep the ice without melting. (Ex- Ice cream boxes, Beer ...
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1answer
49 views

Why do randomly flying gas molecules have a distribution of energies?

Why do randomly flying gas molecules have a distribution of energies? This is a question from my chemistry textbook (not homework, just questions to help us think about and understand the concepts). ...
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1answer
40 views

How can we use conductivity measurements of water to find hydrogen ion concentration of water?

How can we use conductivity measurements of water to find the hydrogen ion ($\mathrm{H}^+$) concentration in water?
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48 views

Why dynamic equilibrium exists?

We know that at equilibrium Gibbs energy is minimum. We also know that at equilibrium both forward and reverse reactions occur simultaneously, and also we know that for a reaction to be spontaneous ...
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1answer
129 views

What causes an emulsion to be stable or unstable?

The other day I made a salad dressing based on oil and vinegar. To my understanding, there is a positive energy associated with the surface between the oil and vinegar. The most stable state is also ...
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1answer
76 views

Electronic spectroscopy question in a more physics oriented view. What is the operator that describes relaxation pathways?

Recently I was studying spectroscopy in Symmetry and Spectroscopy: An Introduction to Vibrational and Electronic Spectroscopy p.357-358 as shown in the image http://i.stack.imgur.com/LSLyZ.jpg The ...
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3answers
202 views

Why is alcohol less dense than water?

Ethyl alcohol (ethanol) is less dense than water, and it's boiling point is lower. But this molecule is more complex and bigger than the simple H2O. How can a substance with a higher molecular size ...
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2answers
129 views

Can $CO_2$ be separated into $C$ and $ O_2$?

I'm doing a little bit of research for an experiment that I want to conduct in science and it relies on that one question. So, Is it possible to separate a $CO_2$ molecule into a $C$ and $O_2$? ...
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232 views

Why are only Group III & V elements used for doping?

Only group III & IV are used for doping in elemental semiconductors like Si and Ge, why can't other groups be used instead?
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35 views

Notation in a neutron star superfluidity

In this article "Neutron Star and Superfluidity", by Ka Wai Lou: http://guava.physics.uiuc.edu/~nigel/courses/569/Essays_Fall2010/Files/lo.pdf symbols as $^1S_0$ and $^3 P_2$ are shown, but I not sure ...
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1answer
30 views

Why higher FAT level implies more signal in XPS analysis?

In XPS analysis, the FAT (Fixed Analyzer Transmission) parameter controls the electrostatic field of an emispheric analyzer, called Pass Energy $E_P$. The FWHM of a peak of signal is given by $$\...
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1answer
115 views

Spacetime curvature effect on chemistry

Do current chemistry / astrophysics / stellar chemistry calculations include the effects of the curvature of spacetime on chemical reactions? For example, the heat transfer from a point closer to the ...
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2answers
196 views

The NERVA had to use liquid H2… But why?

The NERVA engine, developed at the late 60ies, was a nuclear thermal rocket developed for vacuum use in space craft. It was supposed to use Liquid Hydrogen, a cryogenic fuel with quite a few issues ...
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1answer
34 views

Spin-$\frac{1}{2}$ particles in chemistry

Electrons and protons are spin-$\frac{1}{2}$ particles, so under a rotation by 360$^\circ$, their wavefunction changes by a sign. They are also commonly found alone in chemical reactions, especially ...
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Bonding Two Cationic Hydrogen Isotopes (protium) yields H2 or He?

If you have two hydrogen atoms. And they are the isotope form "Protium" (1 neutron removed) and they are also cationized +1 (1 electron removed) then you have (in a sense) a single proton (two of them ...
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36 views

What is the relation between Nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR)? [duplicate]

It seems to me that the basic principles are exactly the same, right? Then I am puzzled that the former was awarded a nobel prize while the later not. I noticed a similar question here What's the ...
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1answer
146 views

Parkhomov's E-cat reproduction [closed]

In the beginning of the year, Professor Alexander Parkhomov of Lomonosov Moscow State University claimed to have replicated (as read in e.g. Wired) of the E-cat functioning, albeit with lower effect. ...
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1answer
951 views

How does wax fuel a flame? [duplicate]

I get how an oil lamp runs until the fuel runs out, but a normal wax candle doesn't seem like it works the same way.
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3answers
131 views

Is there an way water can burn or cause fire?

Water known as the fire extinguisher.What is the possibility watere being the fuel to fire. "Pure water"
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1answer
28 views

Ionization Through Atomic Collisions - Any Reason(s) for Its being Unimportant?

The dominant processes which contribute to the ionisation of a gas (which is possibly hot and dense) are often deemed to be electron-impact ionization ($A + e^- \rightarrow A^+ + e^- + e^-$) and photo-...
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1answer
72 views

Why is blue darker than yellow in an analog black and white photograph?

Blue is perceived darker than yellow by the human eye, because of biological principles within the eye. I can understand that therefore, when making a picture black&white in software like Adobe ...
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1answer
48 views

electron shell jumping in Iron?

I understand a "little" about electron shell jumping, I was wondering about "Iron", If iron was heated to a gas, perhaps held in a vacuum maybe even under pressure, would the added energy make the ...
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3answers
338 views

Are chemical bonds matter?

So it recently blew my mind that chemical bonds have mass. And that a spring that's wound up similarly weights a little more. But there is a distinction between mass and matter. I believe that a ...
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1answer
92 views

Exothermic vs. endothermic reactions

An exothermic reaction is a chemical reaction that releases energy by light or heat. Does this mean that if I mix two chemicals in a test tube when the reaction between them is endothermic then the ...
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28 views

Charge Transport Mechanicsm of Organic Semiconductors

I understand the general concept behind inorganic semiconductors. Start with Silicon, dope the material to add an electron or a hole, and now these are free to move about in the material, creating ...
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2answers
213 views

Calculating the radius and potential energy of an atom?

Is there a general equation that gives the potential energy of any element at each energy level? I know that there is an equation for the potential energy of a hydrogen atom at each energy level but ...