Study of macroscopic and microscopic phenomena in chemical systems in terms of physical laws and concepts [thermodynamics, statistical mechanics, kinetic theory, quantum mechanics...].

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14 views

If I want to sample rate constants of chemical reactions, what the distribution will be appropriate? [closed]

For example, I have a (chemical) reaction systems, I want to sample the parameter space. What will be the best and validated distribution for sampling? And why? Thanks!
2
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2answers
117 views

Calculating the radius and potential energy of an atom?

Is there a general equation that gives the potential energy of any element at each energy level? I know that there is an equation for the potential energy of a hydrogen atom at each energy level but ...
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2answers
59 views

Does chemical energy contribute to mass? [duplicate]

Does chemical energy contribute to the mass of an object? I don't mean the bond energy, but the possible energy that could be released (i.e. Does an atom of oxygen and a molecule of hydrogen (H2) have ...
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2answers
133 views

Is it possible to mix a luminescent drink? [closed]

Is it possible to create a drink that glows? In other words, is it possible to create a non-poisonous drink that fluoresces? Are there known compounds suitable for that? If not, then what about a ...
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1answer
38 views

How much carbon dioxide do we actually ingest from a can of coke?

On this most trustworthy page it states that a 355 mL can of coke contains on average about 2.2 grams of carbon dioxide. As far as I know, this carbon dioxide can exist in solution as carbonic acid, ...
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2answers
54 views

Formation of bonds and heat release

We know when there's formation of bonds during chemical reaction there's heat release to the surrounding due to conservation of energy. But what I am confused about, is the kinetic energy of the ...
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0answers
32 views

What is the specific source(s) of sliding kinetic friction

In simplistic (K-8) physics classes, it seems to be generally instructed that the friction between two moving surfaces is due to the unevenness of each surface and the microscopic roughness. However, ...
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2answers
94 views

Gibbs free energy + maximum work

The Gibbs free energy is the maximum amount of non-expansion work that can be extracted from a closed system; this maximum can be attained only in a completely reversible process. This maximum work is ...
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0answers
27 views

Difference between “chemical master equation” and “master equation”

Is there any mathematical difference between "master equations" and "chemical master equations"? Is the chemical master equation in any way more specific than the master equation? I see the former ...
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2answers
53 views

Quenching of binary alloy: Concentration equilibrium

I'm currently reading "Models for phase separation and their mathematics" by Paul C. Fife and there is a paragraph which I don't understand because I lack the necessary background in ...
2
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1answer
67 views

Do antiparticles exhibit different chemical properties?

In my physics class today. My teacher mentioned anti-helium and since I had never heard of anti-atoms (if you get what I mean by that) just antiparticles, this made me think: If we could produce ...
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2answers
1k views

Vaporizing ethanol from liquid

What is going on here http://youtu.be/LQFmKPA-iAg Is ethanol leaving the liquid? If so, why? Does the pressure add energy to the ethanol molecules causing them to gasify and move rapidly near border ...
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4answers
36k views

Why does ice have a lower density than water?

Can someone explain me why is ice less dense than water? As I know, all solids are usually denser than the liquids (correct me if I am wrong).
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3answers
508 views

Jet turbine blades from single crystals, how are they formed?

I know about nothing about crystals, although I do know a bit more about jet turbine engines, and I definitely know that you don't want the fan blade hitting the fan housing. The reason given in the ...
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0answers
45 views

Difficulty in understanding Maxwell Boltzmann distribution in case on ions in a field

I learned that the velocity of molecules obey Maxwell Boltzmann (MB) distribution at a Temperature T. If I have ions of mass 'M' accelerated to 2eV in a specific region. As the ions are not ...
2
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0answers
43 views

The underlying chemical interactions behind torque

I did some searching around, and didn't find any previous topics that address torque in this specific way -- here goes: Say I just have a plain ol' piece of wood -- relatively long in one axis, so it ...
2
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0answers
72 views

Why is the activation energy of combustion so large compared with regular bonding?

I wanted to know why combustion requires an activation energy and I found this article (see this too). It says that molecular oxygen ground state is a triplet state (according to Hund's rules), and ...
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0answers
19 views

Why does carbon help with electron transfer in a dye sensitized solar cell?

what property of carbon(soot) makes it easier for electron transfer within a dye sensitized solar cell?
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0answers
41 views

Visible wavelengths of air fluorescence data - needed for school demo laser telephone design

I'm seeking information about fluorescence in visible wavelengths (390-700nm) of any of the main constituents of air ( $ N_2, O_2, CO_2, H_2O, CO, etc. $) that can be excited with a (hopefully ...
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3answers
836 views

Why does a pitcher with lemon juice have foam, while one with pure water does not?

Whenever I pour water into lemon juice (pouring directly from the tap into the pitcher, not quietly along its edge) I get a foam on top: The same pitcher with water (same water tap, pitcher, time ...
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1answer
111 views

Is water steam in air a case of liquid in gas solution?

Thinking of this question, I thought that the phenomenon of water evaporation into the air is totally analogous to the solid (say, salt) that is dissolved into a liquid (water). Indeed, in this ...
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0answers
82 views

How does fluid velocity affect the dissolution of some solute in the fluid?

Suppose we have a perfect sphere of some solute such as sugar and we place it in a fluid such as water, at a certain temperature, that is not moving. It will dissolve and diffuse into the water due to ...
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1answer
45 views

Why don't fire hoops blow out while spinning, but blow out when blown out?

My friend spins fire hoops and we're wondering why they don't blow out while she's spinning them, but do, when she blows them out one by one. I don't imagine there's so much more CO2 (so much less ...
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2answers
250 views

Extra vibrational mode in linear molecule

When calculating the number of vibrational modes for a molecule, the formulas differ for linear $(n = 3N - 5)$ and non-linear $(n = 3N - 6)$ molecules, where $n$ is number of modes and $N$ is number ...
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3answers
446 views

What force creates ions out of neutral atoms?

Consider the reaction between Na and Cl to form NaCl. Na loses an electron and "gives" it to Cl because this makes both atoms more stable. But what forces "pulls" the electron from Na to Cl? Both ...
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0answers
37 views

Heat Retention of Wine

This may seem odd and lengthy but I am going to attempt to consolidate my thoughts as much as possible. I'm sorry in advance for the length of my post and if this is confusing. I am currently ...
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0answers
46 views

What factors are influencing a woosh rocket?

Not sure if this is too much chemistry, but I'll try: If I fill a plastic bottle with a small amount of rubbing alcohol, shake it around and hold a match to the bottle neck, I'll get a flame wooshing ...
3
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1answer
102 views

Physical distribution of salt anions and cations during electrophoresis

If I have a volume of $L$ liters of salt water at a concentration of $\approx N$ mM NaCl and I pour it into an electrophoretic apparatus (like this one: ). Once we turn the apparatus on, and set the ...
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1answer
327 views

Electrical Resistance and chemistry

Can some one describe or explain what happens when too much current is passed through lets say a copper wire, I am looking for an explanation to do with physics and chemistry. For instance we have ...
0
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1answer
72 views

Energy of a system if the nuclear repulsion increases

I have calculated the optimised geometry for a molecule. I have noticed that the energy of the nuclear repulsion increases with each iteration of optimisation. What is the logic behind this?
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0answers
58 views

Virial equation - Taylor expansion

I don't get how Taylor expansion over $ \frac{1}{\overline{V}} $ of Virial equation of state is carried: $Z = \frac{P\overline{V}}{RT} $ which yields $$ Z = 1 + \frac{B_{2V}(T)}{\overline{V}} + ...
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0answers
26 views

Maxwell relations | U goes down pressure?

Differentiating Helmholtz function $ A = U - TS $ with respect to $V$ we get: $$ (\frac{\partial A}{\partial V})_{\scriptscriptstyle T} = (\frac{\partial U}{\partial V})_{\scriptscriptstyle T} ...
2
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4answers
791 views

The “binding energy” of bonded particles adds mass?

This is a follow-up my previous question. Several of the answers indicated that the mass of a particle (atom, proton, etc.) increase with the "binding energy" of it's component particles - the energy ...
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2answers
90 views

Electrolysis boat engine

Would it be possible to create a submersible boat engine using the combined principles of electrolysis of water, ramjet propulsion, and hydrogen-oxygen combustion similar to that used in rocket ...
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0answers
47 views

Does a fixed amount of gas have slighty more mass when at a higher temperature?

According to relativity, energy and mass are equivalent. Does this mean that the energy added to a fixed amount of gas when it is heated adds slightly to the mass of the gas? The difference would be ...
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0answers
42 views

Filling an empty box with ambient air

A rigid box has a volume of $V_1$ and is thermally isolated so that it exchanges no heat with its environment. Initially the box is empty, and the air around it has a pressure of $P_0$ and a ...
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5answers
4k views

When I stretch a rubber band, it breaks. When I hold the broken ends together, why doesn't it join again?

The question is simple. When we join the two broken surfaces, what is it that keeps the surfaces from connecting with each other, while earlier they were attached to each other? Also, would the two ...
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4answers
15k views

Is it possible to flow current in open circuit?

As I know a battery is an example of a closed circuit where it can then produce electricity , electrons will flow from negative pole to positive. A chemistry representation of this battery is for ...
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2answers
44 views

Molecules from atoms [closed]

Why does two oxygen atoms combine to form a molecule and not 3 or 4?Also why does one sodium and one chlorine atom combine to form NaCl while two chlorine atoms are required to combine with one ...
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2answers
398 views

Correlation energy - is it the difference between the Hartree-Fock energy and exact energy, or Hartree-Fock PE and exact PE?

For some reason I can't find anything stating it either way explicitly. What I'm talking about is this. Is this difference referring to potential energies or just energies in general? I assume it's ...
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2answers
11k views

How to estimate the physical size of a molecule?

I'm reading some chemistry-related papers that employ concepts of droplet evaporation. Since I am no chemist, I am wondering: How can I estimate the actual size of a molecule, say succinic acid? An ...
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2answers
3k views

Obtain oxidation numbers from looking at electron configuration?

Suppose I know that Selenium has electron configuration $[Ar] 4s^2 3d^{10} 4p^4$. How can I use this information to then come to the conclusion that its possible oxidation states are 6, 4, 2, 1 and ...
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1answer
64 views

Why water expands when freezes? [duplicate]

I'm sure this is for most of you a basic question, but it really puzzles me: How it is that, even though all materials expand as they get warmer, and contract (maybe these are not the correct terms) ...
3
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5answers
411 views

What compounds or elements only have one phase or two phases?

Wood appears to be one. I think gases like helium and hydrogen cannot exist in the solid state under normal pressures, correct? And why do those "phase cheaters"-- those elements/compounds which ...
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2answers
111 views

Atomic orbitals

I just studied atomic orbitals in a theoretical QM class, and I'm left with several questions, that are probably more questions in quantum chemistry: Many orbitals seem to have a preferred axis - ...
2
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1answer
60 views

Why does sunlight cause colors to fade?

If you leave something outside, its colors seem to inevitably fade or bleach due to exposure. Is this due to UV absorption? What sort of mechanism causes this - is it that man-made dyes deform on a ...
0
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2answers
94 views

Why do corpses come back to water surfaces after sinking at first?

I want to know that why do dead bodies or corpses come back to the water surface after being sunk at first by the use of stones or anything. For what I can understand, I think it's due to water ...
3
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2answers
103 views

Questions about the strange character of antimatter

Its been a few days and i have just been introduced to the concept of antimatter. Every Speck of matter in the world has its anti form basically that we have antimatter whenever we have matter. But I ...
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1answer
87 views

Question regarding NaCl equilibrium separation

So I am tutoring someone later and one of the problems is from Eisberg/Resnick Ch 12. The potential energy $V$ of NaCl can be described emperically by $$V = \frac{-e^2}{4\pi\epsilon_0 ...
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1answer
350 views

Donors/Acceptors in Metal Oxides

Can anyone explain to me why most articles describe chromium as an acceptor in titanium dioxide? In TiO2, titanium has the charge state Ti$^{4+}$ and oxygen has the charge state O$^{2-}$. When Cr ...