Study of macroscopic and microscopic phenomena in chemical systems in terms of physical laws and concepts [thermodynamics, statistical mechanics, kinetic theory, quantum mechanics...].

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What is the position of hydrogen in the periodic table? [migrated]

Hydrogen is not in the first group as it was before and it is now placed above the periodic table? So why is it still categorized as a metal in some books?
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3answers
50 views

Theoretical Calculation of Specific Heat of a Gas

I've read that the theoretical specific heat of a monatomic gas (like dissociated hydrogen or oxygen) is $20.8\, \mathrm{\dfrac{J}{mol\cdot K}}$ at constant pressure and $12.5\, \mathrm{\dfrac{J}{mol\...
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27 views

Where does the energy that release when bond is formed between two atoms come from? [duplicate]

When two atoms attracted to form bond, energy is released. But where does this energy comes from. Is this energy released when electrons goes to their ground state or somewhere else?
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1answer
29 views

How is the formula for percent ionic character derived? [on hold]

How do the "-(0.25)" and the exponential come into play? Formula: Ionic Character = $100(1 - e^{-0.25(X_C - X_H)^2})$
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1answer
49 views

How much approximately the pressure would drop?

A container made from from aluminium ($0.5~\mathrm{mm}$ thickness $10^3~\mathrm{cm^3}$) closed system , it has 50 psi (nitrogen) pressure inside at temperature $80^\circ~\mathrm C.$ Approximately : ...
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37 views

Is Gas flow rate or Volumertric flow rate right one to use for thick wall?

I will make container from steel or aluminium ( 0.5 mm thickness ) and fill it with air (2 bar) and I want to know how much pressure would the container loose overtime (20 years) ? I have asked this ...
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1answer
18 views

Is the bond order in a resonance situation an average or can half bonds exist?

When drawing the lewis dot structure for $NO_2^-$ There is one double bond and one single bond so the molecule exhibits resonance and has bond order of 1.5. Does this mean the molecule shares 0.5 ...
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1answer
41 views

Avoiding a Divide by Zero with Absolute Entropy

I've been reading that unlike enthalpy, entropy has an absolute value that we obtain by setting it equal to zero at absolute zero temperature, but I'm having a hard time understanding how to avoid a ...
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762 views

Is the amount of the soil reduced when plants grow? [migrated]

According to the principle of mass conservation I think the amount of the soil should be reduced when plants grow. But this reduction is not observable so much. For example, some trees (big trees) ...
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1answer
16 views

Adiabation Flame Temperature Overestimation (Hydrogen Gas)

I'm working on some code that computes adiabatic flame temperature given a balanced equation and the relevant thermodynamic properties and I'm starting with the simplest combustion reaction I can ...
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13 views

Is there a way to calculate the change in temperature of water in a vacuum?

My understanding is that water boils when the vapor pressure is reached and then, at some point, freezes. Is there a way to relate the vacuum pressure to the temperature of the water until it changes ...
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40 views

Why human body is not affected on magnetic field?

Electric-current easily cause shock to human body. But magnetic fluxs through human body do-not cause any perceptible change, as-well no invisible-impacts/ health impacts are well-known. We, when hold-...
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2answers
67 views

How much pressure would I lose on one side?

The equation for the gas flow rate (in pressure*volume/time units) $$ Q = {kA\over d} (p_1-p_2) $$ where $A$ is the surface area, $d$ the wall thickness, $p_{1,2}$ the pressures on either side of the ...
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30 views

Question about the reaction quotients

I have a question connected with the reaction quotients. In another post (How to express the chemical potential at zero partial pressure?) it was revealed that the chemical potential of a substance is ...
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0answers
28 views

How to express the chemical potential at zero partial pressure?

Does someone know how to express the chemical potential at zero pressure? In the expression of the $i$th component $${{\mu }_{i}}=\mu _{i}^{\otimes }+\int\limits_{p_{i}^{\otimes }}^{{{p}_{i}}}{{{V}_{m}...
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2answers
42 views

How does sawdust selectively absorb water?

This Wikipedia page states that sawdust, cellulose etc. can be used to absorb water from azeotropic ethanol to produce anhydrous ethanol. How does this work? Why would the sawdust not simply absorb ...
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2answers
54 views

Why does the Gibbs free energy not decrease ad infinitum?

I would like to ask which guarantees if the Gibbs free energy has a minimum in closed system (e.g. in a chemical reaction system) at constant pressure and temperature? Why does it not decrease ad ...
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2answers
29 views

How can the energy released when bonds formed be harnessed to do work?

I'm trying to understand how living organisms get energy from food. I've heard that "energy is released when bonds form", but what exactly does "released" mean? If the energy dissipates in the form ...
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2answers
4k views

Why does sound absorption in oceans depend on the pH?

I was reading "The Sixth Extinction: An Unnatural History", by Elizabeth Kolbert, and there she comments that high level of $CO_{2}$ in the atmosphere lowers the pH of oceans (which makes sense) and, ...
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1answer
47 views

Why do molecules have $3N-5$ or $3N-6$ degrees of freedom?

In linear molecule, it has $3N-5$ degree of freedom in vibration mode and $3N-6$ in non-linear molecule. I can get idea about $5$ and $6$ which is related to translation and rotation but I cannot ...
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1answer
52 views

Total chemical potential of electrons in pn junction

I am reading this page about electron energy concept terminology. I am trying to apply that for the pn junction in equilibrium below. Could anyone help me to see if I get it correctly? C = ...
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1answer
65 views

The exact mechanism of energy release durning bond formation on the atomic level

Image a situation: We have two atomic hydrogen atoms. We magically collide them together dead center and perpendicular. Each atom has exact amount of kinetic energy. We collide them with precisely ...
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1answer
46 views

global warming due to CO2 vs water

What is the physical reason for CO2 being a vital greenhouse gas when it is present at only approx 0.03% of atmospheric composition compared to water vapour, which is present at at least 100 times ...
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66 views

Why exactly does molten NaCl explode, when it is poured into water?

Why does molten NaCl explode, when it is poured into water? NaCl has high melting point, 1074 Kelvins (801'C). NaCl has molar mass 58.44 g/mol, it has specific heat capacity 36.79 J/(Kmol) = 629.53 J/...
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67 views

How to calculate the minimum kinetic energy required by a surface molecule to escape the liquid (during evaporation)?

Evaporation occurs when surface molecules have enough Kinetic Energy to escape the surface of the liquid. Given a certain volume of liquid at a certain temperature, is it possible to determine this ...
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128 views

If a water molecule is neutral how do water molecules attract one another by electric force & form water?

This no sense to me! (im new to physics) and my textbook didnt explain this well!
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1answer
43 views

why do microscopic cracks happen?

2 weeks ago i asked a question about " Gas permeation through solid metal? " i have got a very good answer here .but microscopic crack was mentioned in the answer. i searched in Internet but i didnt ...
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1answer
43 views

What's the minimum time scale for a candle to be lit in order for it to establish a steady state?

My Understanding When a candle is lit initially, it goes through a few stages (see, e.g. this explanation from the National Candle Association): Wick burns. Crusted wax on wick melts, evaporates ...
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26 views

Determining bond length of HCN using rotational constant (Physical Chemistry 2)

Context: 2nd year undergraduate student taking Physical Chemistry II. Question: Determine the HC and CN bond lengths in HCN from the rotational constants: B($^{1}H$$^{12}C$$^{14}N$) = 44.316 GHz B($...
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2answers
48 views

Copper density modification

Can you increase the density of a material surface (metal) by surface treatment? For example commercial copper. If we take the ordinary OF copper (99.95%), I would expect not to have the tabulated 8....
2
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1answer
155 views

Gas permeation through solid metal?

if i make a box from aluminum ( 0,5 mm thickness ) and put air in it ( about 2 bar or 3 bar). would the box lose the air over time (10 years period) or not ? assuming the temperature will change ...
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1answer
25 views

Absorption spectra of molecules library

Do you know where I can find a library with absorption spectra? I would like it if then I could input a wavelength and get back a specific value. More specifically I would like to see the absorption ...
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1answer
51 views

Physical reason of adding salt when we're cooking rice (osmosis)

Why do we add salt when we're cooking rice? I know one reason is related to the boiling point of water but someone said it is also related to "Osmosis". What is the relation between adding salt and ...
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1answer
59 views

Velocity from the cumulative distribution function of the Boltzmann distribution

I want to get a Boltzmann distribution of the $v_x$, $v_y$ and $v_z$ velocity components (please, notice that the distribution is one-dimensional). To do so, I need the cumulative distribution ...
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0answers
39 views

Chemistry of water under pressure [closed]

What is the structure of water under extreme pressure, like the bottom of the ocean on a moon like Europa.
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10 views

Do the isotopologues of a compound affect it's cracking patterns in a residual gas analyzer?

For instance, CO2 is listed as 100% of the peak at 44, 11% of the peak at 28, 9% of the peak at 16, and 6% of the peak at 12. But now consider CO2 comprised of C13. obviously the peaks would be at ...
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1answer
67 views

Why is it easier to remove stains with water?

And I don't mean stain removers, but literally tap water. See here's the thing, you can't remove a stain without some sort of friction, and water reduces friction. Yet if I say, spill some coffee and ...
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1answer
31 views

Conformational Analysis of Ethane and Butane

How does a condensed matter theorist explain conformations of Ethane and Butane using tools from Quantum field theory? If they don't how do they calculate energy differences and predict differences ...
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55 views

Would it be correct to state that all the forms of everyday matter (mountains, tables, buildings, people, etc.) are in a metastable state?

We had a fire going in the backyard of a friends house this weekend, and after thinking about the chemical reactions occurring in the wood (and anything else we threw into the pit), I started to ...
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19 views

How strong is the HCN Union when modelling with springs

I'm modeling the HCN Molecule with springs, giving the bounds between H and C the name k1 and between C and N k2. Is there any information of how strong is the bound? We were asked to get the ...
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2answers
63 views

Free Expansion Of and Ideal Gas

We know that in free expansion of an ideal gas, no heat enters or leaves the system. We also know that $P_\text{initial}V_\text{initial}=P_\text{final}V_\text{final}$ is valid. If heat exchange ...
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8 views

Energy Per Dry Ice Mass Required By de Laval Expansion of Air?

There has been a lot of talk lately about CO2 extraction from air. Since there are rocket engines in which ice crystals precipitate in the exhaust when expanding into near vacuum, it seems dry ice ...
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29 views

breaking bonds with light

Light, for instance green light (532 nm = 2.33 eV) has an energy comparable to that of many chemical bonds (C-C bond dissociation energy is about 3.6-3.7 eV). So how is it that I'm not being burned ...
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1answer
98 views

FCC-to-BCC phase transition in NaCl, Buckingham or Lennard-Jones potentials?

Background The transformation from B1 (face centered cubic (FCC) type) to B2 (body centered cubic (body centered cubic (BCC) type) structures is one of the best documented high pressure phase ...
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9 views

Butler-Volmer Anodic and Cathodic Activation Constant Proof

In the Butler-Volmer Equations, I have often seen the activation constant at the anode and cathode related by: $$ a_a=1-a_c $$ This is the relation used, for example, on plots of this equation on ...
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1answer
41 views

How much salt to dissolve in water for a noticeable change in volume?

I am reading through this High School science lab about how dissolving salt changes the volume of water: Place 300 to 400 g of salt in the flask (1L) Pour in enough water to cover the dry salt, and ...
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1answer
20 views

Why is beta-minus decay considered isobaric?

Page 20 of Physics in Nuclear Medicine says that beta-minus decay is isobaric (eg the A/Z ratio remains the same). The reason it gives is that "mass number A does not change." However, in beta-minus ...
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1answer
99 views

What is the desest material on earth? [closed]

Apart from the elements, do we know of materials that are denser? I.e. can an alloy be denser than the sum of its compounds, for example if the new lattice packs denser than each of the compounds it's ...
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30 views

How did scientists calculate the number of atoms in one mole of a substance? [duplicate]

Please explain me about the basic methods about how can we calculate that 1 mole of a substance contains 6.022140857 × 10 23 molecules? Tell how the modern scientists calculated it and how Avogadro ...
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77 views

What would be the best material to reflect radio waves?

I was thinking about what would be needed to build a parabolic dish and I inevitably came to what material to use. From what I could gather after a quick search on the internet, it would seem that any ...