Tagged Questions

Study of macroscopic and microscopic phenomena in chemical systems in terms of physical laws and concepts [thermodynamics, statistical mechanics, kinetic theory, quantum mechanics...].

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1answer
23 views

bimolecular reaction master equation

I was wondering how to write down the deterministic rate equation for a bimolecular reaction with similar particles. e.g. $A \rightarrow^{k_+} B +B$ and $B +B \rightarrow^{k_-} A$ now the rate ...
1
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0answers
12 views

Reduction of Ilmenite [migrated]

I am looking for a process in which reduces ilmenite to pure Titanium with the highest yield possible. We are to use a process of our choice or one that we have created in conjunction with FactSage to ...
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0answers
16 views

What is the minimum bend radius of a square optical fiber on a microfluidic chip interface?

I want to make a microfluidic chip with colorimetry cuvettes with 100um square optical fibers coupled to the side of them. They should bend at a 90 degree angle to exit the side of the chip in a ...
1
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0answers
18 views

Mixing liquids when applying a voltage

I'm thinking in the following experiment: A) Two (non mixable (like water and oil)) liquids are going to lie in a container, in the extremes of the container there are two electrodes, those ...
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2answers
364 views

Can we fully simulate molecular physics?

Is our knowledge of physics complete enough to achieve fully natural simulations of molecular interactions in a computer simulation? How far off are we? Reason for question: I wonder how far we are ...
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0answers
28 views

problem about heat in thermodynamics

$$\nabla G=-T\nabla S-T\nabla S_{sur}=-Q+q $$ $$\nabla G=-T\nabla S-T\nabla S_{sur}=-(U-W_{rew})+q $$ $$\nabla G=-T\nabla S-T\nabla S_{sur}=-(q+W-W_{rew})+q $$ $$\nabla G=-T\nabla S-T\nabla ...
1
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2answers
47 views

How do we represent 'smell' and 'taste' as signals?

I was wondering if we could represent 'smell' and 'taste' as signals like we do for audio. How do we mathematically represent them? Is there any research papers related to it? Can someone give me ...
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5answers
109 views

Mass and Energy

Would the mass of burnt firewood be equal to the mass of firewood before burning? Then where does that heat come from? According to Einstein's equation, $E=mc^2$ Shouldn't there be some mass going ...
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1answer
45 views

Boiling is not well described? [duplicate]

It is said that boiling occurs only when the vapour pressure becomes equal to the pressure surrounding the vapour (say atmospheric pressure). Why does it take place only satisfying these conditions ...
1
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2answers
45 views

How much entropy is produced in evaporating water due to irreversible evaporation towards equilibrium (humidity=100%)?

$dS=dH/T_{boil}$ for the increase in entropy by changing a phase at saturation ($T=373\text K$ for $p=1\text {atm}$ for water). However, water also obviously evaporates below boiling point when ...
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1answer
70 views

Understanding the phase separation of a chemically reactive mixture

Let's consider a mixture of solvent and components $A$ and $B$ such that $A$ can transform into $B$ with a rate $k_1$, and the reverse reaction with a rate $k_2$. $A \rightleftharpoons^{k_1}_{k_2} B ...
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0answers
17 views

Conical intersections - phase

Can anyone explain why at a conical intersection the wavefunction changes sign? My understanding is that it is a test to see if the crossing IS indeed a conical intersection or just a coincidence of ...
1
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1answer
146 views

Gas viscosity at high pressure, high temperature

EDIT 1 PER COMMENTS I am wanting to model nitrogen gas viscosity as a function of pressure and temperature OR learn of an existing equation that models nitrogen viscosity for the pressure and ...
7
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1answer
68 views

What would be the first compound formed in the early universe?

This may sound like a chemistry problem, but I suspect this would have lot to do with primordial nucleosynthesis. After all physics underlies everything. It is believed that several elements were ...
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0answers
27 views

Solving for the Nernst Potential in 3D

Hi guys I'm totally stuck on the following question: We know the ionic flux between two chambers due to uneven concentration can be computed by the Nernst-Planck equation $$j = -D_p \left(\nabla C ...
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4answers
345 views

Two soft questions about spin and the particle nature of electrons

How can we define spin as the spin of an electron around it's own axis if an electron is described by a probability cloud of finding an electron in a point in space? How does that probability cloud ...
0
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1answer
23 views

(Chemistry) Dimensionless heat transfer coefficient

I'm trying to reproduce in Matlab the model of a continuous stirred tank reactor (CSTR) that I've gotten for a project. The model is written in the state space and uses some dimensionless values, ...
6
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1answer
233 views

Steam above meal

When I fry something on the pan and the fire is big and intensive (the flame over the pan), there is no stean above the pan or just a little. But when I turn off the fire, suddenly the steam appears, ...
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0answers
55 views

Why are atoms with a complete octet the most stable ones? [duplicate]

I mean are the valence electrons in an octet arranged so that they have the lesser amount of energy that is lesser than electrons in other atoms?
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0answers
29 views

Approach to model solvent in a lattice: e.g. H2O in NaCl

If a lattice contains a solvent, lets say NaCl and water of crystallisation, what is the condition for a solvent molecule to change it's location? From my current point of view I assume that such a ...
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4answers
500 views

Bond Angles - H2O vs CO2

H2O has a 109.5 degree bond angle, but CO2 has exactly 180 degrees. Is there a qualitative reason for this? It's hard to believe CO2 is exactly 180 degrees unless there were some symmetry, but the ...
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0answers
39 views

Linear decrease in temperature during a redox reaction?

This is physics-related, don't worry. To calculate the enthalpy change of a solution during a redox reaction, what we did in class was measure the temperature of the solution every 30 seconds (before, ...
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1answer
37 views

Hydrogen extraction efficiency of newish nano particle AA battery

The internet is ablaze with the new nano particle based extraction method of converting water to hydrogen. In 2002/2003 when I was 16 there was a similar craze about a lawn mower motor which ...
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1answer
40 views

why some elements of same group cannot be used for doping semiconductors?

15th group elements like As, Sb, P can be used for doping whereas N and Bi cannot be used for doping even though they too belong belong to 15th group. Why ?
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3answers
183 views

Potential energy graphs of chemical systems

I really wish someone could dissect this for me in the language of physics. The system is that of two atoms that approximate each other along 'r' (or distance themselves apart). My concerns are ...
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0answers
79 views

Milk-First School

I have always been struck by the huge amount of different arguments about the issue: When you make a cup of tea, the milk should be poured first or added to the cup after the tea? Wikipedia, ...
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1answer
30 views

Can a Chemical's Opacity be Deduced Mathematically?

all. I have tried Googling but have had no luck. My question is simple (although, I presume the answer is not): If one knows the chemical structure of, well, a chemical, could its optical properties ...
3
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1answer
180 views

Why does the thermal conductivity of water decrease with increasing salinity?

Intuitively I would expect the thermal and electric conductivity to be positively related, and since electric conductivity increases with salinity, so should thermal. But according to this table ...
1
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1answer
64 views

Conductivity of Aqueous Ionic Solutions as a Function of Time

It is well-known that an aqueous ionic solution can conduct electricity. Let's take the electrolyte NaCl for example. In the diagram below, the circuit consists of a voltage source, a light bulb, and ...
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3answers
97 views

Is duplication of nucleus, electron and proton (sub-atomic particles) possible? [closed]

usually a single cell develops into a huge mass to form a substance or an organism. is this happening because of multiplication of sub-atomic particles? if yes, then is it possible to multiply the ...
3
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2answers
171 views

Why does smashing a TV remote load its batteries?

Many times I had the same problem: my TV remote's batteries were too weak for it to operate, but then, when I shook the remote a bit and smashed it on my palm, somehow the remote regained its ability. ...
2
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0answers
26 views

Electrochemical cell potential - Prigogine book

I'm trying to understand equation 10.2.14 from Prigogine book "Moder thermodynamics": $V=\frac{\tilde{A}}{nF}=\frac{1}{nF}\left(\mu_X^R+\mu_Y^L-\mu_{Xred}^R-\mu_{Yox}^L\right) - \left( \phi^R-\phi^L ...
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1answer
59 views

On Thermodynamics of Spontaneity of the Reduction-Oxidation Chemical Reactions

According to the first and second law for a closed system containing different chemicals we have \begin{align} &\delta Q - \delta W = dU = T dS - p dV +\sum_i \mu_i d N_i\\ ...
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1answer
58 views

Why does intramolecular hydrogen bonding cause molecules to separate?

Today I learned about intramolecular hydrogen bonding, which occurs in molecules such as ortho-nitro-phenol. What I was told is that, in case of intramolecular bonding, the molecules separate from ...
7
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2answers
139 views

Why is salt so hard to remove from water?

Water molecules and various salt molecules are very different. However, it seems very difficult to separate the two. Once a salt is dissolved in water, an energy or chemical intensive method (like ...
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0answers
67 views

Solar still and how it works

I use a solar still that holds 182 cubic feet of water. Here is how it works: There is an insulator on both sides of the metal bowl. On the outside it covers the whole thing. on the inside it covers ...
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2answers
154 views

Melting and Boiling Points of Odd Materials

In Chemistry, I was taught that there are three main states of matter: solid, liquid, and gas, and that heat and pressure determine that state. For some substances, the line is blurry between them. ...
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0answers
24 views

How does Passivation in Mercury-arc-valve cause “diode” behavior

Does passivation of lead anodes cause them to become semiconductors? Or even become diodes (eg. a p-n passage)? How does this work on an atomar level? This question has been risen by trying to ...
0
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1answer
60 views

does there exists a rope such that it takes longer to burn the whole rope from one end? [closed]

And it takes less time to burn from the other end. The rope could be any of materials and structures and asymmetric. EDIT: But the external environment may not change during burning, and the way (eg ...
2
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2answers
85 views

Is every material able to exist in every state of matter?

I was shocked while reading Kittel's "Introduction to Solid State Physics", that the solid state of noble gases is a well described and makes one of the fundamental achievements of solid state ...
3
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0answers
79 views

What is a covalent bond?

What is a covalent bond, quantum mechanically? How does it hold the two atoms together, and at one point can you qualify the electron as being shated between two atoms, versus feeling attractive ...
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0answers
29 views

Covalent Bonds, Varities and Limits!

Related:http://chemistry.stackexchange.com/q/9459/ I was wondering, covalent bonds tend to share two electrons, apparently rarely more than three, and normally between two electrons. Can someone give ...
3
votes
2answers
211 views

Kinetic proof of law of mass action

Suppose we have a chemical reaction of the form $$n_1 A_1 + \cdots + n_r A_r \leftrightarrow m_1 B_1 + \cdots + m_s B_s$$ where $A_i$ and $B_i$ are molecules, and the $n_i$ and $m_i$ are the integer ...
2
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1answer
64 views

Would other intelligent life in the Universe be likely to construct the same periodic table of the elements? [closed]

Is the structure of the periodic table fundamental enough that other forms of intelligent life would likely structure their own listing of the elements in the same way (i.e. are there other ways of ...
3
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2answers
66 views

Chemical effect on gravitation?

We know, that gravitation field of charged black hole is different than one of uncharged. I this true only for objects with singularity or is true for all objects? If true, then may we say, that ...
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3answers
134 views

Solving the simplest coupled nonlinear ODES for chemical kinetics [closed]

I am just trying to get the integrated form for the kinetics of the reaction $A + B \rightarrow C + D$ characterized by: $$ -\dfrac{d[A]}{dt} = -\dfrac{d[B]}{dt} = k[A][B] \; . $$ As you note, ...
0
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1answer
57 views

In what sense can an object in outer space be “on fire”?

The famous "Tears in rain" soliloquy in Blade Runner goes like this: I've... seen things you people wouldn't believe... [contemptuous laugh] Attack ships on fire off the shoulder of Orion. I ...
2
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4answers
143 views

role of entropy in gibbs free energy intuition

I have looked at various derivations of the Gibbs free energy equation and the underlying definition of the gibbs free energy. However I have been unable to attain direct insight/intuition over the ...
0
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1answer
50 views

Chemical potential in terms of temperature and pressure

For part (a), I know how to take the partial derivatives of S to get chemical potential, pressure. But there seems that I still need one equation to correctly express chemical potential in terms of ...
2
votes
1answer
254 views

Particle in a 1D Box with Symmetric potential: How find solutions?

I am working on a problem in which I shall find the normalised solution to the 1D particle in a box. Solving for the particle in an asymmetric potential is quite straight forward, but I run into ...