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What is the effect of phase transition on the thermodynamic state variables of a material?

When a material undergoes a phase transition, it releases an amount of heat (under a specific temperature). So the effect of the phase transition on entropy would be equal to: \begin{align} ...
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3answers
237 views

The cooling curve of tin during solidification

I'm going to measure the freezing point of tin by recording the cooling curve. It sounds like a dull experiment because all I have to do is to heat up the tin, wait for it to cool, and the computer ...
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1answer
210 views

Goldstone mode in O(N) (non-linear $\sigma$ model)

The question is does the Non-linear $\sigma$ model have a Goldstone mode? Consider a $O(N)$ mode for which the Hamiltonian is $H=J\sum_{i,j}\vec{n}_i \cdot \vec{n}_j$, where ...
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2answers
139 views

Drying up a wet object

I am wondering whether an object which has been wet with hot water always dries up more easily and more quickly than one wet with cold water. How much do the shape, roughness, material, structure of ...
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1answer
133 views

Is water a gas at critical density, room temperature?

I am quoting Chaikin, Lubensky, Principles of Condensed Matter Physics, p. 4. Now suppose we have a closed container of water vapor at a density of 0.322 g/cc at room temperature. As the ...
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1answer
47 views

Reversed freezing point

Helium-3's Phase diagram shows that at the right temperature and pressure combination, the solid region dips downward as temperature increases. That means that you can heat it up and it will freeze. ...
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0answers
249 views

Can Lee-Yang zeros theorem account for triple point phase transition?

Now the prominent Lee-Yang theorem (or Physical Review 87, 410, 1952) has almost become a standard ingredient of any comprehensive statistical mechanics textbook. If the volume tends to infinity, ...
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2answers
464 views

Is there a phase transition between a gas and plasma?

Does a phase transition occur as a gas is heated to create a plasma? If so, is this a first or second order phase transition? Also, does the presence of a phase transition depend on the pressure or ...
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1answer
101 views

What is the 'super' parameter of superconductivity and what is the role of Cooper pair?

Only thing I know about superconductors is that here the electrical current face zero resistance. My first question is what is 'super' (physical or mathematical entity) about a superconductor. Or more ...
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1answer
344 views

Does this type of phase transition exist?

The short version of this question is: Is there, or could there be, a system with a phase transition where adding a small amount of heat causes a discontinuous jump in its temperature? Below are ...
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3answers
4k views

First and second order phase transitions

Recently I've been puzzling over the definitions of first and second order phase transitions. The Wikipedia article (at the time of writing) starts by explaining that Ehrenfest's original definition ...
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0answers
187 views

Some ambiguous points on Spontaneous Symmetry Breaking (SSB)?

Almost in every textbook of condensed matter physics, the standard description of SSB could be formulated as follows: Consider the lattice Heisenberg model in an external magnetic field ...
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1answer
431 views

Definition of phase transitions in statistical mechanics

Phase transitions in statistical mechanics are usually taught by working through a bunch of examples. I decided to try and think about them from a more "fundamental" point of view - but I've run into ...
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0answers
41 views

Vapor Pressure and Container

The following comes from my text and concerns vapor pressure: Consider a liquid in a closed, cylindrical container that is half full. The molecules at the surface of the container and along the edges ...
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0answers
48 views

Reconciling Different Vapor Pressure Definitions

In describing vapor pressure, I have often heard the following intuition: Assume a closed container that is partially filled with water. Above the water lies a vacuum. The water will vaporize until ...
3
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1answer
194 views

Symmetry breaking in Bose-Hubbard model

According to Landau's symmetry breaking theory, there is a symmetry breaking when phase transition occurs. What is the symmetry breaking of superfluid-Mott insulator transition in Bose-Hubbard ...