# Tagged Questions

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### Proof of Liouville's theorem: Relation between phase space volume and probability distribution function

I understand the proof of Liouville's theorem to the point where we conclude that Hamiltonian flow in phase-space is volume preserving as we flow in the phase space. Meaning the total derivative of ...
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### Canonical ensemble, energy, heat bath

I am studying through the book Thermodynamics and Statistical Mechanics by Walter Greiner and I’ve got a couple of doubts when I was reading about the classical ensembles, specially the Canonical ...
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### Can statistical mechanics be formulated generally in terms of phase space?

In many statistical mechanics books, notably Landau and Lifschitz' volume in the course on theoretical physics, the quantities central to statistical mechanics such as entropy are defined in terms of ...
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### phase-space volumes or cells for N particle system

For N non interacting spinless particles in a volume, we have 3N degrees of freedom and we can divide the phase space into 6N dimensional cells of volume h raised to power 3N. And each cell ...
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### Ensemble of harmonic oscillators

I have some problems with problem 2.3 from Reif's Fundamentals of statistical and thermal physics: Consider an ensemble of classical one-dimensional harmonic oscillators. a) If we assume ...
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### What would happen if energy was conserved but phase space volume wasn't? (and vice-versa)

I'm trying to understand the relationship between the two conservation laws. As I understand, Liouville's result is a weaker condition: it relies merely on the particular form assumed by Hamilton's ...
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### Phase space in quantum mechanics and Heisenberg uncertainty principle

In my book about quantum mechanics they give a derivation that for one particle an area of $h$ in $2D$ phase space contains exactly one quantum mechanical state. In my book about statistical physics ...
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### Postulate of a-priori probabilities

In Statistical Mechanics, we often postulate that for an isolated system, the phase-space density of all accessible microstates (i.e all microstates consistent with the energy) is the same. This is ...
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### Phase volume contraction in dissipative systems

I am confused about phase-volume contraction in dissipative systems. Please help me catch the flaw in my understanding. From a macroscopic point of view I understand that a dynamic system tends to go ...
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### number of microstates associated with two-level quantum systems

this is a very simple question, but apparently one that has no simple answer, at least from standard quantum mechanics theory I'm trying to figure the number of simple quantum states (microstates) of ...
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### Is particle number a problem for formulating statistical physics in a mathematically rigorous manner?

Quantities like the chemical potential can be expressed as something like $$\mu=-T\left(\tfrac{\partial S}{\partial N}\right)_{E,V}.$$ Now the entropy is the log some volume, which depends on the ...