3
votes
0answers
86 views

What does it mean to expand a Hamiltonian using perturbation theory?

On UC Davis chemwiki website, the Hamiltonian for quadrupolar coupling in NMR is analyzed. (The details of this aren't important.) It is said in the analysis that: The expansion of the ...
0
votes
1answer
48 views

Vanishing diagonal matrix elements of pertubation

In time-dependent pertubation theory we can denote the Schrödinger equation by a set of two equations $$\dot{c_a} = -\frac{i}{\hbar}\Big[c_aH'_{aa}+c_bH'_{ab}e^{-i(E_b-E_a)t/\hbar}\Big] \\ \dot{c_b} ...
2
votes
1answer
121 views

Quick question on perturbation theory

Suppose we have a particle in an infinite potential well, with $V(x) = 0,\space 0< x < a $ and infinity everywhere else. Now suppose we have a perturbation on the LHS of the well: $V_1(x) = v, ...
5
votes
2answers
665 views

Expectation value of time-dependent Hamiltonian

I'm trying to solve a problem in QM with a forced quantum oscillator. In this problem I have a quantum oscillator, which is in the ground state initially. At $t=0$, the force $F(t)=F_0 \sin(\Omega t)$ ...
2
votes
1answer
199 views

Perturbation method & eigenvalues

I have a problem but I don't understand the question. It says: "Show that, to first order in energy, the eigenvalues ​​are unchanged." What does it mean? It means that if the Hamiltonian has the ...
1
vote
1answer
253 views

Symmetry and overlapping of ground states

In a quantum mechanics, there is the following formula to derive the zero energy $E_0$ of a perturbed Hamiltonian $$H = H_0 + V$$ knowing the zero energy $W_0$ of the free Hamiltonian $H_0$: $$E_0 = ...
4
votes
1answer
306 views

center of mass Hamiltonian of a Hydrogen atom

I'm working through Mattuck's "A Guide to Feynman Diagrams in the Many-Body Problem", but I'm stuck on a bit which I feel should be trivial. In section 3.2 (p 43 in the Dover edition) he gives a ...