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3
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1answer
51 views

Physical interpretations of the generating functions $Z[J]$ and $W[J]$ (or $E[J]$)

In quantum field theory, the generator of all Green's functions $Z[J]$ and that of the connected Green's functions $E[J]$ are related as $$Z[J]=\exp[-iE[J]]=\int D\phi\exp[i\int ...
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1answer
37 views

What is the difference between these two expressions for the partition function, Z?

What is the difference between these two expressions given for the partition function, Z? $$Z = \sum_{i}e^{-\varepsilon_i/kT}$$ $$Z = \sum_{j} g_je^{-\varepsilon_j/kT}$$ where each energy level has ...
0
votes
1answer
50 views

Relation between Canonical and Grand Canonical Ensemble for a two levels system

For a two-level system of classical non interacting distinguishable paricles, labelling energy levels as $+\epsilon, -\epsilon$, in the canonical ensemble I found for the partition function ...
4
votes
2answers
314 views

Physical meaning of partition function in QFT

When we have the generating functional $Z$ for a scalar field \begin{equation} Z(J,J^{\dagger}) = \int{D\phi^{\dagger}D\phi \; \exp\Big[{\int L+\phi^{\dagger}J(x)+J^{\dagger}(x)}\phi\Big]}, ...
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votes
1answer
52 views

Why does this formula for the partition function not include the multiplicity?

I am having problems understanding the formulas used for describing the partition functions and the probability distributions for canonical ensembles. In the first case I have two formulas for the ...
1
vote
1answer
34 views

How to write any partition function?

So I am familiar with the derivation of the partition function for a canonical and a grand canonical ensemble. I have seen definitions of the partition function for some of the quantum counterparts of ...
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0answers
27 views

3-state Potts model - probability of finding a site in state 1

Question: Consider the 1d 3-state Potts model of N sites (i.e., each site can be in either state 1, 2 or 3). Find the partition function and the probability of finding a site in state 1, $< ...
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1answer
85 views

Deriving Enthalpy from Stat Mech

One can derive all the numerous thermodynamic potentials (Helmholtz, Gibbs, Grand, Enthalpy) by Legendre transformations, but I'm interested in seeing each from Stat Mech instead (ie taking the log of ...
1
vote
1answer
52 views

Difference between semi-classical Maxwell Boltzmann Statistics and Boson Statistics

Since semi-classical MB assumes the indistinguishability of particles and Boson Einstein statistics similarly treats degenerate states as indistinguishable states. What is their difference when ...
0
votes
1answer
38 views

Question on the degeneracies of a thermodynamic system

I think I have a basic understanding of what degeneracies are: Two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon ...
1
vote
1answer
35 views

Partion function for ideal gas - why use only one octant?

In these lecture notes (page 2) and in other sources I have checked, it says that the number of states with $k\in[k,k+dk]$ is: $$dN=\frac{4\pi k^2V}{8\pi^3}$$ Saying the factor of $8$ comes from the ...
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vote
1answer
60 views

Relation between the $N$ particle partition function and probability?

For the 1 particle partition function the probability that the particle is in the state with energy $\varepsilon_i$ is given by: $$P_i =\frac{e^{-\varepsilon_i \beta}}{Z_1}$$ where $Z_2$ is the 1 ...
6
votes
1answer
138 views

General formulation for fermions

Let us look at a set of fermionic creation and annihilation operators $b_n$, $b_n^\dagger$ with $n \in \mathbb{N}$. What is the precise relationship between this and this sequence here (partition ...
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0answers
58 views

What is the phase space volume in terms of angular momentum?

Given a rigid rotor Hamiltonian, defined along the principle axes as $$ H = \sum_{i=1}^3 \frac{L_i^2}{2I_i} $$ say we would like to compute the classical partition function of this system. Is the ...
0
votes
1answer
90 views

Statistical mechanics of ideal gas in a box with adsorption states on surface [closed]

Assume we have a cubic box of side length 1m with ideal gas particles inside. We assume the binding energy of a gas molecule to the wall is 1eV. One can make the simplifying assumption that: ...
2
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0answers
77 views

How to find explicit QFT particles from a heterotic String theorie partition function

Starting with a SUSY $E_8$ x $E_8$ heterotic partition function: $ Z = - \frac{1}{8} \sum Z^8_x Z_4[^s_{s'}] Z_8[^t_{t'}] Z_8[^u_{u'}] $ where the sum is over all spin structures $s,t,u,s',t',u' = ...
5
votes
1answer
221 views

What are alternative ways to think about transfer matrix as used in Ising model?

I recently learned about how to find the partition function of Ising model using Transfer Matrix method. At my level of understanding things, it is a trick that happens to work! I would like to ...
3
votes
1answer
76 views

Does the canonical partition function count microstates?

The microcanonical partition function is the density of states. The canonical one, from a dimensional point of view, is still a number of states, but does it actually count microstates? I tried ...
2
votes
1answer
107 views

Partition Function and BlackBody Radiation

I'll start with a few definitions: $$\beta \equiv \frac{1}{k_bT}$$ Where T is the temperature of a system. And the partition function: $$Z \equiv \sum_{j}e^{-\beta \epsilon_j}=\int ...
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0answers
27 views

Partition Function And Macroscopic Properties

In renormalization group transformations, partition function is fixed. My question is which thermodynamic properties are fixed in a renormalization group transformation.
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0answers
440 views

What is the physical meaning of a Partition Function in Statistical physics?

In many places in statistical physics we assume the partition function. To me the explanations after partition functions are most of the times clear but always wonder why a partition function and what ...
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0answers
59 views

Is there a local canonical ensemble partition function for a Bose-Einstein gas?

The grand canonical partition function for a Bose-Einstein gas is $$ Z_{\text{grand bos}} = \exp \left( \sum_{j=0}^{\infty} -\ln \left( 1-e^{\beta(\mu-\epsilon_j)} \right)g_j \right) $$ where $\beta$ ...
2
votes
2answers
233 views

Multiplicity vs Partition function

I'm a little confused between all the different notations for the multiplicity and partition function. They're not the same thing, are they? I know that entropy can be expressed as $ S = k \ln\Omega ...
0
votes
1answer
39 views

potential energy of a segment of an ideal chain under external force

I want to construct the partition function of an ideal chain under applied external force. Let's say we apply force to both ends (with opposite sign) acting in z-direction and a segment of the ideal ...
1
vote
1answer
104 views

canonical ensemble that is quantum mechanical and continuous?

I do not understand what the following statements from Wikipedia mean For a canonical ensemble that is quantum mechanical and continuous, the canonical partition function is defined as $$ Z = ...
0
votes
1answer
39 views

Mono-atomic gas particles coupled by spring forces don't care how many particles are involved?

I calculated the partition function of $N$ classical atoms of identical mass $m$ who all experience a mutual spring forces with identical spring constant $k$. The Hamilton is \begin{align} H = ...
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2answers
104 views

Partition function of a 3D vibrating string

Is the partition function of a 3D vibrating string a sum of discrete energies, an integral of an energy continuum, or both? $$ Z_{\text{disc}} = \sum_{k=1}^{\infty}g_ke^{-\beta E_k} $$ or $$ ...
1
vote
1answer
83 views

A trace formula of two noncommutative operators

In many cases of quantum many-body problems, the Hamiltonian $H$ can always be divided into two parts, i.e. $H_0$ and $H'$. In this occasion, one can systemically calculate the partition function ...
0
votes
1answer
77 views

Partition function is simply temperature if possible sub system energy is continuous?

Partition function is $$Z=\sum_j\exp\left(-\frac{\epsilon_j}{kT}\right)$$ a sum over all possible energy levels $\epsilon_1,\epsilon_2, ..., \epsilon_M$. There must be a finite number of choices ...
3
votes
1answer
367 views

About the factorial N! in the partition function

After reading these posts: Why is the partition function divided by $(h^{3N} N!)$? , What is the resolution to Gibb's paradox?, and some of these: http://arxiv.org/abs/1012.4111 , ...
2
votes
1answer
79 views

Einstein model for thermal capacity of solids and indistinguishability of the oscillators

Albert Einstein's theory of thermal capacity of a solids makes the assumption that a crystal is made up from oscillators which of course oscillate, in all three directions. Thus, for N atoms of the ...
1
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1answer
261 views

Difference in partition function of classical and quantum Ideal gas

First, I have read this question:What is meant by the term "single particle state" There is an analysis going on in my book (Mandle F. Statistical Physics) that has brought me in a ...
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4answers
523 views

Why is the partition function divided by $(h^{3N} N!)$?

When computing partition functions for classical systems with $N$ particles with a given Hamiltonian $H$ I've seen some places writing it as $$Z = \dfrac{1}{h^{3N} N!}\int e^{-\beta H(p,q)}dpdq$$ ...
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1answer
169 views

What is the definition of 'relative population' in context of partition function?

In statistical mechanics, what is the definition (or mathematical definition) when authors refer to relative population in the case of a classical particle system?
0
votes
1answer
61 views

is it necessarily true that the partition function $Z$ (with degeneracies) $ =1$?

The partition function with degnerate energies is $$\text{Z}=\sum _ig_ie^{{-E_i}/{k_BT}}.$$ Because the partition function Z is defined as the normalisation constant, does Z always = 1?
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vote
2answers
141 views

Conceptual explanation of the Single particle partition function

The Single particle partition function is defined mathematically as $$\text{Z=$\sum $}g_ie^{\left(\frac{-E_i}{K_BT}\right)}$$ But what is the physical interpretation of the partition function and ...
1
vote
1answer
62 views

Superstring vacuum amplitude on the torus

My question is how to obtain the superstring (Type II A and B) vacuum amplitudes on a torus. They are given in Polchinski's String Theory Vol. 2 equation (10.7.9): ...
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vote
0answers
163 views

How is partition function related to ordinary generating function?

Ordinary generating function can be used to solve combinatorial enumeration problems. Now if the energy levels are discrete, say $g_i$, and if one want to count how many ways one can add up $g_i$ ...
2
votes
1answer
165 views

How to understand Density of States with dispersion relation

I am having trouble understanding the Density of states concept. As I currently understand it, for the density of states $g(k)$ it is the number of microstates with wave number in the range ...
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0answers
69 views

Proving the Virial theorem

Consider the expectation in the canonical ensemble defined by $$\left\langle x_i\frac{\partial \mathcal{H}}{\partial x_j} \right\rangle=\frac{1}{Z}\int d\Gamma x_i\frac{\partial ...
0
votes
1answer
61 views

Where does this hyperbolic tangent in Nakahara's text come from?

I don't see why the term with $\tanh$ appears in the equation 1.164 The textbook is the second edition of Geometry, Topology and Physics
0
votes
1answer
145 views

How do I find the partition functions for the Saha equation for elements that are complex like Argon?

The question I have is with regards to the partition function needed for solving the Saha equation for Argon. Basically the part I'm confused with is the part of the formula where $g_i/g_a$, where ...
0
votes
1answer
111 views

Relation between 1D and 3D partition function

In a solid state physics text author said $$Z_{3D} = [ Z_{1D} ]^{3} $$ $$<E_{3D}>=3<E_{1D}>$$ Where $Z$ is partition function. Can anyone convince me why it is so?
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4answers
2k views

The unreasonable effectiveness of the partition function

In a first course on statistical mechanics the partition function is normally introduced as the normalisation for the probability of a particle being in a particular energy level. ...
0
votes
1answer
60 views

Internal energy from a canonical partition function

How to derive this relation, though it looks simple in eyes $$U=-\frac{\partial ln Q}{\partial \beta}$$ where Q is a canonical partition function and $\beta=\frac{1}{K_BT}$
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0answers
44 views

Given the Pair Correlation Functions for a Multi-component Fluid, is There a Simple Way to Obtain the Helmholtz Free Energy?

I think it may not be possible. Given all the pair correlation functions (e.g. calculated from Ornstein Zernike theory), it seems possible to obtain the internal energy (assuming different species ...
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0answers
62 views

Ising Model with All Spins Interacting with All Other Spins

I am studying the Ising model with all spins interacting with all other spins and have formulated $Z$. I am trying to understand what it means to study at large N but not infinite N. I know that at ...
2
votes
1answer
209 views

Expansion of Onsager's Exact Partition Function for 2D Ising Model

We have a question where we are given the exact expression for the 2D Ising model partition function: $$\frac{1}{N}\ln Z ~=~ \ln(2 \cosh^2(\beta J)) $$$$+ ...
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0answers
62 views

manipulations with SU(N) Nekrasov partition function

Think of a Young tableau $R$ as collection of rows $y_1 \geq ... \geq y_d > y_{d+1}=0$ and all others zero, with $\ell(Y):= \sum_j y_j$ and for a box $s=(i,j)\in R$ we have $a_Y(s):=y_i-j$ and ...
0
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1answer
102 views

Heat capacity $C$ at low temperature

The internal energy, $U = Nk_bT$ where $N$ is particle number, $k_b$ is Boltzmann constant and $T$ is temperature. Therefore, the heat capacity $C$ is given by $C=\frac{dU}{dT}=k_b$. However, in ...