In physics, an operator is almost always either a square matrix or a linear mapping from one space of functions (often on $\mathbb{R}^N$ or $\mathbb{C}^N$) to the same or other like space of functions. Operators serve as *observables* and as *time evolution operators* in Quantum Mechanics. This tag ...

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Why does replacing bra and ket basis vectors by their row and column representations give the wrong matrix representation in a non-orthogonal basis?

I have a Hermitian operator (for a 2D Hilbert space) given by $$H=|\psi\rangle \langle \psi|+|\phi\rangle \langle \phi|$$ where $|\psi\rangle$ and $|\phi\rangle$ are normalized but not necessarily ...
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Why is the electric field operator normalized by a volume?

I came across the following definition of the electric field operator: But I am not sure what this $V$, the "volume of a box", is about. It seems to enter the discussion in order to have standing ...
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Expectation of momentum in the bound state

Is it logically correct to assert that the expectation of the momentum $$\langle \hat p \rangle=0$$ for any bound state because it is bound to some finite region? What is the physical interpretation ...
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How does Dirac define the representative of $\{\langle\phi\frac{d}{dq}\}\psi\rangle = \langle\phi\{\frac{d}{dq}\psi\rangle\}$

On pate 89 of Dirac's book, The Principles of Quantum Mechanics, he writes: Let us treat the linear operator $\frac{d}{dq}$ according to the general theory of linear operators of section 7. We ...
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How do I prove that the del squared operator commutes with the angular momentum operator? [closed]

I need to prove in Cartesian coordinates that $[\nabla^{2},\hat{L_{z}}]= 0$ I know that the angular momentum operator is defined as: $\hat{L_{z}}=x\hat{p_{y}}-y\hat{p_{x}}$ And the del squared is ...
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Hamiltonian acting on sum operator

I am following a derivation in a book. It is implementing a state $|{\psi}\rangle$ into the eigenvalue equation $\hat{H}|{\psi}\rangle=E|{\psi}\rangle$. The $|{\psi}\rangle$ term contains a ...
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44 views

Ballentine's proof of (one half of) Stone's theorem

Reading Ballentine's "Quantum Mechanics; A Modern Development" I got stuck on his really short proof of what I think is Stone's theorem. On page 65 (paperback, reprint of 2008) he writes about about a ...
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210 views

Kraus operator rank

All quantum operations $\mathcal{E}$ on a system of Hilbert space dimension $\mathcal{d}$ can be generated by an operator-sum representation containing at most $\mathcal{d^2}$ elements. Extending ...
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$p^4$ in radial coordinates not Hermitian

Griffiths' quantum textbook claims in question 6.15 that "$p^2$ is Hermitian, but $p^4$ is not, for hydrogen states with $l=0$." First off, I am puzzled at his use of terminology. An operator is ...
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80 views

Translation Operators

Show that if the wave function $\langle x|\psi\rangle$ is modified by a position-dependent phase $\langle x|\psi\rangle \to e^{\frac{ip_ox}{\hbar}}\langle x|\psi\rangle$ then $\langle x\rangle ...
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Translation Operator

Let $|\psi\rangle \to |\psi'\rangle = \hat{T}(\delta x)|\psi\rangle$ for infinitesimal $\delta x.$ Show that $\langle x \rangle' = \langle x \rangle + \delta x$ and $\langle p_x \rangle' = \langle ...
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Evolution operator for time-dependent Hamiltonian

When I studied QM I'm only working with time independent Hamiltonians. In this case the unitary evolution operator has the form $$\hat{U}=e^{-\frac{i}{\hbar}Ht}$$ that follows from this equation $$ ...
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Anticommutator difference [closed]

What is the value of this difference of anticommutators $$\{x^2,p^2\}-(\{x,p\}^2)/2$$ if the commutator $$[x,p]=i\hbar ~?$$ I have tried and obtained a value $$-3\hbar^2/2 - 2i\hbar px.$$ But ...
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Prove that $e^{\frac{i\lambda}{\hbar} S_x}S_ze^{-\frac{i\lambda}{\hbar}S_x}=S_z\cos(\lambda)+S_y\sin(\lambda)$ [closed]

Prove using Hadamard's lemma that $$e^{\frac{i\lambda}{\hbar} S_x}S_ze^{-\frac{i\lambda}{\hbar}S_x}=S_z\cos(\lambda)+S_y\sin(\lambda) $$ where $\lambda$ is a complex number. I get: ...
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Prove that $(e^{i\lambda A})^\dagger=e^{-i\lambda A^\dagger}$ [closed]

Prove $$(e^{i\lambda A})^\dagger=e^{-i\lambda A^\dagger}$$ where $A$ is an operator. Can anyone explain how to go about this question? Writing it as a power series gets confusing. So basically I ...
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How to calculate the expectation value of position/momentum using path integrals?

We have the formula: \begin{equation} \langle F \rangle = \frac{\int Dx \times F[\phi] exp\{i/\hbar S[\phi]\}}{\int Dx \times exp\{i/\hbar S[\phi]\}} \end{equation} Now, I am wondering how a change ...
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The equivalence between Heisenberg and Schroedinger pictures

In quantum mechanics, the two pictures of Schroedinger and Heisenberg are taken as equivalent, where in the former wavefunctions are time variants and operators are not, and in the latter it is the ...
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How to calculate the expectation value of position vector?

$$\psi (\vec{x})=Ae^{-(1/4a^2)|\vec{x}-\vec{x}_0|^2}e^{i\vec{p}_0\cdot \vec{x}/\hbar}$$ The wave function is like this, then how is the expectation value of position vector (not position) calculated? ...
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What is the Hermitian adjoint of operator $\hat{K}\psi = \psi^*$?

For many operators, their adjoint can be expressed as a function of other known operators, for example $$\hat{T}_a^\dagger = \hat{T}_{-a} \\ \hat{p}_x^\dagger = \hat{p}_x$$ where $\hat{T}_a \psi (x) = ...
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Adjoint of momentum operator

In position basis, we have, $$\langle x \mid \hat p \mid \Psi(t) \rangle = -\imath \hbar \frac{\partial{\langle x \mid \Psi(t) \rangle}}{\partial{x}} $$ Now I know $\hat{p}$ is a Hermitian operator ...
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How to pull out the momentum operator?

In the equation (1.7.17), how does operator $p$ get out of the bracket without any operation though $<a | $, $| x'>$ are function of $x'$? How to prove this?
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Understanding the Quantum Vacuum State [duplicate]

In terms of the creation and annihilation operators $a_{j}$ and $a_{j}^{\dagger}$ (fermionic or bosonic, doesn't matter): Is the vacuum state $\mid\mathrm{vacuum}\rangle$ exactly the zero vector on ...
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Binomial expansion of non-commutative operators

I would like to determine the general expansion of $(A+B)^n$, where $[A,B]\neq0$, i.e. A and B are two generally no-commutative operators. How could I express this in terms of summations of the ...
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Calculating $\langle x | \hat{x} | p \rangle$ in $p$ basis

I am trying to calculate $\langle x\ |\ \hat{x}\ |\ p\rangle$. I can work in the $x$-basis like so: $$\langle x\ |\ \hat{x}\ |\ p\rangle=\int dx'\langle x\ |\ \hat{x}\ |\ x'\rangle\langle x'\ |\ ...
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How does the momentum operator act on state kets?

I have been going through some problems in Sakurai's Modern QM and at one point have to calculate $\langle \alpha|\hat{p}|\alpha\rangle$ where all we know about the state $|\alpha\rangle$ is that ...
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53 views

Total angular momentum operator

How do the eigenfunctions of the total angular momentum operator analytically look like? I mean the operator is given by $J = L+S$ so the eigenfunctions have to be tensor-product states, right? Can ...
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43 views

Apply Hamiltonian to position eigenstates

Let $\hat{H}$ be the free Hamilton operator, is it then true that $$\langle {\bf r}| \hat{H} ~=~ - \frac{\hbar^2}{2m} \Delta \langle {\bf r}|~?$$ Where $\Delta\equiv \nabla^2$. I currently don't see ...
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Intuitive meaning of the exponential form of an unitary operator in Quantum Mechanics

I'm an undergraduate student in Chemistry currently studying quantum mechanics and I have a problem with unitary transformations. Here in my book, it is stated that Every unitary operator ...
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Prove that this operator is unitary

$\hat{O}\equiv(1/\sqrt{2\pi})\int e^{-iNz}dz$ $\hat{O}^\dagger\equiv(1/\sqrt{2\pi})\int e^{iN'x}dx$ We have the operator $\hat{O}$ and its Hermitian adjoint $\hat{O}^\dagger$, in the one dimensional ...
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Can someone clarify what should and should not be an operator in my verification of the 1D solution to the SE for a free particle?

I just worked out the 1D free particle solution to the Schrödinger equation. My wave function was \begin{equation} \psi(x,t) = Ae^{i(px-Et)/\hbar} \end{equation} So I plugged this into both sides ...
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Simultaneous eigenket

J. J. Sakurai states in his "Modern Quantum Mechanics", this fact as a theorem ($\pi$ is the parity operator): Suppose $$[H,\pi]=0$$ and $| n>$ is a nondegenerate eigenket of $H$ with ...
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Help understanding proof in simultaneous diagonalization

The proof is from Principles of Quantum Mechanics by Shankar. The theorem is: If $\Omega$ and $\Lambda$ are two commuting Hermitian operators, there exists (at least) a basis of common eigenvectors ...
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Unitary operator algebra and multiplying by identity

If $\hat{H}$ is Hermitian, with eigenvalues $a_k$, then $$\hat{H} = \sum_k a_k \left|\psi_k\right> \left<\psi_k\right|.$$ I read that it then follows that $$\begin{align*} e^{i\hat{H}} = ...
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Probability of getting a particular spin

I'm a beginner in quantum mechanics, and I'm a bit confused about states and the probability to measure certain values. I would like to understand at least the following simplified situation: ...
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Fundamental Commutation Relations in Quantum Mechanics

I am trying to compile a list of fundamental commutation relations involving position, linear momentum, total angular momentum, orbital angular momentum, and spin angular momentum. Here is what I have ...
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Commutator between square position and square momentum [duplicate]

I need (as a part of one exercise) to find commutator between $\hat{x}^2$ and $\hat{p}^2$ and my derivation goes as follows: $$[\hat{x}^2,\hat{p}^2]\psi = [\hat{x}^2\hat{p}^2 - ...
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How to tackle 'dot' product for spin matrices

I read a textbook today on quantum mechanics regarding the Pauli spin matrices for two particles, it gives the Hamiltonian as $$ H = \alpha[\sigma_z^1 + \sigma_z^2] + ...
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Computing $\langle0|T[Q(t_2)Q(t_1)]|0\rangle$

Given Hamiltonian $H=\frac{P^2}{2}+\frac{\omega^2}{2}Q^2$, compute $\langle0|T[Q(t_2)Q(t_1)]|0\rangle$, where $T$ is the time-ordering of the product, $|0\rangle$ is the ground state. Now set ...
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Why are the spin operators defined as they are?

$$\begin{align*}S_z &= \frac{\hbar}{2} \left(\left|+\right>\left<+\right| - \left|-\right>\left<-\right|\right)\\ S_y &= i\frac{\hbar}{2} \left(\left|-\right>\left<+\right| - ...
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65 views

Problem with momentum operator

Why is there no problem with the eigenfunction of the momentum operator being non-normalisable? How can it be a valid quantum state?
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RH side of the Uncertainty principle: when is it a number and when an expectation value?

The uncertainty principle between the position $x$ and the momentum $p$ is given by: $$ \sigma_x \sigma_p \geq \hbar/2,$$ whereas for the $x$ and $y$ components of the angular momentum is given by: ...
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Is the Hilbert space spanned by both bound and continuous hydrogen atom eigenfunctions?

As e.g. Griffiths says (p. 103, Introduction to Quantum Mechanics, 2nd ed.), if a spectrum of a linear operator is continuous, the eigenfunctions are not normalizable, therefore it has no ...
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Product on Tensor Products

I'm trying to understand how products on tensor products work. For instance, in quantum mechanics, you have ($x$ tensor $y$) times ($z$ tensor $a$), where $x$, $y$, $z$, $a$ are all operators acting ...
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Why we cannot describe operator for force $F$ in quantum mechanics?

In quantum mechanics we describe operators corresponding to momentum but we don't define operator for force what is the reason behind it?
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91 views

How much information does the Hamiltonian contain in quantum mechanics? [closed]

Given a Hamiltonian, let's say of a many-body system, through the Schrodinger equation,in principle we can find the eigenfunctions and their corresponding eigenvalues (spectrum). Now given an ...
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How are anyons possible?

If $|ψ\rangle$ is the state of a system of two indistinguishable particles, then we have an exchange operator $P$ which switches the states of the two particles. Since the two particles are ...
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60 views

How to find creation and annihilation operators? [duplicate]

I get confused when trying to find this. Please describe it as simply as possible, but keep in mind I have no budget whatsoever to pay for textbooks, so here goes: How do you find the creation and ...
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70 views

Why are the charge operator $Q$ and the baryon number operator $B$ unbounded?

A friend recommended me to read PCT, Spin and Statistics, and All That written by R. F. Streater and A. S. Wightman. In page 5 to 6, here's what the authors of this book have to say: [...] In ...
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Show that a function takes the following form using the definition for the function of an operator

If $f(z)$ is a function with a Taylor series expansion $$f(z)=\sum _{ n=0 }^{ \infty }{c_n z^n },$$ then we define $$f(M)=\sum _{ n=0 }^{ \infty }{c_n M^n }.$$ First consider ...