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1answer
27 views

Equilibrium when it shouldn't be?

I'm doing an experiment that requires me to balance a ring, tied to four strings, in the middle of a force table; in other words, the objective is to set the ring at equilibrium. Each string is ...
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1answer
29 views

Chemical reaction A+B$\leftrightarrow$C. Equilibrium VS Non Equilibrium

Could you please confirm or say why I am wrong? Let us consider the steady state of the chemical reaction $A+B \leftrightarrow^{k_+}_{k_-} C$, with $k_+$ and $k_-$ the forward and backward rates. ...
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0answers
37 views

What is the use of Schwinger-Keldysh formalism?

In non-equilibrium statistical mechanics, there is this formidable formalism, called the Schwinger-Keldysh formalism. I have read about it, and I understand what it is. However, what I what to know ...
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0answers
9 views

how far away from stable equilibrium is sys+res master equation valid?

just wondering how reliable the standard development of system+reservoir master equation model is from equilibrium. Thanks!
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0answers
35 views

Is the system in equilibrium?

If the time derivative of the Liapunov functional related to free energy of my system is zero, can I say my system is in chemical equilibrium?
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0answers
26 views

Fano factor in conductance

A generalized conductance formula has been found in 1992 by Meir and Weingreen. This formula is available for any systems form by two lead coupled to an interactive region. With some assumptions we ...
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0answers
36 views

Validity of topological thermodynamics?

I've been reading some material by R. Kiehn, developing a topological approach to non-equilibrium thermodynamics through Cartan forms, where the fundamental claim is that irreversible processes are ...
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0answers
64 views

Diffusion in a chemical potential gradient

I am having troubles to understand to connection between equilibrium and non equilibrium thermodynamics. I am studying a mixture of molecules $A,B,C$ and solvent $S$. The free energy $F$ is given by ...
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0answers
34 views

Boltzmann equation (Number density)

I'm trying to understand the Boltzmann equations use in the early Universe. The derivation is somewhat tedious, but in the end I end up with: $$a^{-3}\frac{d}{dt}\left(n_1a^3\right) = ...
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0answers
28 views

Examples of systems with linear response behavior

I've checking the linear response theory and there are 3 fundamental assumptions. 1) Linearity of the response of the system to an external excitation, 2) Stationary response function: ...
1
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1answer
61 views

Defintion of temperature without thermal equilibrium condition

Is temperature only defined in thermal equilibrium? Then how can we explain heat flow by temperature differences?
0
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1answer
105 views

Applying Euler Homogenous Function Theorem to $df$ or $f$

I am currently reading Demirel's Nonequilibrium Thermodynamics in order to learn more about entropy and nonequlibrium thermodynamics However I and stumped on how the author's do the following step: ...
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0answers
34 views

intervalley optical phonon scattering

Is there any difference between modeling of intravalley and intervalley optical phonon scattering in solid?
1
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1answer
98 views

How to prove the Bose enhancement factor $(1+f)$ and the Pauli blocking factor $(1-f)$ in Boltzmann equation?

For the collision integral in the Boltzmann equation for particles obeying different statistic, the factor is 1 for classical particles , 1-f for fermions, 1+f for Boson. While why it's exactly this ...
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2answers
85 views

How stable are Benard Cells when the thermal gradient begins decreasing?

I've found lots of information on the formation of Benard Cells and convection currents but very little information about what happens to the self-organized structures when the energy gradient being ...
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0answers
35 views

Modeling the creation of transverse waves

Suppose I hang one end of a jump rope against a wall and start waving the other end. I'm interested in knowing the behavior of the jump rope as it starts generating waves. In other words, how can I ...
3
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1answer
102 views

Definition of entropy in nonequilibrium states

Thermodynamical definition of entropy $$S(p)=-\int p\ln p~dx$$ is defined only on equilibrium system. But why can't we use it for non-equilibrium system? Is there a well-accepted definition for it?
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2answers
179 views

What are the contributions of the Non-equilibrium Thermodynamics?

I am very interested in Thermodynamics, but though it is easy to find good books and information about classical thermo, it seems that is not the same for non-equilibrium thermodynamics. I would like ...
4
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3answers
329 views

Is Fourier's law of conduction a consequence of the second principle?

In classical thermodynamics courses, entropy is often motivated by the need to justify that heat flows from high temperatures zones to lower temperatures zones: this is seen as a consequence of ...
3
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2answers
100 views

What materials are used in non thermal plasma?

While reading about non-thermal plasmas, I came across their ionization potentials(~1%), and other capabilities, such as their non Maxwellian energy distributions. At what temperatures, and pressures ...
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2answers
139 views

How quickly should a fluid come to hydrostatic equilibrium?

Let's say I'm holding a one-liter water bottle, full of water, which I then drop. Before dropping the water bottle, the equilibrium is for there to be a pressure gradient in the water canceling the ...
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0answers
113 views

Langreth rules and Keldysh formalism

I am trying to confirm the proof of Langreth's theorem / rules as seen in http://www.iue.tuwien.ac.at/phd/pourfath/node52.html . My problem is equation 3.55. I would do it like this: $\int_{C_{1}} ...
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0answers
177 views

Fluctuations in energy for macro and micro canonical ensembles

I was thinking about fluctuations in energy for a system in thermal equilibrium. I think that the Boltzmann distribution itself has an standard deviation approximately equal to the mean, as it is ...
2
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1answer
78 views

what does “an average over noise” mean in Zwanzig's book

This is a very specific question about Robert Zwanzig's book Nonequilibrium Statistical Mechanics. Specifically, what is he talking about in equation 1.25 on page 10 that he calls "an average over ...
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1answer
81 views

Steady state average of physical quantities

Consider the following Hamiltonian: $$ H = \sum_n \left[\dfrac{p_n^2}{2m_n} + U(x_l) + V(x_{l+1} - x_l) \right], $$ that corresponds to a 1-D system of particles with nearest-neighbor interactions ...
1
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1answer
372 views

The choice of pivot point in non-equilibrium scenarios

It is true that under equilibrium condition, no matter what pivot point one choose, the resulting net torque will always be zero. I wonder if this principle apply to non-equilibrium scenarios as well, ...
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0answers
75 views

Derivation of the Landauer formula for phonons using Nonequilibrium Green's functions

I am currently trying to understand this paper: http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.96.255503 I really like their derivation of the Landauer formula for phonons using ...
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1answer
275 views

Are they the same thing: Wigner distribution in quantum Boltzmann equation and Wigner function in quantum optics?

We know that quantum Boltzmann equation (QBE) is an equation of motion for the interacting Green's function $G^<(\vec{x}_1,t_1;\vec{x}_2,t_2)\equiv\mathrm{i}\langle ...
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1answer
277 views

Understanding collision terms in Boltzmann equation

I am reading a paper that deals with the Boltzmann equation. They add a collision which is supposed to account for collisions which happen when particles are within a radius of $d$ from each other. ...
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2answers
140 views

Non-Equilibrium Statistical Mechanics

Can anybody please explain what is the difference between equilibrium state and steady state, as quoted by book by Degroot and Mazur. Also, does violation of Principle of Detailed Balance means the ...
7
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1answer
503 views

``What is life?'' by a physicist definition [closed]

The question is about defining ``What is life?'' in the field of Physics. Whether there is any (insightful) way of defining ``What is life?'' from physicists. There are pioneer works, including ...
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1answer
121 views

Surface Area Relative to Element Distribution

We tend to find heavier elements like iron and others toward the center of celestial bodies. Lighter elements like carbon, hydrogen, and oxygen are almost always towards the surface. That makes ...
2
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1answer
177 views

Mathematical form of chemical potential difference and entropy production

I'm trying to understand the form of the 'force' which drives chemical reactions, ie. the difference in chemical potential, also sometimes called the 'affinity'. $$\Delta \mu = - kT ln ...
1
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1answer
73 views

Nonequilibrium themal QFT

Wick rotation to thermal of QFT in Minkowski space to thermal QFT, which is after this transformation analogue to statistical mechanics, does only describe equilibrium statistical mechanics. On page ...
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0answers
72 views

Is there a systematic way to determine the relevant variables needed to describe a nonequilibrium system?

In strong nonequilirium, the statistical operator describing the system depends on an infinite number of variables (BBGKY-hierarchy), contains information about all the previous states starting from ...
2
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1answer
285 views

Non-equilibrium Green functions

How do we use non-equilibrium Green's functions (NEGF) or the Keldysh formalism in the theory of quantum transport? Please take a simple example like the Hopping model with a non-equilibrium ...
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0answers
283 views

Kubo formalism application

Suppose I have some pertubative Hamiltonian on the Hubbard Hamiltonian and I want to calculate the change in current in linear response using the Kubo formalism. Now the kind of perturbative ...
3
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1answer
178 views

when is coherent state a good approximation?

Consider a Hamiltonian of a system coupled to a bath. Let $H_{sys}=\nu c^{\dagger}c$ ; $H_{env}=\Sigma \omega_r a^{\dagger}a$ ; $H_{int}=\Sigma (g_r ac^{\dagger}+g_r^* ca^{\dagger})$. Then it is ...
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1answer
446 views

The Bhatnagar-Gross-Krook (BGK) approximation of the collision integral

Bhatnagar, Gross and Krook (BGK) proposed a relaxation term for the collision integral $ Q$ as follows $$J = \frac{1}{\tau} (f^{eq} - f)$$ where $f^{eq}$ is the distribution at equilibrium. $Q$ has ...
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3answers
108 views

Consistent application of Microscopic evolution with the definition of Macrostates?

How does one use the concept of microstate evolution and definition of macrostate in a consistent manner. As my understanding goes the thermodynamic concepts are defined in equilibrium. How does one ...
2
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2answers
90 views

What is the derivation for the exponential energy relation and where does it apply?

Very often when people state a relaxation time $\tau_\text{kin-kin}, \tau_\text{rot-kin}$,, etc. they think of a context where the energy relaxation goes as $\propto\text e^{-t/\tau}$. Related is an ...
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2answers
452 views

Pumping water from a closed column. Will the column get empty or just circualte?

As a picture is worth a thousand words, here is my problem: It is a closed water column with a bit of air in the top section. If I run the pump and make the water flow from IN to OUT, Will the ...
6
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1answer
851 views

Maximum Principle vs. Minimum Principle in Non-equilibrium Thermodynamics

Prigogine's Min. principle states that in steady-state non-equilibrium systems the entropy generation rate is at a minimum, i.e., a system will seek a steady-state that has min entropy generation. ...
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0answers
46 views

Any new texts directly on second law of thermodynamics? [duplicate]

Possible Duplicate: Recommendations for Statistical Mechanics book Is anyone aware of any recent text that summarises the research and arguments on second law of thermodynamics and also on ...
2
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2answers
276 views

Phase volume contraction in dissipative systems

I am confused about phase-volume contraction in dissipative systems. Please help me catch the flaw in my understanding. From a macroscopic point of view I understand that a dynamic system tends to go ...
4
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1answer
583 views

Relating the variance of the current operator to measurements

(EDIT: Thanks to Nathaniel's comments, I have altered the question to reflect the bits that I am still confused about.) This is a general conceptual question, but for definiteness' sake, imagine a ...
3
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1answer
934 views

What is non-thermal plasma?

I read about non-thermal plasma, but I still have some questions: The ions and neutral particles are not in thermal equilibrium with the electron, does that mean that the overall temperature is low ...
4
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5answers
2k views

Does high entropy means low symmetry?

According to Bogolubov postulate (various texts name it differently) in Non-equilibrium thermodynamics, the number of needed parameters to describe our system is decreasing with time, and finally at ...
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3answers
1k views

What are some of the best books on complex systems?

I'm rather interested in getting my feet wet at the interface of complex systems and emergence. Can anybody give me references to some good books on these topics? I'm looking for very introductory ...
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2answers
451 views

State-dependent diffusions: Fick's law vs. Fokker-Planck's, which and why?

Consider a "state-dependent diffusion": a diffusion process for which the diffusion coefficient $D(x)$ depends on the (stochastic) state $x$ of the system. (An example is provided by the diffusion of ...