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2
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1answer
140 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? Otherwise, what is the difference between them? My question is not about the solids, but I ...
0
votes
0answers
11 views

Forces from molecular potential energy surface

Let's assume we cannot use Hellmann-Feyman theorem and we wish to calculate the forces on molecules' atoms at arbitrary configuration only from its potential energy. My question is how many different ...
0
votes
1answer
55 views

Are lighter molecules in the air more affected by earth gravity?

Or: Why are raindrops falling? In vacuum a heavy (big mass) object is attracted by gravity with the same speed as a light object as shown on the moon with the hamer and the feather. But on earth ...
-1
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0answers
27 views

Carbon dioxide oscillations along main axis ---TRICKY PROBLEM— [closed]

I'm completely new to physics.stackexchange.com. I would like to try this kind of service. I have received a problem from my professor which sounds like this : "Carbon dioxide molecule in ...
5
votes
3answers
390 views

Extra vibrational mode in linear molecule

When calculating the number of vibrational modes for a molecule, the formulas differ for linear $(n = 3N - 5)$ and non-linear $(n = 3N - 6)$ molecules, where $n$ is number of modes and $N$ is number ...
2
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1answer
2k views

Finding the approximate distance between molecules in a gas

I have a problem to understand why the below derivation can be used to find the distance between molecules: This example is an approximation. We are supposed to find the average distance between the ...
1
vote
1answer
339 views

Why is the orbital angular momentum of a pi electron along the axis of two atoms' molecule one?

I'm reading quantum chemistry. The book says that the orbital angular momentum of a $\pi$ electron along the symmetry axis of a molecule made up of two atoms is $\pm 1$. I think this is a primary ...
0
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2answers
120 views
3
votes
1answer
523 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
-1
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2answers
38 views

Motion of molecules of an ideal gas

Why does an ideal gas show only translatory motion and not vibratory motion?
0
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2answers
415 views

Resonate frequency of an object?

Below is a paragraph taken from the web site, physicsclassroom.com: It is often useful to think of these electrons as being attached to the atoms by springs. The electrons and their attached ...
2
votes
1answer
162 views

Para and ortho hydrogen angular momentum values

In Wikipedia, it is said that: Orthohydrogen, with symmetric nuclear spin functions, can only have rotational wavefunctions that are antisymmetric with respect to permutation of the two protons. ...
1
vote
1answer
149 views

Do solids have translational energy?

Along with having vibrational energy, do both crystalline and amorphous solids also have translational energy? I ask because I've always understood solids to have just vibrational motion/energy. But ...
3
votes
1answer
155 views

induction of van der Waals forces

Is there a way to maximize van der Waals forces between two materials, by electrifying one material, thus creating dipoles/instantaneous dipoles and thus creating stronger van der Waals forces? has ...
5
votes
0answers
49 views

What is the max frequency of sound in a given medium?

When talking about acoustic waves, medium continuity (pressure, density) is implicit. But can the wavelength of an acoustic wave be as small as intermolecular separation? For example, can ~10 THz ...
1
vote
1answer
840 views

Bimolecular recombination in few words

I'm making a short seminar about VERY broad topic of fullerenes in photovoltaics, but I'd like it to be educational (not just full of words hard to audience to make them think I'm smart). In one of ...
0
votes
1answer
15 views

Methods to ioniz air molecules

What are other alternatives ways to ionize air molecules, except the electric field charging and the use of the so-called corona discharge?
2
votes
0answers
39 views

Plasmon quenching vs plasmon decay. What is the difference?

I'm reading an article "Quenching, Plasmonic, and Radiative Decays in Nanogap Emitting Devices" (pubs.acs.org/journal/apchd5). I don't understand the following: Counterintuitively, we evidence ...
3
votes
2answers
49 views

Creasing of a material at the molecular level

What exactly happens when a material (particularly paper or even cloth or a metal) is folded to form a crease? Why is it that a creased material tends to retain form, while a lightly folded one, '...
5
votes
5answers
797 views

Why is quantum physics needed to explain photosynthesis?

Why is quantum physics needed to explain photosynthesis? In what aspect does the corresponding classical theories for photosynthesis fail?
3
votes
1answer
106 views

Finding Electronic Energy Levels by Representation Theory

Let $$u=\left( \begin{array}{cccc} c_1&c_2&c_3&c_4 \end{array} \right)^T$$ for $$\psi = c_1\psi_1 + c_2\psi_2 + c_3\psi_3+ c_4\psi_4$$ We assume that $\left<\psi_i|\psi_j\right> = \...
0
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0answers
16 views

Average Rate of Evaporation of Water

Consider a container of volume $V$ and cross sectional area (exposed to another fluid, say air) $SA$. The container is at constant temperature $T$, and contains $N$ molecules of water, where $N$ is ...
0
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2answers
2k views

Thermal Velocity

What is thermal velocity? What is it's physical significance? Wikipedia says: The thermal velocity or thermal speed is a typical velocity of the thermal motion of particles which make up a gas, ...
0
votes
2answers
58 views

Do homonuclear diatomic molecules interact with infrared light?

A molecule will appear on IR spectra if its dipole moment changes during vibration. Due to symmetry, the dipole moment of homonuclear diatomic molecules ($\mathrm{H_2, N_2, O_2, F_2, \dots}$) is zero. ...
3
votes
0answers
38 views

If 2 fermionic atoms form a molecule, will the molecule always behave as a boson?

2 fermionic atoms give a bosonic molecule. 2 bosonic atoms form a bosonic molecule. Is there a energy scale where these two molecules will behave differently? If yes, will it depend on the ...
1
vote
1answer
57 views

Any Antimolecule so far?

As i've been reading on Wikipedia, we are artificially able to join an antiproton with a positron to form an antihydrogen. But if i search for antimolecule, i can't find any results on that, only a ...
0
votes
1answer
32 views

Neutron scattering off molecules

From neutron scattering off molecules it is possible to get information about molecules' geometry. Given the size of a particular molecule, what are the criteria for choosing the wavelengh of the ...
0
votes
1answer
73 views

Can two different objects or system of molecules have different temperatures, but having same internal kinetic energy?

If I take an extreme case, where a body has only an internal potential energy with zero internal kinetic energy, does this body have a temperature? Another question related to it: if two objects A and ...
5
votes
3answers
285 views

What is the difference between the shapes of molecules with different isotopes

I'll explain my question on example of water molecule. Let us have three water molecules: normal water $H_2 O$, heavy water $D_2 O$ and semiheavy water $HDO$. Is there any difference between the ...
3
votes
0answers
135 views

Is the translational information all that matters, or do we need to take into account internal states?

For anyone in this community that's familiar with quantum teleportation, I need desperate help. I am currently working on my senior thesis and my goal is to teleport a molecule. Background: So in ...
0
votes
1answer
51 views

Atomic number of $\rm CO_2$? [closed]

I have to calculate the Bethe-Bloch equation for a $\rm CO_2$ absorber, I know this is a stupid question, but is Atomic number additive? Or do I need to do something a little more complex? I was ...
1
vote
3answers
595 views

Sound as a use to separate molecular structures

Sound can be a destructive force. However, could it be used to separate say the Hydrogen atom from the Oxygen atoms?
1
vote
0answers
28 views

Why do very small balls attached to a tiny spring propel themselves in hardly moving fluids? [duplicate]

I recall watching a youtube video about a ball with a spring on the idea propelling themselves through stable fluids without any assistance, even if we make sure the spring isn't moving in the ...
6
votes
0answers
100 views

How do proteins perform their function? [closed]

Let's, for example, take a ribosome. It is an enzyme that is in turn just a molecule that must follow the laws of physics. Correct me if I'm wrong, but it can be looked upon as a molecular machine ...
6
votes
3answers
8k views

What is the resonant frequency of liquid water?

I learned it's not 2.45 GHz. But what is it, then? In my failure to find the real value, I'm starting to wonder: does it even make sense talking about a resonant frequency of water molecules?
1
vote
1answer
31 views

Does less heat equals more reflexion? [duplicate]

Does colder metal reflect more if hotter metal reflect less? Why?
0
votes
1answer
46 views

can odorous VOCs be removed by an ionizing air purifier? [closed]

I am considering replacing my IQAir HealthPro 250 air purifier by an Electrolux EAP300. According to the marketers, the EAP300 has PlasmaWave(TM) technology that supposedly removes odours from the air ...
0
votes
0answers
35 views

how can VOC filters work given that atmosphere has 1800 ppb methane?

I have an IQAir HealthPro 250 air purifier that has a 2.5 kg activated charcoal volatile organic compound (VOC) filter. According to the manufacturer, the replacement interval is from 12 to 24 months. ...
0
votes
3answers
186 views

Why is alcohol less dense than water?

Ethyl alcohol (ethanol) is less dense than water, and it's boiling point is lower. But this molecule is more complex and bigger than the simple H2O. How can a substance with a higher molecular size ...
2
votes
0answers
39 views

Why is CO a good tracer for H2? How are those molecules correlated?

One always reads and hears that CO is a good tracer for H2. How are they correlated? How can you deduce from the (measurable) CO the amount of the (unmeasurable) H2 in the ISM?
-2
votes
2answers
129 views

Can $CO_2$ be separated into $C$ and $ O_2$?

I'm doing a little bit of research for an experiment that I want to conduct in science and it relies on that one question. So, Is it possible to separate a $CO_2$ molecule into a $C$ and $O_2$? ...
3
votes
1answer
65 views

How do molecules absorb heat?

How do molecules absorb and retain heat, and how is that heat able to still affect nearby molecules? On Venus there is a green-house effect where the large, dense Carbon-Dioxide atmosphere absorbs ...
4
votes
2answers
111 views

Mountains and their local effects on Earth's gravity

I was once a truck driver and can feel the inertia and kinetic energy on heavy loads while traveling. While climbing mountains in the Rockies I noticed gravity was different on the side of the ...
0
votes
1answer
58 views

Atoms Inside a Lightning Bolt

What happens to atoms trapped in lightning? Why do electrons not split an atom but can change them inside the bolt? Can atoms travel on a bolt?
0
votes
1answer
74 views

How to determine rotational energy of gas molecules

For an arbitrary polyatomic molecular gas, what is the expected behavior of $U_{rot}(T)$, the rotational kinetic energy of the atoms, in the two limits T high and T low? So far, I have written an ...
0
votes
1answer
52 views

How can I determine the vector parallel to the long molecular axis?

I have a molecule in a system (the molecule is not in the center) with determined coordinates of all atoms. One of my molecule is on the picture below What I need is to determine the vector that ...
2
votes
2answers
51 views

When dihydrogen is formed, are photons being emitted?

When a hydrogen in an excited state transits back to the ground state, a photon (or series of photons) is emitted in accordance with the selection rules. When two free hydrogen atoms in the ground ...
1
vote
1answer
69 views

Is (or why isn't) static charge as lethal as ionizing radiation?

Ionizing radiation, e.g. the "stuff" emitted by radioactive materials, is dangerous to humans since changes to the electron configurations (in the human body) causes the various molecules (in the ...
0
votes
3answers
66 views

Splitting molecule

The photon reacts with the binding electrons orbiting the two atoms. The photons have the 'correct' wavelength for Bond Dissociation Energy (BDE). 'Splitting' the molecule involves applying the ...