The tag has no wiki summary.

learn more… | top users | synonyms

2
votes
2answers
71 views

To what fraction of the speed-of-light has any multi-atom molecule (or polyatomic ion) been accelerated?

Of course photons go $c$ in a vacuum, and seems there's data on electrons getting to $0.999999999976c$ and protons to $0.99999912c$. For the twins paradox to be plausible, one of the twins must ...
-4
votes
0answers
18 views

Book recommendation for atomic & molecular physics

What are some wonderful books about modern physics for a sophomore undergrad to learn atomic & molecular physics? Some easygoing books for a start up would go well.
0
votes
1answer
95 views

Unknown magnetic moment of orthohydrogen

Conforming to present atomic physics, the two elementary particles in hydrogen atoms can have either parallel or antiparallel magnetic moments, and the energy differences between these two kinds of ...
0
votes
0answers
22 views

Is it possible to get the (Pauli) repulsive term in the Lennard-Jones potential from theoretical considerations?

Title says it: Is it possible to get the form of the (Pauli) repulsive term in the Lennard-Jones potential from theoretical considerations, or is it purely found experimentally through fits?
0
votes
0answers
28 views

What exactly is cutting with a knife will look like on the atomic scale? [duplicate]

Some times I like to view the world in the microscopic scale .ie. at this level all objects any thing will be collection of atoms which we normally don't view with our naked eye. At that scale I ...
0
votes
0answers
66 views

In every glass of water there are water molecules that came through Hitler's urinary bladder? [closed]

I was told that in every glass of water there are water molecules that came through Hitler's urinary bladder. How much it is true probabilistically?
1
vote
0answers
19 views

Why is the potential minimum of a molecule shifted towards greater nucleii separation for excited electron states?

I know it has to do with symmetry of the wave function, but I am having trouble piecing it all together. For a positive H ion we have a symmetric wave function $\psi_{+}$, which base functions ...
1
vote
1answer
203 views

Why is the orbital angular momentum of a pi electron along the axis of two atoms' molecule one?

I'm reading quantum chemistry. The book says that the orbital angular momentum of a $\pi$ electron along the symmetry axis of a molecule made up of two atoms is $\pm 1$. I think this is a primary ...
66
votes
5answers
14k views

What does it mean for two objects to “touch”?

If you've ever been annoyingly poked by a geek, you might be familiar with the semi-nerdy obnoxious response of "I'm not actually touching you! The electrons in the atoms of my skin are just ...
2
votes
1answer
183 views

How fast do molecules move in objects?

I guess it depends on the heat or the type of the material but can you give some examples or formulas to calculate it ? The best example would be the average speed of the air molecules (all types in ...
13
votes
2answers
818 views

Why is the bottom part of a candle flame blue?

What’s the explanation behind the bottom part of a candle flame being blue? I googled hard in vain. I read this. I don’t understand how it’s explained by the emission of excited molecular radicals in ...
3
votes
3answers
137 views

How to understand this symmetry in the wavefunctions of a diatomic molecule?

In Wikipedia (and elsewhere), a particular symmetry of the quantum system of a diatomic molecule is mentioned: symmetry under reflection along a plane containing the internuclear axis. The ...
1
vote
1answer
165 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
1
vote
1answer
105 views

Thermionic emission, delayed emission and predissociation

In molecular photodissociation, the thermionic emission, delayed emission and predissociation are the same? Otherwise, what is the difference between them? My question is not about the solids, but I ...
0
votes
2answers
52 views

Relation between sound waves and air molecules

The following was written in my book When sound waves travel in air, air molecules do not move. When wind blows,air molecules move. This produces variation in velocity of sound waves. The first ...
8
votes
4answers
651 views

Hot water freezing faster than cold water

This question has puzzled me for a long time. There is already a question like this on Physics.SE. John's answer to the question seems quite satisfying. But when I googled the cause I found this and ...
1
vote
1answer
36 views

Why does the surface structure of a metal make it hydrophobic?

I was just reading this article from phys.org describing water-repellant surfaces. However the article doesn't go into enough details of explaining why a particular structure repels the water. Can ...
1
vote
0answers
28 views

Bond Angle in a water molecule

I recently started up reaching up on the Feynman lectures on Physics and in Vol I,Chap 1-2,Feynman states that the bond angle between the hydrogen and oxygen atom is 105° 3′. I know that the bond ...
1
vote
1answer
3k views

What's the size of carbon dioxide? [closed]

My question is very simple. How big is a carbon dioxide ($\mathrm{CO}_2$) molecule, i.e. the width, length and height of it?
0
votes
0answers
10 views

Why molecules in this potential have a common average distance $r_m$ to their neighbors?

A commonly used potential describing intermolecular interactions in liquids and real gases is the so-called Lennard-Jones potential. In this model the interaction of atoms and molecules with each ...
0
votes
1answer
26 views

What is “Lifetime Intensity” in photoluminescence?

I'm reading an article "Surface plasmon enhanced Förster resonance energy transfer between the CdTe quantum dots". Link The reasearchers are writing about increase in "lifetime intensity" and even ...
4
votes
2answers
172 views

What methods exist to calculate the density of states in the continuum of a molecule?

Say I have an arbitrary molecule in the Born-Oppenheimer approximation, and furthermore say that I can approximate the molecule as having only one active electron. What methods exist to calculate the ...
3
votes
2answers
133 views

What is the difference between the shapes of molecules with different isotopes

I'll explain my question on example of water molecule. Let us have three water molecules: normal water $H_2 O$, heavy water $D_2 O$ and semiheavy water $HDO$. Is there any difference between the ...
2
votes
0answers
111 views

Para and ortho hydrogen angular momentum values

In Wikipedia, it is said that: Orthohydrogen, with symmetric nuclear spin functions, can only have rotational wavefunctions that are antisymmetric with respect to permutation of the two protons. ...
1
vote
1answer
34 views

Vibrationing molecules/atoms and the effect

If the molecules/atoms of a solid object vibrate quickly enough, would the way a human eye perceives that object be changed? Would the object appear to "flicker" or have almost a transparent look to ...
7
votes
2answers
691 views

The distance between touching objects

What is the distance between, say, a cup of coffee and the table it rests on? What is the distance between two touching hands?
107
votes
3answers
9k views

How does a knife cut things at the atomic level?

As the title says. It is common sense that sharp things cut, but how do they work at the atomical level?
-1
votes
4answers
454 views

What forces are at play when molecules wiggle (due to heat)?

What forces are at play when molecules wiggle (due to heat)? Or in other words, What makes them move?
5
votes
4answers
2k views

Water in vacuum (or space) and temperature in space

So, water in vacuum will boil first and then freeze. I don't know how the freeze happens. As pressure lowers to zero, what happened to freezing point? (I know heat taken by vapor, and the water cool ...
1
vote
0answers
77 views

Why is graphene the only (stable) 2D sheet structure? [duplicate]

I know that Carbon molecules can form different structures depending on how they bond with each other: graphite, diamond, graphene and fullerene. As far as I understand, graphene is just a "sheet" of ...
1
vote
1answer
85 views

How many wavefunctions are in a minimal basis set for benzene?

I am reading Modern Quantum Chemistry by Szabo and Ostlund and on page 62 he says "A minimal basis set for benzene consists of 72 spin orbitals." I tried to understand this number but failed. ...
1
vote
0answers
35 views

Books on collision probability and collision processes

Are there any books specifically on collision processes between atoms and molecules and collision probability? I would like to get an overview of the factors that determine collision probability ...
1
vote
2answers
64 views

Photon striking a molecule and getting reflected

I am writing a simple simulator which simulate absorption of UV light in solution. The idea is to see if I can see Beer-Lambert laws in my model. It is not intended to be a precise simulator but ...
2
votes
0answers
112 views

Is the translational information all that matters, or do we need to take into account internal states?

For anyone in this community that's familiar with quantum teleportation, I need desperate help. I am currently working on my senior thesis and my goal is to teleport a molecule. Background: So in ...
1
vote
0answers
69 views

XCrysDen Structure file [closed]

Does anyone know how to directly convert a .cif file to a Xcryden structure file(.xsf) ? I know how to extract the lattice vectors and the atom positions from a .cif file, but don't whether the .cif ...
0
votes
1answer
195 views

Thermal Velocity

What is thermal velocity? What is it's physical significance? Wikipedia says: The thermal velocity or thermal speed is a typical velocity of the thermal motion of particles which make up a gas, ...
0
votes
0answers
47 views

matrix elements of the electronic molecular Hamiltonian between a hartree product and a Slater determinant

This may belong in Chemistry, but I thought I might try my luck here first. In Szabo's book, an exercise requires a proof that = (N!)^(1/2) * given that |K(HP)> is the Hartree product wave ...
3
votes
1answer
104 views

Measuring Atomic Radius of a Noble Gas

How exactly can you measure the atomic radius of a noble gas such as Neon or Helium accurately? Would liquefaction help? I also heard that the aforementioned gases are the only common elements which ...
0
votes
0answers
17 views

Why photoelectron imaging is a 'complete' measurement?

In many articles and books, it says that photoelectron imaging gives a 'complete' information. What is mean by 'complete' measurement or a 'complete' information? Through photoelectron imaging ...
1
vote
2answers
53 views

What is is a molecular/microscopic explanation for why a balloon rises in water?

If we consider a balloon full of air submerged in water then we all know that it will rise rapidly. I am having trouble understanding this at the level of individual molecules of air and water. What ...
5
votes
4answers
624 views

Why is quantum physics needed to explain photosynthesis?

Why is quantum physics needed to explain photosynthesis? In what aspect does the corresponding classical theories for photosynthesis fail?
1
vote
0answers
29 views

Covalent Bonds, Varities and Limits!

Related:http://chemistry.stackexchange.com/q/9459/ I was wondering, covalent bonds tend to share two electrons, apparently rarely more than three, and normally between two electrons. Can someone give ...
3
votes
0answers
86 views

What is a covalent bond?

What is a covalent bond, quantum mechanically? How does it hold the two atoms together, and at one point can you qualify the electron as being shated between two atoms, versus feeling attractive ...
0
votes
0answers
20 views

Dipole and multipole bound state anions: Do these bound electrons behave exactly like conventional electrons in the molecular orbitals?

Recently, I read about dipole and multipole bound anions. Dipole bound anions are those, if I understood correctly, when an electron is attached electrostatically on a neutral molecule which is polar. ...
0
votes
1answer
39 views

Air vs. Water attraction of Oxygen Molecules

The air we breathe is made up of nitrogen and oxygen gases. The water in a pond is made of a single hydrogen/oxygen molecule. If it wasn't for the surface tension on top of the water, oxygen molecules ...
0
votes
4answers
454 views

Is vapour pressure based on partial pressures or just total pressure on the liquid?

The explanation for the boiling point of water is that at 100C, the vapour pressure becomes greater than atmospheric pressure. But say you had a a jar of water sealed in argon at 1atm, which is larger ...
9
votes
4answers
407 views

Can we detect whether food has previously been heated in a microwave oven?

An acquaintance told me that she refuses to eat microwaved food because she read that the microwave changes the molecules of the food somehow. Her statement is vague and her sources are dubious but I ...
0
votes
1answer
97 views

Why are diodes able to amplify signals in groups, but not alone?

Single diodes can determine whether a signal passes or not (depending on the biased)(plus they can even rectify a signal), yet why does it take a combination of diodes(like a transistor) to amplify a ...
0
votes
0answers
83 views

Creep of materials at atomic/molecular level under stresses

Do the viscoelastic materials creep at the same rate under three types of fundamental stresses, viz.- TENSION, COMPRESSION and SHEAR??? My intuition tells me that the answer is no. But, I can't get ...
0
votes
0answers
23 views

Are there examples of “loss-less” Forster Resonance Energy Transfer (FRET)?

When I think of a Forster Resonance Energy Transfer (FRET) process, I typically imagine the initial excitation of an absorbing chromophore with a photon followed by the subsequent emission of a lower ...