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2
votes
2answers
241 views

What's the difference between two Hydrogen atoms?

If we are given two Hydrogen atoms, would the only difference between them would be their quantum state (Energy level or eigen value, and the corresponding Orbital or eigen state) and their location ...
6
votes
1answer
305 views

Gas kinetic representation of trans-critical conditions

From a molecular point of view, can we think of the super-critical conditions as conditions where T and p are large enough that the collisions of gas molecules are frequent and powerful enough to ...
2
votes
1answer
451 views

Theoretical treatment of Hydrogen bond?

I would like to understand how the Hydrogen bond can be described through the Schroedinger equation. I don't need numerical methods that one uses them to simulate it, rather I need its treatment from ...
7
votes
1answer
190 views

Are Born-Oppenheimer energies analytic functions of nuclear positions?

I am looking for references to bibliography that explores the smoothness and analyticity of eigenvalues and eigenfunctions (and matrix elements in general) of a hamiltonian that depends on some ...
1
vote
1answer
59 views

Rotation of diatomic homonuclear molecule

I know that the rotation energy of a diatomic homonuclear molecule is $E_{Rot}=\frac{\hbar J(J+1)}{R^2 M}$. Does the axis of rotation depend on $J$? With respect to which axis does the molecule for ...
-2
votes
3answers
321 views

What forces are at play when molecules wiggle (due to heat)?

What forces are at play when molecules wiggle (due to heat)? Or in other words, What makes them move?
5
votes
1answer
574 views

How the bond angle of a water molecule is measured?

How the angle of a water molecule is measured? The bond angle for water was first determined by vibrational and rotational analysis of its infrared absorption spectra. How is bond angle extracted?
2
votes
0answers
105 views

Is the translational information all that matters, or do we need to take into account internal states?

For anyone in this community that's familiar with quantum teleportation, I need desperate help. I am currently working on my senior thesis and my goal is to teleport a molecule. Background: So in ...
6
votes
1answer
1k views

What happens when you shake a can of soda?

Of course the CO2 comes out of the liquid, and it will even build up a lot of pressure if needed. The question is what happens at a molecular level to cause it to leave the liquid?
2
votes
2answers
278 views

Origin of Electromagnetic Interactions between Molecules

What is the origin of electromagnetic interaction between molecules? Anyway, it should have some relation with atoms. Also, These electromagnetic interactions are playing a major role in different ...
3
votes
2answers
120 views

Time-dependence in LCAO

I would like to study time-dependence (TD) in linear combinations of atomic orbitals (LCAO). The Hückel method enables quick and dirty determination of MOs for suitable systems (view link for ...
-5
votes
1answer
695 views

Lennard-Jones potential - equilibrium [closed]

If I have Lennard-Jones potential, how can I calculate equilibrium? $$ U(r)=\epsilon \left ( \left (\frac{r_m}{r} \right )^{12}-2 \left (\frac{r_m}{r}\right )^6 \right ) \ $$
2
votes
1answer
129 views

If the temperature of 2 materials are the same does that mean the molecules are vibrating at the same speed?

Pretty much what the title says. My base question is this. Assuming I take a piece of steel, and a piece of PVC plastic and I measure both their temperatures and find they are the same. I then take a ...
8
votes
3answers
316 views

What is the microscopic picture for warm air rising?

The usual explanation for warm fluids rising past cooler ones is that the warmer fluid has a lower density. I'm trying to understand what this looks like at a molecular scale. The density seems to ...
1
vote
1answer
161 views

Why does a coulomb explosion induce fusion?

If you strip the valence electrons apart with a very short intense electromagnetic field the remaining core explodes in a so called coulomb explosion. But experiments have shown that under certain ...
54
votes
5answers
9k views

What does it mean for two objects to “touch”?

If you've ever been annoyingly poked by a geek, you might be familiar with the semi-nerdy obnoxious response of "I'm not actually touching you! The electrons in the atoms of my skin are just ...
0
votes
1answer
2k views

what's the size of carbon dioxide [closed]

First of all, I'm not good at English, so if you guys can use simple English it will help. My question is very simple. How big is a carbon dioxide ($\mathrm{CO}_2$) molecule, i.e. the width, length ...
3
votes
1answer
126 views

Experiment to find structure of water

Who first determined the structure of water (two hydrogen atoms stuck to an oxygen atom at approx 105 degrees), and, more importantly, how was this done?
3
votes
3answers
486 views

Why is quantum physics needed to explain photosynthesis?

Why is quantum physics needed to explain photosynthesis? In what aspect does the corresponding classical theories for photosynthesis fail?
2
votes
1answer
4k views

Why is oxygen in a triplet state and what are the consequences?

From Wikipedia here and here: ''Almost all molecules encountered in daily life exist in a singlet state, but molecular oxygen is an exception.'' ''The unusual electron configuration prevents ...
4
votes
3answers
586 views

Is photon emission possible without electrons changing energy levels?

Does molecular vibrational transition and consequent emission of infrared radiation involve electrons changing energy level? In wikipedia, about vibronic transitions it says "Most processes leading to ...
0
votes
1answer
424 views

Vibrational motion of linear diatomic molecule

This question concerns the following exercise from an old exam: The vibrational motion of a linear diatomic molecule can be approximated as simple harmonic motion. A CO molecule has a bond ...
3
votes
3answers
2k views

Does stirring water in a bucket in whirlpool keeps it warm?

I did an experiment when I was a teenager. I want to prove/see what really went on in that experiment. When taking a bath, take a warm water in bucket and start taking a bath. You will notice that ...
1
vote
2answers
229 views

Subshell notation for hydrogen cation?

Looking at $s$,$p$,$d$ configuration for atoms & ions: Since a hydrogen cation $H^+$ has no electron, how would the subshell notation be written? My best estimate would be $1s^0$.
2
votes
2answers
105 views

What are some molecules stable in outer space that are unstable under terrestrial conditions?

What are some molecules stable in outer space that are unstable under terrestrial conditions? So there are many molecules that violently react on Earth because they're too charged, have unfilled ...
9
votes
4answers
1k views

Does it exist a free good molecule / atom simulation software?

I'm looking for a software or software package (for example C/C++) that can simulate a lot (say thousands at least) of molecules in action (ie. in movement or attached to say static walls). I have ...