The tag has no wiki summary.

learn more… | top users | synonyms

7
votes
2answers
595 views

The distance between touching objects

What is the distance between, say, a cup of coffee and the table it rests on? What is the distance between two touching hands?
2
votes
2answers
82 views

What is the difference between the shapes of molecules with different isotopes

I'll explain my question on example of water molecule. Let us have three water molecules: normal water $H_2 O$, heavy water $D_2 O$ and semiheavy water $HDO$. Is there any difference between the ...
1
vote
0answers
69 views

Why is graphene the only (stable) 2D sheet structure? [duplicate]

I know that Carbon molecules can form different structures depending on how they bond with each other: graphite, diamond, graphene and fullerene. As far as I understand, graphene is just a "sheet" of ...
4
votes
1answer
114 views

What methods exist to calculate the density of states in the continuum of a molecule?

Say I have an arbitrary molecule in the Born-Oppenheimer approximation, and furthermore say that I can approximate the molecule as having only one active electron. What methods exist to calculate the ...
1
vote
1answer
62 views

How many wavefunctions are in a minimal basis set for benzene?

I am reading Modern Quantum Chemistry by Szabo and Ostlund and on page 62 he says "A minimal basis set for benzene consists of 72 spin orbitals." I tried to understand this number but failed. ...
95
votes
3answers
7k views

How does a knife cut things at the atomic level?

As the title says. It is common sense that sharp things cut, but how do they work at the atomical level?
1
vote
0answers
29 views

Books on collision probability and collision processes

Are there any books specifically on collision processes between atoms and molecules and collision probability? I would like to get an overview of the factors that determine collision probability ...
1
vote
1answer
19 views

Vibrationing molecules/atoms and the effect

If the molecules/atoms of a solid object vibrate quickly enough, would the way a human eye perceives that object be changed? Would the object appear to "flicker" or have almost a transparent look to ...
1
vote
2answers
56 views

Photon striking a molecule and getting reflected

I am writing a simple simulator which simulate absorption of UV light in solution. The idea is to see if I can see Beer-Lambert laws in my model. It is not intended to be a precise simulator but ...
1
vote
1answer
74 views

Wigner Threshold law in Photodetachment and Photoionization

I am writing this question here because I have a problem in understanding the Wigner Threshold law in Photodetachment and Photoionization. The Wigner Threshold Law is given by: $\sigma$=$E^{L+1/2}$. ...
1
vote
0answers
38 views

XCrysDen Structure file [closed]

Does anyone know how to directly convert a .cif file to a Xcryden structure file(.xsf) ? I know how to extract the lattice vectors and the atom positions from a .cif file, but don't whether the .cif ...
0
votes
1answer
52 views

Thermal Velocity

What is thermal velocity? What is it's physical significance? Wikipedia says: The thermal velocity or thermal speed is a typical velocity of the thermal motion of particles which make up a gas, ...
2
votes
1answer
56 views

How fast do molecules move in objects?

I guess it depends on the heat or the type of the material but can you give some examples or formulas to calculate it ? The best example would be the average speed of the air molecules (all types in ...
0
votes
0answers
31 views

matrix elements of the electronic molecular Hamiltonian between a hartree product and a Slater determinant

This may belong in Chemistry, but I thought I might try my luck here first. In Szabo's book, an exercise requires a proof that = (N!)^(1/2) * given that |K(HP)> is the Hartree product wave ...
3
votes
1answer
62 views

Measuring Atomic Radius of a Noble Gas

How exactly can you measure the atomic radius of a noble gas such as Neon or Helium accurately? Would liquefaction help? I also heard that the aforementioned gases are the only common elements which ...
7
votes
3answers
452 views

Hot water freezing faster than cold water

This question has puzzled me for a long time. There is already a question like this on Physics.SE. John's answer to the question seems quite satisfying. But when I googled the cause I found this and ...
0
votes
0answers
15 views

Why photoelectron imaging is a 'complete' measurement?

In many articles and books, it says that photoelectron imaging gives a 'complete' information. What is mean by 'complete' measurement or a 'complete' information? Through photoelectron imaging ...
1
vote
2answers
53 views

What is is a molecular/microscopic explanation for why a balloon rises in water?

If we consider a balloon full of air submerged in water then we all know that it will rise rapidly. I am having trouble understanding this at the level of individual molecules of air and water. What ...
3
votes
0answers
79 views

What is a covalent bond?

What is a covalent bond, quantum mechanically? How does it hold the two atoms together, and at one point can you qualify the electron as being shated between two atoms, versus feeling attractive ...
1
vote
0answers
29 views

Covalent Bonds, Varities and Limits!

Related:http://chemistry.stackexchange.com/q/9459/ I was wondering, covalent bonds tend to share two electrons, apparently rarely more than three, and normally between two electrons. Can someone give ...
0
votes
0answers
14 views

Dipole and multipole bound state anions: Do these bound electrons behave exactly like conventional electrons in the molecular orbitals?

Recently, I read about dipole and multipole bound anions. Dipole bound anions are those, if I understood correctly, when an electron is attached electrostatically on a neutral molecule which is polar. ...
0
votes
1answer
30 views

Air vs. Water attraction of Oxygen Molecules

The air we breathe is made up of nitrogen and oxygen gases. The water in a pond is made of a single hydrogen/oxygen molecule. If it wasn't for the surface tension on top of the water, oxygen molecules ...
0
votes
1answer
73 views

Why are diodes able to amplify signals in groups, but not alone?

Single diodes can determine whether a signal passes or not (depending on the biased)(plus they can even rectify a signal), yet why does it take a combination of diodes(like a transistor) to amplify a ...
0
votes
0answers
59 views

Creep of materials at atomic/molecular level under stresses

Do the viscoelastic materials creep at the same rate under three types of fundamental stresses, viz.- TENSION, COMPRESSION and SHEAR??? My intuition tells me that the answer is no. But, I can't get ...
0
votes
0answers
16 views

Are there examples of “loss-less” Forster Resonance Energy Transfer (FRET)?

When I think of a Forster Resonance Energy Transfer (FRET) process, I typically imagine the initial excitation of an absorbing chromophore with a photon followed by the subsequent emission of a lower ...
3
votes
1answer
73 views

Using the fine structure constant to measure atomic and molecular sizes

This is kind of a coursework question but it bring up some really interesting things about the fine structure constant $\alpha$ so I wanted to post it to not only make sure I understood something but ...
1
vote
0answers
112 views

Why and how will the string break?

While i was searching on the identity discussed earlier that is $$1 + 2 + 3 + 4 + 5 + ... = -\frac{1}{12}$$ I found a similar identity applied to physics concept. It started by arranging long ...
2
votes
3answers
387 views

Is the molecule of hot water heavier than that of cold water?

We know that the molecule of hot water($H_2O$) has more energy than that of cold water (temperature = energy) and according to Einstein relation $E=mc^2$ ,this extra energy of the hot molecule has a ...
0
votes
2answers
75 views

Molecular mean free path probability

Let's let $p(\xi)$ be the probability a molecule travels at least $\xi$ between collisions, lets say $\xi=0.01$. When I think of this statement, I think it it is the probability the molecule is able ...
0
votes
0answers
67 views

Saddle point and transition state of a molecule

During a transition of a molecule from one state to another, it pass through a transition state. This transition state, mathematically speaking, is a saddle point. That means, the second derivative ...
1
vote
1answer
137 views

Why is the orbital angular momentum of a pi electron along the axis of two atoms' molecule one?

I'm reading quantum chemistry. The book says that the orbital angular momentum of a $\pi$ electron along the symmetry axis of a molecule made up of two atoms is $\pm 1$. I think this is a primary ...
9
votes
4answers
348 views

Can we detect whether food has previously been heated in a microwave oven?

An acquaintance told me that she refuses to eat microwaved food because she read that the microwave changes the molecules of the food somehow. Her statement is vague and her sources are dubious but I ...
1
vote
2answers
104 views

Sound as a use to separate molecular structures

Sound can be a destructive force. However, could it be used to separate say the Hydrogen atom from the Oxygen atoms?
2
votes
1answer
39 views

Having nano-scale holes in metal, possible today?

I am considering to design a gas filtering system that is based on the size of gas molecules. Basic idea is to flow mixed gas in a long pipe, and to allow CO2 to get of pipe through nano-size holes ...
0
votes
4answers
218 views

Is vapour pressure based on partial pressures or just total pressure on the liquid?

The explanation for the boiling point of water is that at 100C, the vapour pressure becomes greater than atmospheric pressure. But say you had a a jar of water sealed in argon at 1atm, which is larger ...
0
votes
2answers
60 views

Molecules of a solid [closed]

Question: Molecules of a solid : (a) are always in a state of motion (b) move only when heated (c) move because they are loosely bound (d) do not move at all My attempt: I ...
1
vote
2answers
58 views

Molecules and electrons energy types

What are the types of energy that an atom or a molecule could have? For example they have kinetic energy, could they also have other types?
0
votes
2answers
84 views

Is the potential energy of molecules related to its temperature? [duplicate]

Do ideal gases have a certain potential energy at a certain temperature?
0
votes
0answers
36 views

Difficult to visualize Franck-Condon overlap

The franc condon principle says about the vertical transitions, means the coordinates of the nuclei remains unchanged during an electronic transition. But, what is the physical meaning or how to ...
5
votes
4answers
465 views

Water in vacuum (or space) and temperature in space

So, water in vacuum will boil first and then freeze. I don't know how the freeze happens. As pressure lowers to zero, what happened to freezing point? (I know heat taken by vapor, and the water cool ...
0
votes
3answers
214 views

Potential energy curve for intermolecular distance

I'm trying to understand this curve better, but I can't quite figure out what "negative potential energy" means. The graph should describe a molecule oscillating between $A$ and $B$, however where ...
-1
votes
1answer
79 views

What is opposite of electric field?

A negatively charged molecule will generate a field, an electric field, and it will repel all negative ions. So what does positively charged molecule generates that causes other positive molecules ...
3
votes
2answers
279 views

How to determine what an object is composed of?

Heads up: This question has never been asked (here) before the way I will ask it here, so let's shed some light on it a bit. Prelude and anecdote(can be skipped): The other day I was walking home, ...
1
vote
1answer
36 views

Molecular formula of a compund [closed]

I have no idea on how to get information out of this one. A compound contains only hydrogen and nitrogen. Nitrogen makes up for 87.4% of the mass. A sample of this have a density of 0.977 g/L at ...
0
votes
1answer
183 views

Are valence electrons in nonpolar molecules localized/delocalized?

Are valence electrons in non-polar molecules localized or delocalized? I'm quite confused about the whole electron localization and delocalization business. I'd love a simplified explanation that a ...
1
vote
5answers
344 views

What laws (formulas) govern forces between atoms?

What laws (formulas) govern the fundamental forces of nature? For example, gravity is governed by the inverse-square law. I am thinking about how particles attract each other, but also repel. All ...
2
votes
1answer
209 views

If the source of sound is vibration, why can't we “hear” a object whose molecules are vibrating?

According to our physics textbook, the source of sound is vibration. According to our chemistry textbook, substances in solid state have molecules vibrating in a fixed position. So why can't I hear my ...
4
votes
2answers
109 views

Why is it energetically favourable for molecular bonds to form from a QM point of view?

For example, if you have two hydrogen atoms and an oxygen atom, they are all electrically neutral and don't attract each other. But then if they manage to get "close enough" somehow they snap together ...
3
votes
1answer
90 views

Relative weights in rotational bands of symmetric diatomic molecules

In an old paper, Ehrenfest 1931, the introduction starts off as follows: The band spectra of symmetric diatomic molecules show certain striking differences from those of asymmetric molecules. For ...
1
vote
1answer
69 views

Difference between photo electron spectrum and photoelectron angular distribution

I am trying to learn the Photoelectron velocity map imaging. While I was going through the article "Chem. Soc. Rev., 2009,38,2169-2177", it is said that the "photoelectron spectrum reflects the energy ...