0
votes
0answers
30 views

matrix elements of the electronic molecular Hamiltonian between a hartree product and a Slater determinant

This may belong in Chemistry, but I thought I might try my luck here first. In Szabo's book, an exercise requires a proof that = (N!)^(1/2) * given that |K(HP)> is the Hartree product wave ...
1
vote
1answer
119 views

Matrix elements of the operator $\hat{x} \hat{p}$ in position and momentum basis

I want to calculate the matrix elements of the operator $\hat{x} \hat{p}$ in momentum and position basis, that is the two quantities ($p,q$ - momenta, $x,y$ - positions): $$\langle p|\hat{x} ...
4
votes
1answer
146 views

How are matrices used to represent quantities, and what is the meaning of a matrix?

So I'm reading this text on Quantum Mechanics, and it goes through a few chapters that I understand fairly well including probability. But then it says that all quantities, like position and energy ...
0
votes
0answers
84 views

Matrix element of an operator

Suppose we want to calculate the following matrix element. $$ \langle \alpha |\hat{o}|\beta\rangle $$ Where $\alpha$ and $\beta$ are two arbitrary basis states in a many-particle basis set, and ...
0
votes
0answers
61 views

How do I find the unitary operator for a combined system?

I want to describe the interaction between a target and a probe and know that this is described by some unitary operator that acts on both systems. My operator needs to implement a $\pi/q$ rotation ...
3
votes
3answers
658 views

When Eigenfunctions/Wavefunctions are real?

When the Hamiltonian is Hermitian(i,e. beyond the effective mass approximation), generally under which conditions the eigenfunctions/wavefunctions are real? What happens in 1D case like the finite ...
1
vote
2answers
200 views

What is the correct arrangement of the elements of Pauli matrices?

I'm dealing with angular momentum, or particularly spin, on my quantum mechanics course; I guess the Pauli matrices thing is a more general one, but I'd like to illustrate my doubt with them (maybe ...
3
votes
4answers
811 views

Is the momentum operator well-defined in the basis of standing waves?

Suppose I want to describe an arbitrary state of a quantum particle in a box of side $L$. The relevant eigenmodes are those of standing waves, namely $$ \left<x|n\right>=\sqrt{\frac{2}{L}}\cdot ...
3
votes
2answers
248 views

How to express continuous values as a matrix

Usually a quantity of a matrix is defined as the eigenvalues of the matrix. If so, how can anyone express continuous values, as in Schrodinger picture, into a matrix?
6
votes
2answers
2k views

Matrix Representations of Quantum States and Hamiltonians

I am a high school student trying to teach himself quantum mechanics just for fun, and I am a bit confused. As a fun test of my programming/quantum mechanics skill, I decided to create a computer ...
4
votes
1answer
236 views

Creation and Annialation Operators and Kinetic Energy Matrix Elements

I'd like to write equations for $c_{ij}(t)$, With a hamiltonian of the form $$H=\sum_{kn}a^{\dagger}_k t_{kn}a_n + \frac{1}{2}\sum_{klmn}a^{\dagger}_k a^{\dagger}_l v_{klmn}a_m a_n$$ with $t_{kn}$ ...
2
votes
3answers
272 views

Vector space of $\mathbb{C}^4$ and its basis, the Pauli matrices

How do I write an arbitrary $2\times 2$ matrix as a linear combination of the three Pauli Matrices and the $2\times 2$ unit matrix? Any example for the same might help ?