# Tagged Questions

991 views

### How do we know that heat is a differential form?

In thermodynamics, the first law can be written in differential form as $$dU = \delta Q - \delta W$$ Here, $dU$ is the differential $1$-form of the internal energy but $\delta Q$ and $\delta W$ are ...
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### Separation of variables in various PDEs, physical meaning

The method of separation of variables produces an undetermined separation constant and a family of solutions indexed by the values of this constant. For instance, in the case of an infinitely long ...
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### Can Lee-Yang zeros theorem account for triple point phase transition?

Now the prominent Lee-Yang theorem (or Physical Review 87, 410, 1952) has almost bocome standard ingredient of any comprehensive statistical mechanics textbook. If the volume tends to infinity, ...
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### Thermalisation - Open quantum systems

I would like to understand better a phenomenon of a quantum heat bath. Below I present one example, which seems quite clear to me. It would be great to see some less-discrete models, and more ...
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### What is the meaning of following expresion $C=\frac{\delta Q}{dT}$ mathematicly

Our professor raised the following question during our lecture in Statistical Physics (even so it's related to Thermodynamics): Many text books (even wikipedia) writes wrong expressions (from ...
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### Entropy, flow of informations and fundamental theories

In the hierarchy of theories, first comes hamiltonian theory, from which one deduces kinetics theory, and at last thermodynamics and fluid theories. From a kinetics point of view, entropy and ...
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### Ideal gas with two kinds of particles, Grand canonical partition function

Consider an ideal gas contained in a volume V at temperature T. If all particles are identical the Grand canonical partition function can be calculated using Z_g(V,T,z) := \sum_{N=0}^\infty z^N ...
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### Normal distribution of x, xdot

I have some real measurements from a process and I happened to look at the mutual distribution of (x(t), xdot(t)). I found that they seem to follow 2d normal distribution around (mu, 0). See image, ...
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### Heat equation and Bessel's function [closed]

Could someone please explain why if the time-independent heat equation can, via changing of variables, take the form of Bessel's equation that the $\sqrt\lambda$ should take the values of the zeros of ...
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### The entropic cost of tying knots in polymers

Imagine I take a polymer like polyethylene, of length $L$ with some number of Kuhn lengths $N$, and I tie into into a trefoil knot. What is the difference in entropy between this knotted polymer and ...
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### Proof that Statistical Mechanics is a model of Themodynamics

The laws of thermodynamics are essentially four axioms of a mathematical theory. The expectation values of a statistical ensemble are supposed to satisfy the axioms of thermodynamics (under the ...
Suppose I have a gas of particles that is initially uniformly distributed so that the number density is $n_0$ (number of particles per unit volume), and then I displace the particles by the vector ...