Kinetic theory is part of statistical physics. DO NOT USE THIS TAG for macroscopic [kinematics](http://en.wikipedia.org/wiki/Kinematics). In this case use the tag [tag:kinematics] instead.

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Ideal gas and inelastic collisions

Why is it necessary that all inter-molecular collisions in an ideal gas be elastic? My understanding is that a gas behaves ideally so long as the potential energy arising from inter-molecular ...
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275 views

Momentum change in colisions (Drude Model)

A particle suffers elastic colisions with scattering centers with a probability of colision per unit time $\lambda$. After a colision the particle is in a direction caracterized by a solid angle ...
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Effusion of particles from one box to another - pressure calculation

Suppose we have a container divided into equal halves. Right half is fixed at temperature $T$, volume $\frac{V}{2}$. Initially it has pressure $P_0$, a hole of area $A$ is opened between them. I ...
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Kinetic proof of law of mass action

Suppose we have a chemical reaction of the form $$n_1 A_1 + \cdots + n_r A_r \leftrightarrow m_1 B_1 + \cdots + m_s B_s$$ where $A_i$ and $B_i$ are molecules, and the $n_i$ and $m_i$ are the integer ...
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Speed distribution in 1 dimension

In 3D, the maxwell velocity distribution is: $$f = \left(\frac{\alpha}{\pi} \right)^{\frac{3}{2}} e^{-\alpha v^2} d^3 \vec v$$ To get the speed distribution in 3D, we simply expand $d^3\vec v = 4\pi ...
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Do particle velocities in liquid follow the Maxwell-Boltzmann velocity distribution?

The Maxwell-Boltzmann velocity distribution arises from non-reactive elastic collisions of particles and is usually discussed in the context of the kinetic theory (for gases). There are various ...
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Gillespie's stochastic framework valid for particles in aqueous solution?

Gillespie proposed a stochastic framework for simulating chemical reactions which is predicated on non-reactive elastic collisions serving to 'uniformize' particle position so that the assumption of ...
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Taylor expansion in Lattice Boltzmann Method derivation

Currently I'm trying to understand Lattice Boltzmann Method for solving CFD problems. In its derivation BGK approximation is used to get rid of complicated collision integral. But when they come to ...
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Degrees of freedom of particles in Lattice Boltzmann method

Is it true that in Lattice Boltzmann method particles have only one degree of freedom even in 3D case? Can someone explain that fact or provide a link? Thanks!
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If temperature is average KE per particle, and heat is total KE of all the particles, how can molar heat capacity vary?

If temperature is defined as the average kinetic energy per particle, and heat energy is defined as the total kinetic energy of all the particles (or more strictly, heat transferred is the total ...
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27 views

Kinetic energy of a gas molecule

I am working through the derivation of the equation $$pV=\frac13mNC_{rms}^2,$$ but relating to this formula my textbook states that the kinetic energy of an average molecule of gas is given by ...
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46 views

Relative change in drift velocity

Consider an ensemble of electrons which all experienced a collision at time $t=0$. Let $n(t)$ denote the number of electrons in this ensemble. Assume that the number of electrons $\mathrm{d}n$ from ...
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Is there a known equation for evolution of classical particle probability density?

Suppose we have some very imprecise knowledge of classical particle's coordinates and momentum: what we can only tell is the probability density to find it in some point of phase space. This is ...
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2k views

formula for mean free path in two dimensions

I'm running some simulations of particle collisions in two dimensions with discretised time and space. In essence, particles only collide if they occupy the same location (cell) at the same time step. ...
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Three-body correlation function in kinetic theory

In Kinetic Theory, one studies the evolution of a system of $N$ particles interacting with each other. We use the notation $\boldsymbol{w}_{i}$ to describe the coordinates in phase-space of each ...
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77 views

Calculating elastic energy constant [closed]

I ran into a kinetic physics problem: "A spring is hanging on the ceiling. Let's place an object 'M' at the end of the spring. Yet hold 'M' so the spring doesn't stretch. The distance between the ...
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42 views

Interpretation of Einstein relation in kinetic theory

I am reviewing my (independent) study notes on diffusion and found the following comment preceding the derivation of the Einstein relation: Now, since the particles that deliver the stochastic ...
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38 views

How to approach this kind of task about kinetic energy? [closed]

The bullet with mass $$m_{ball}=0.2 kg$$ travels with speed $$v=2 \frac{m}{s}$$ and hits Plasticine sphere with mass $$m_{sphere}=2.5 kg$$ and get stuck. I need to find the amount of heat ejected. How ...
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Root Mean Square Speed of Gas

The RMS speed of particles in a gas is $v_{rms} = \sqrt{\frac{3RT}{M}}$ where $M$ = molar mass; according to this Wiki entry: http://en.wikipedia.org/wiki/Root-mean-square_speed The gas laws ...
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What information is lost in the symmetrization necessary to derive the BBGKY hierarchy?

The book on Kinetic theory I'm reading derives the BBGKY hierarchy after introducing the reduced distribution functions $f_s(q^1,p_1,q^2,p_2,\dots,q^s,p_s):=\int\ \rho\ \ \mathrm d q^{s+1} \mathrm d ...
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How close together must air molecules be to bounce off one another?

When, say $\text{N}_2$, is in the wild, it regularly collides with other $\text{N}_2$. I assume these collisions happen as, having become sufficiently close, the atomic electrons are repelled from ...
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54 views

Yearly onshore wind turbine energy production [closed]

I am trying to work out the yearly energy production of an onshore Siemens SWT-3.0-101, hub height 94m, total height 144,5. Here is the power curve at each wind speed level worked out through a ...
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Modified Arrhenius equation source? year proposed?

I was curious to know when was the first time (which year) the modified Arrhenius expression was proposed: $k=A(T^n)e^{\frac{-Ea}{RT}}$. I know that the simple Arrhenius equation ...
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Molar heat capacity of gas defined by relation $p=kV$

we have this problem where relation between Pressure($p$) , Volume($V$) is defined by relation $$p=kV$$ where $k$ is a constant and we have to find the molar heat capacity of the gas. Note:Ideal gas ...
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118 views

Ergodicity of the Drude model

The Drude model of electric conduction in solids deals with independent free electrons subject to random collisions with the crystal lattice (the direction where the electrons are scattered after a ...
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243 views

Expression for kinetic energy of gas per molecule

The average kinetic energy (KE) per molecule of a gas is $\frac{3}{2}kT$. While finding this we do $$ \text{ Average KE} =\frac{1}{2} M \frac{1}{N}\sum v^2=\frac{3}{2}kT$$ But why do we not add ...
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How to formally write down the Boltzmann equation?

Can someone write down the Boltzmann equation, not neglecting any of the variables of the involved functions and integrals? Specifically, how to concisely capture the "primed" variables in a sensible ...
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300 views

naive question on Boltzmann equation and conservation laws

The Boltzmann equation in absence of external force reads: $\frac{\partial f}{\partial t} + \vec{v} \cdot \frac{\partial f}{\partial \vec{r}} = \left( \frac{\partial f}{\partial t}\right)_{coll}$ ...
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250 views

Rate of effusion in kinetic molecular theory?

According to the kinetic molecular theory obeying Maxwell-Boltzmann distribution of speeds, the rate of effusion through a pinhole of area $A$ is $$R=\frac{PA}{\sqrt{2\pi M R T}}$$ where $M$ is the ...
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How to deduce E=(3/2)kT?

It says in my course notes that a particle has so-called "kinetic energy" $E=\frac{3}{2}kT=\frac{1}{2}mv^²$ Where does this formula come from? What is k?
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787 views

Heavy vs Light Particle Ideal Gases

Assume there are two ideal gases. The first is made of a light particle, and the second is made of a heavy particle. The two are of the same amount, in the same volume container, and at the same ...
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Why do moving particles emit thermal radiation?

While answering another question about heat in an atom, the discussion in the comments led to the question of how heat is related to thermal radiation picked up by infrared cameras. The answer is that ...
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How to derive the two-term approximation for the Boltzmann equation?

Starting with the Boltzmann equation in terms of $f(t,\vec v,\vec x)$ or $f(t,\vec v)$ http://en.wikipedia.org/wiki/Boltzmann_equation $$\left(\frac{\partial}{\partial t} + \vec{v} \, ...
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Derivation of Pressure/Kinetic Therory problem involving hole in box

A box of volume $V_0$ has a small hole of area $A_0$. The box initially has one mole of an ideal gas at $t = 0$, which is at an initial temperature $T (t = 0)$. Find the rate of energy flow through ...
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188 views

Validity of the Multi-Species Navier-Stokes Equations for real gases

I'm wondering what are the validity limits of Multi-Species Navier-Stokes equations. I'm aware of the limit for rarefied gases. But is there any new limit that arises in the context of real gases? I ...
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Are two thin blankets significantly warmer than a single thick blanket?

Almost every source I can find online maintains that two 0.5 cm blankets are significantly warmer than a single 1cm blanket due to air trapped between the thin blankets. However, the thermal ...
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Question regarding Drift velocity in general?

The derivation of drift velocity in case of electrons is equivalent to the case of an charged ionic gas and therefore all the arguments also apply there. Now for an ideal "ionic" gas which interacts ...
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What physical processes may underly the collisional term in the Boltzmann equation, and how do they increase entropy?

Consider particles interacting only by long-range (inverse square law) forces, either attractive or repulsive. I am comfortable with the idea that their behavior may be described by the collsionless ...
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Integral related to particle diffusion

In the context of particle diffusion, I am trying to understand the equations that describe Brownian motion as a macroscopic process. Assume $N(x,t)$ is a number concentration and $D$ is a diffusion ...
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Photon gas kinetic theory

Suppose a black body as an enclosure of volume $V$ with a hole of section $A$. In the interior there is a photon gas, whose energy density $u$ is, at temperature $T$. $$ u=cT^4$$ How can I show that ...
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Cauchy Problem for Boltzmann Equations

One of the first profound analysis about the solutions of the Boltzmann Equation was given by DiPerna and Lions in the late 1980s. You can find one of their main papers here: ...
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231 views

How does the volume change affect an adiabatic process?

A gas consisting of rigid diatomic molecules was initially under standard conditions. Then the gas was compressed adiabatically, 5 times the original volume. Find the mean KE of rotating molecules ...
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Probability Density Function for Dust in the Colision-less Vlasov equation

My problem is the following: I'm trying to model a dust (pressure-less relativistic gas) in the presence of electromagnetic field using colisioness vlasov-equation (relativistic version of boltzmann ...
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Michaelis-Menten derivation for 2 enzyme substrates

We know that the Michaelis-Menten derivation for the following reaction: $E + S \rightleftharpoons ES \rightarrow E + P$ However, what if the reaction took place in a different scenario whereby: $E ...
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1answer
51 views

Is the diffusion coefficient for a macromolecule sensitive to mass?

Suppose I have two neutrally-buoyant macromolecules diffusing in water. They have the same radius of gyration (i.e. same root-mean-square distance from their center of mass), but one of them is ...
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877 views

Collision frequency at surfaces

Collision frequency for particles in gases is well known, and collision theory is used to derive chemical reaction rates in gases, (and particles in liquid solutions as well). Using the mean velocity ...
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90 views

Influence of choice of statistics on gas kinetics

In the derivation of distributions over energy states, a common assumption made is that under normal conditions (normal from a fluid dynamics standpoint, so > 300K typically) the energy states are ...
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Height of a piston in a heated cylinder containing H2O

I'm a first time user and I hope I won't be too enigmatic asking the following question: I have a cylinder (radius= $6$ $\text{cm}$) with a frictionless piston on top of it and inside $30$ $g$ of ...
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How does evaporation affect the temperature of the air?

A wet object or a volume of water will decrease in temperature due to the effect of evaporation. We understand this to be because of the molecular kinetics, where the faster water molecules escape ...
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375 views

Angular Momentum of Diatomic Molecules

I have run into a problem trying to calculate angular momenta and I wonder if someone can set me straight. I think I know that the lowest order rotational mode should have angular momentum of h, and ...