0
votes
1answer
26 views

Ideal gas and inelastic collisions

Why is it necessary that all inter-molecular collisions in an ideal gas be elastic? My understanding is that a gas behaves ideally so long as the potential energy arising from inter-molecular ...
1
vote
0answers
24 views

Effusion of particles from one box to another - pressure calculation

Suppose we have a container divided into equal halves. Right half is fixed at temperature $T$, volume $\frac{V}{2}$. Initially it has pressure $P_0$, a hole of area $A$ is opened between them. I ...
1
vote
1answer
38 views

Speed distribution in 1 dimension

In 3D, the maxwell velocity distribution is: $$f = \left(\frac{\alpha}{\pi} \right)^{\frac{3}{2}} e^{-\alpha v^2} d^3 \vec v$$ To get the speed distribution in 3D, we simply expand $d^3\vec v = 4\pi ...
3
votes
1answer
93 views

Is there a known equation for evolution of classical particle probability density?

Suppose we have some very imprecise knowledge of classical particle's coordinates and momentum: what we can only tell is the probability density to find it in some point of phase space. This is ...
2
votes
0answers
61 views

Three-body correlation function in kinetic theory

In Kinetic Theory, one studies the evolution of a system of $N$ particles interacting with each other. We use the notation $\boldsymbol{w}_{i}$ to describe the coordinates in phase-space of each ...
4
votes
2answers
156 views

What information is lost in the symmetrization necessary to derive the BBGKY hierarchy?

The book on Kinetic theory I'm reading derives the BBGKY hierarchy after introducing the reduced distribution functions $f_s(q^1,p_1,q^2,p_2,\dots,q^s,p_s):=\int\ \rho\ \ \mathrm d q^{s+1} \mathrm d ...
2
votes
1answer
119 views

Ergodicity of the Drude model

The Drude model of electric conduction in solids deals with independent free electrons subject to random collisions with the crystal lattice (the direction where the electrons are scattered after a ...
1
vote
0answers
86 views

How to formally write down the Boltzmann equation?

Can someone write down the Boltzmann equation, not neglecting any of the variables of the involved functions and integrals? Specifically, how to concisely capture the "primed" variables in a sensible ...
1
vote
2answers
314 views

naive question on Boltzmann equation and conservation laws

The Boltzmann equation in absence of external force reads: $\frac{\partial f}{\partial t} + \vec{v} \cdot \frac{\partial f}{\partial \vec{r}} = \left( \frac{\partial f}{\partial t}\right)_{coll}$ ...
1
vote
1answer
274 views

Rate of effusion in kinetic molecular theory?

According to the kinetic molecular theory obeying Maxwell-Boltzmann distribution of speeds, the rate of effusion through a pinhole of area $A$ is $$R=\frac{PA}{\sqrt{2\pi M R T}}$$ where $M$ is the ...
2
votes
0answers
178 views

How to derive the two-term approximation for the Boltzmann equation?

Starting with the Boltzmann equation in terms of $f(t,\vec v,\vec x)$ or $f(t,\vec v)$ http://en.wikipedia.org/wiki/Boltzmann_equation $$\left(\frac{\partial}{\partial t} + \vec{v} \, ...
0
votes
1answer
133 views

Derivation of Pressure/Kinetic Therory problem involving hole in box

A box of volume $V_0$ has a small hole of area $A_0$. The box initially has one mole of an ideal gas at $t = 0$, which is at an initial temperature $T (t = 0)$. Find the rate of energy flow through ...
4
votes
0answers
100 views

Cauchy Problem for Boltzmann Equations

One of the first profound analysis about the solutions of the Boltzmann Equation was given by DiPerna and Lions in the late 1980s. You can find one of their main papers here: ...
5
votes
2answers
91 views

Influence of choice of statistics on gas kinetics

In the derivation of distributions over energy states, a common assumption made is that under normal conditions (normal from a fluid dynamics standpoint, so > 300K typically) the energy states are ...
3
votes
1answer
140 views

Why is the $\langle v_{x}^{2} \rangle=\frac{1}{3} \langle v^2 \rangle$?

For a randomly moving particle. Or, I suppose that 1/3 could generalise to 1/n, where n is the non rotational degrees of freedom for that particle. Related reference Kinetic Theory of Gasses.
1
vote
1answer
63 views

Pressure change due to fan removing air from a non-airtight room

The following problem occurred to me today: Suppose a $100\mathrm{cfm}$ fan is pushing air out of a large room which is airtight except for a $10 \mathrm{cm}^2$ hole. The air pressure outside the ...
5
votes
2answers
327 views

What physical processes may underly the collisional term in the Boltzmann equation, and how do they increase entropy?

Consider particles interacting only by long-range (inverse square law) forces, either attractive or repulsive. I am comfortable with the idea that their behavior may be described by the collsionless ...
3
votes
4answers
866 views

Accuracy of the Boltzmann equation

I have had this question for some time now. Hopefully someone can answer it. I know that the Boltzmann equation is widely regarded as a cornerstone of statistical mechanics and many applications have ...