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1answer
128 views

Expression for kinetic energy of gas per molecule

The average kinetic energy (KE) per molecule of a gas is $\frac{3}{2}kT$. While finding this we do $$ \text{ Average KE} =\frac{1}{2} M \frac{1}{N}\sum v^2=\frac{3}{2}kT$$ But why do we not add ...
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1answer
194 views

Rate of effusion in kinetic molecular theory?

According to the kinetic molecular theory obeying Maxwell-Boltzmann distribution of speeds, the rate of effusion through a pinhole of area $A$ is $$R=\frac{PA}{\sqrt{2\pi M R T}}$$ where $M$ is the ...
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1answer
534 views

Heavy vs Light Particle Ideal Gases

Assume there are two ideal gases. The first is made of a light particle, and the second is made of a heavy particle. The two are of the same amount, in the same volume container, and at the same ...
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2answers
1k views

Root Mean Square Speed of Gas

The RMS speed of particles in a gas is $v_{rms} = \sqrt{\frac{3RT}{M}}$ where $M$ = molar mass; according to this Wiki entry: http://en.wikipedia.org/wiki/Root-mean-square_speed The gas laws ...
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1answer
69 views

Working out the mean velocity of particles in a gas

I'm trying to answer the following question: Air consists of molecules Oxygen (Molecular mass = 32$amu$) and Nitrogen (Molecular mass = 28$amu$). Calculate the two mean translational kinetic ...
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3answers
9k views

How to deduce E=(3/2)kT?

It says in my course notes that a particle has so-called "kinetic energy" $E=\frac{3}{2}kT=\frac{1}{2}mv^²$ Where does this formula come from? What is k?
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1answer
448 views

Difference in vertical stratification of partial pressure due to gravity

Say you have a mixture of two ideal gases in the presence of gravity. There is a vertical pressure gradient on the mixture due to the force balance. This condition is required to prevent the entire ...
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1answer
4k views
6
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1answer
837 views

Collision frequency at surfaces

Collision frequency for particles in gases is well known, and collision theory is used to derive chemical reaction rates in gases, (and particles in liquid solutions as well). Using the mean velocity ...