A gas that behaves as randomly moving, non-interacting molecules. This allows a simplified equation of state.

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How slow is a reversible adiabatic expansion of an ideal gas?

A truly reversible thermodynamic process needs to be infinitesimally displaced from equilibrium at all times and therefore takes infinite time to complete. However, if I execute the process slowly, I ...
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1k views

How does a gas of particles with uniform speed reach the Maxwell-Boltzmann distribution?

Take an empty container and fill it with $N$ gas particles (ideally a monoatomic gas), each having the same kinetic energy $E$, then isolate the container. Since initially the speeds don't follow the ...
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Why does this perpetuum mobile not work?(Gases and Densities) [duplicate]

I recently came up with the following concept. It is very simple, and may have been thought of before. A picture says more than a thousand words, so here is it explained in a picture: Note that ...
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6answers
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Gay-Lussac's Law & the Patriots

This may be a question better suited for xkcd what if? section...but here goes: with all the hoopla around the patriots / colts game and allegations of cheating by deflating footballs, I've read/heard ...
9
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310 views

What is the pressure of a charged gas?

I have $N$ ${\rm H}^+$ gas molecules in a sealed, electrically insulated container. What equation can I use to accurately calculate the pressure of the gas? It seems to me that $PV = nRT$ will not ...
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695 views

Where does the joules come from (ideal gas constant)?

I have not done any physics in ages and have recently started studying it. The first chapter in my book deals with the ideal gas constant: $$pV=nRT$$ It is rewritten as: $$R=\frac{pV}{nT}$$ When I ...
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Internal energy of an ideal gas as a function of volume

Okay so I've been reading a bit on Thermodynamics and I found something that I couldn't wrap around my head. For an ideal gas, the change in internal energy is equal to $$\Delta U = Q + W$$ And also,...
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726 views

How fast will sublimed dry ice mix with air?

I saw this photo and wondered: Will the CO2 stay mostly in a layer on the floor with the rest of the atmosphere resting on top, or will it quickly diffuse throughout the room? This lab is probably ...
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Why is steam used to spin turbines?

The ideal gas law tells us that the relationship between Pressure (P), Volume (V), Temprature (T), and quantity/amount (n) is $$ PV = nRT $$ where R is the gas constant. Say your an engineer who ...
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716 views

Why are gasses difficult to see? [duplicate]

Why are gases difficult to see?
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1answer
120 views

7/2 versus 9/2 for diatomic heat capacity

Question I calculated the classical heat capacity of a diatomic gas as $C_V = (9/2)Nk_B$, however the accepted value is $C_V = (7/2)Nk_B$. I assumed the classical Hamiltonian of two identical atoms ...
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1answer
968 views

Why is it difficult to mix helium and nitrogen gases?

I recently learned an interesting fact: That it's difficult to mix helium and nitrogen gases in a compressed gas cylinder. Gas suppliers that need to mix the two gases have to rotate the cylinders for ...
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170 views

Doubts about the ideal gas law

EDITED AND SOLUTION: In fact my stupid mistake was to take the wrong value for my $P_1$ and I was getting an 1.2998 that finally is a 1,9178 within just a difference about 7%. So at the end they are ...
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1answer
1k views

Collision frequency at surfaces

Collision frequency for particles in gases is well known, and collision theory is used to derive chemical reaction rates in gases, (and particles in liquid solutions as well). Using the mean velocity ...
6
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468 views

Classical and Semi-classical treatments of the ideal gas

In the semi-classical treatment of the ideal gas, we write the partition function for the system as $$Z = \frac{Z(1)^N}{N!}$$ where $Z(1)$ is the single particle partition function and $N$ is the ...
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1answer
107 views

Adiabatic expansion in the atmosphere

When an air parcel rises and cools adiabatically, it is said that there is no heat transfer as work is done on the surrounding atmosphere as the parcel expands. The parcel loses internal energy and ...
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449 views

Would the temperature of a gas change when accelerated in a train?

I was thinking about a situation where some gas is enclosed inside a container and kept in a train at rest. The train accelerates, gains a maximum speed and then suddenly stops. Would the temperature ...
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Why does a gas get hot when suddenly compressed? What is happening at the molecular level?

My guess is that the molecules of gas all have the same speed as before, but now there are much more collisions per unit area onto the thermometer, thus making the thermometer read a higher ...
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3answers
14k views

What type of substances allows the use of the Ideal Gas Law?

I know that I can use the ideal gas law with pure gases or pure liquids. But can I also use the ideal gas law at saturated gases and saturated liquids as long as they aren't two phase substances?
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Why are volume and pressure inversely proportional to each other?

It makes sense, that if you have a balloon and press it down with your hands, the volume will decrease and the pressure will increase. This confirms Boyle's Law, $ pV=k=nRT $. But what if the ...
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Differentiating the ideal gas law

In reading Fermi's Thermodynamics, to show that $C_p = C_v + R$, the author differentiates the ideal gas law for a mole of gas ($PV = RT$) to obtain: $PdV + VdP = RdT$. Now, the only way I am able to ...
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2answers
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Why energy at room temperature $= kT$ and not $(3/2)kT$ [duplicate]

I always see that a room temperature of $T=300\,\text{K}$ corresponds to an energy of $k_BT \approx \frac{1}{40}\,\text{eV}$. But shouldn't it be $\frac{3}{2}k_BT$ since the molecules in the air have ...
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3answers
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What does it take to derive the ideal gas law in themodynamics?

How can the ideal gas law be derived from the following assumptions/observations/postulates, and these only ? I'm able to measure pressure $P$ and volume $V$ for gases. I notices that if two ...
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437 views

Can we apply $pV^\gamma$=const only for quasistatic adiabatic process?

But If this is so, I have often seen people applying this formula for quick processes where no heat exchange is possible. Here is an example from where I am quoting the following: we will assume ...
5
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1answer
637 views

Ideal gas and diatomic gas with same temperature

If a box of ideal gas and another box of diatomic gas are in thermal equilibrium, does it mean that the average translational energy of ideal gas particle (A) is the same as that of diatomic gas ...
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Understanding mathematically the free expansion process of an ideal gas

I'm trying to understand mathematically that for the free expansion of an ideal gas the internal energy $E$ just depends on temperature $T$ and not volume $V$. In the free expansion process the ...
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Work done by isothermal expansion from two different viewpoints

Consider an adiabatic system as follows. It consists of a gas in a container and a piston. Initially, the system is at equilibrium and the gas inside it occupies a volume $V_i$ at a pressure $p_i$ ...
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425 views

Physical intuition for independence of components of velocity in derivation of Maxwell–Boltzmann distribution

Maxwell derived the shape of the probability distribution of velocity of gas particles by starting with just two assumptions. These are: The probability distribution is rotation invariant. The ...
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2answers
307 views

Can the Sun's core be treated as an ideal gas?

I know that a gas behaves more like an ideal gas at higher temperature, and that is very well achieved in the Sun's core. But also low pressure is needed for a gas to behave like an ideal gas, and the ...
4
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2answers
16k views

What happens to the temperature when an ideal gas is compressed?

I am rather confused about this. I know from Charles' law that under constant pressure, the volume of a gas is directly proportional to its absolute temperature i.e. $$\frac{V_1}{T_1} = \frac{V_2}{...
4
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3answers
868 views

How do gas molecules constantly bounce without losing energy?

From a related question (How does pressurized gas constantly push?), i asked myself this: How do gas molecules constantly bounce off each other without losing energy? If you drop a ball, it bounces a ...
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Will ideal gas law apply to plasma?

I have read that plasma is a state of matter that resembles gas but it consists of ions and electrons coexisting. So my question is : If plasma is just ionized gas, will ideal gas law apply for it ?
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Ideal gas concentration under temperature gradient

I'm trying to calculate the concentration of an ideal gas in an adiabatic container as a function of position where the top and bottom plates of the container are fixed at temperatures $T_1$ and $T_2$,...
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151 views

Kinetic energy and momentum of an expanding gas

Let's take the simplest case of an ideal gas undergoing adiabatic expansion against a vacuum of finite volume, without any heat and work transfer into or out of the system. The gas moves in bulk to ...
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1answer
296 views

Calculation of the efficiency of a Carnot engine for photon gas

I am working on a problem considering the Carnot cycle for a photon gas. The cycle has two isothermic processes at $T_{H}$ and $T_{C}$ and two adiabatic processes. The entropy of the photon gas is $...
4
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1answer
2k views

Simple explanation of relation between speed of sound and r.m.s. speed?

In an ideal gas, the speed of sound $v_s$ is related to the r.m.s. molecular speed $v_m$ by $$\frac{v_s}{v_m}=\sqrt{\frac{\gamma}{3}} \qquad ,$$ where $\gamma=C_p/C_v=7/5$ for a diatomic gas. I ...
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Are Mach Diamonds radially symmetrical?

Videos like this show a form that suggests a radial symmetry in the gas jet. The same is reinforced by schematic illustrations. But other images, like this, look like there is a twisting structure ...
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Deriving combined gas law from Boyle's and Charles' laws

I know that the combined gas law, $$\frac{PV}{T}=k$$ should be derivable from Boyle's Law and Charles' Law. Since these are very basic equations, I presumed that it would be a simple matter, so I ...
4
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1answer
528 views

speed of sound and the potential energy of an ideal gas; Goldstein derivation

I am looking the derivation of the speed of sound in Goldstein's Classical Mechanics (sec. 11-3, pp. 356-358, 1st ed). In order to write down the Lagrangian, he needs the kinetic and potential ...
4
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1answer
247 views

Energy formula for separating $O_2$ from mixture of $O_2$, $NH_3$ and $H_2O$

I have a physics problem I'd like to make sure I get correct. The practical aspect of this problem is that the photosynthetic efficiency of algae is inhibited with dissolved O2 in the growth medium, ...
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3answers
67 views

Enthalpy of condensation

suppose we have one mole of an ideal gas undergoing a phase change at constant temperature. we know that enthalpy change is given by the formula $n\cdot Cp\cdot\delta(T)$. since there is no ...
3
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8answers
271 views

Ideal gas law: Will the piston move at all?

We have the following experimental setup: Before the experiment starts: $$p_1=p_2; \space V_1=V_2; T_1=T_2+\Delta T$$ The experiment starts and both the containers are heated so that the ...
3
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2answers
558 views

$E=kT$ or $\frac32kT$?

Basically, which is the correct formula for thermal energy, and is this the same as kinetic energy? My notes are pretty conflicting on this topic, and I'm getting pretty confused.
3
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4answers
621 views

Where does air pressure come from?

Where does air pressure come from? I thought it was from gravity or the speed of the gas resulting from its heat. However, analyzing my own hypotheses, I think that my 'heat conjecture' is probably ...
3
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3answers
483 views

Simple question about a gas in a box with a moving wall

David Albert is a philosopher of Science at Columbia. His book "Time and Chance" includes this example (p 36). A gas is confined on one side of a box with a removable wall. "Draw the wall out, ...
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Ideal gas equation and atmosphere of Venus

I'm teaching myself some basics of the ideal gas law and working out simple density equations for atmospheric gases at various altitudes. When I applied the gas law to Venus' atmosphere at its ...
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1answer
845 views

Why do we ignore rotational energy in monatomic gases? [duplicate]

I understand that the average energy of each degree of freedom in a thermodynamic system is $\frac12kT$. And so, for an ideal monatomic gas, there are three degrees of freedom associated with the ...
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4answers
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Heat transfer by conduction is not possible for gases?

Today one of my instructor told me that gases cannot have heat transfer thru conduction because molecules are far apart and so it cannot transfer heat,infact the diffusion process of gases transfers ...
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2answers
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With ideal gases, varying quantity of moles, and having a constant volume how do temperature and pressure behave?

I'm trying to build a simulation of gases so I ended-up trying to use law of ideal gases ($PV = nRT$). In my scenario: volume is constant ($V=1\rm{m}^3$); a known quantity of moles are being added ...
3
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2answers
118 views

Gases Expanding and Bonding in the Vacuum? Frozen Clouds

Why do gasses expand in space rather than attract forming a liquid? Do some gasses attract or bond when they get colder and what would be the characteristics of it in space? Would it be like powder ...