A gas that behaves as randomly moving, non-interacting molecules. This allows a simplified equation of state.

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How do I find the amount of atoms in a pure gas in a confined area?

Say I have Argon gas in an area such as a cube with pressure around pressure between 10-5 and 10-3 Torr (pressure) at 25 degrees at 320 Kelvins . How do I find the amount of atoms in that cube? Any ...
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452 views

How does a gas of particles with uniform speed reach the Maxwell-Boltzmann distribution?

Take an empty container and fill it with $N$ gas particles (ideally a monoatomic gas), each having the same kinetic energy $E$, then isolate the container. Since initially the speeds don't follow the ...
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14 views

Calimetric Perfect Ideal Gas

What is the energy equation when you have a ridgid adiabatic open system where you have a mass flow rate in and a mass static inside the system?
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274 views

Density of Air in a balloon

A balloon with volume 2800 m³ is heated up to 60 °C. If the outer temperature is 12 °C and the air has a pressure of 960 hPa, what is the density of the air inside the balloon and on the ...
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40 views

What portion of impulse is received by the cylinder?

Condition: A cylinder with a piston are situated along Y axis. Piston receives an impulse (P1) along Y axis and transmits it to the cylinder through a gas medium with which cylinder is filled. The ...
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99 views

Combined gas law in an open atmosphere

The question was asked about pressure vs. Volume increasing in an ideal gas as temperature is increased. My question then is this. What is the formula to determine how much volume and pressure will ...
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2answers
2k views

In an ideal gas, if temperature increases, will pressure or volume increase?

This question came up when I was talking about the atmosphere. Someone had mistakenly claimed that as temperature increases, the density of the atmosphere should increase as well. I reasoned from the ...
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238 views

Understanding Charles's Law

Charles's law states that, The volume of a given mass of an ideal gas is directly proportional to its temperature on the absolute temperature scale (in Kelvin) if pressure and the amount of gas ...
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231 views

Why is steam used to spin turbines?

The ideal gas law tells us that the relationship between Pressure (P), Volume (V), Temprature (T), and quantity/amount (n) is $$ PV = nRT $$ where R is the gas constant. Say your an engineer who ...
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435 views

Costant volume gas thermometer [closed]

I have two constant volume gas thermometers, one with an ideal gas $pv=RT$ and the other following the Van der Waals equation $(p+\frac{a}{v^2})(v-b)=RT$. They are calibrated using the freezing point ...
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144 views

ideal gas law modelization in a vacuum chamber

I am trying to model a pressure sensor in COMSOL. The basic work is that there is current flowing inside it, if the pressure of the gas around it drops down, the temperature goes down as well (ideal ...
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1answer
53 views

What is the $\delta$ in fluctuation model [closed]

I found this formula : $G-G_0=\frac{-nkT}2\delta^2$ on this Site and I'd like to ask what does the $\delta$ stand for?
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240 views

Average force and pressure in a 3D box due to quantum non-interacting particles

A gas of non-interacting quantum particles occupies a box with lengths $L_1, L_2, L_3$. Calculate its energy and thus the average force and pressure exerted by the gas on the walls of the box. I have ...
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61 views

Compression of a liquid with a gas dissolved in it?

If I remember correctly you cannot compress a liquid, but I know you can compress a gas. (usually to the point it becomes a liquid then no further) What happens if I were to compress soda water? A ...
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55 views

error propagation and collision in ideal gas

When dealing with gas, a statistical approach is needed because For N particles, you have to solve 6N equations which cant be done analytically. To know our time step for numerical solving, you can ...
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3answers
1k views

Air pressure in balloon

I have to calculate the air pressure inside of an hot air balloon. After some searching I found out that I can use the ideal gas law: PV = nRT (from Wikipedia) So to get the pressure in the balloon I ...
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2answers
88 views

Is it possible to obtain higher order corrections to the ideal gas law when one allows realistic phenomena to make their way into the equations?

I had an interesting thought today that caused me to ask whether it'd be possible to make corrections to the ideal gas law via introducing terms derived from more realistic phenomena to make their ...
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321 views

How can I interpret negative values of potential evapotranspiration?

If I extract Potential Evaporation (PET, W/m$^2$) from the National Centers for Environmental Prediction (NCEP), climate reanalysis data (downloadable as netCDF files here), there are some negative ...
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118 views

How fair is it to say that all chemistry arises from failures of the ideal gas law?

I was reading here about how the ideal gas law assumes point masses and non-interaction. Is it fair to say that all chemistry arises from failures of that? Of course, such a sweeping generalization ...
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153 views

Volume of gas at which relative fluctuation of gas density occurs

I have the following question: In what volume of gas occurs 10 % relative fluctuation of gas density under pressure of $10^5\text{ Pa}$ and temperature of $293.15\text{ K}$? I don't understand ...
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218 views

Conversion of ideal gas to real gas via $Z$ compression factor

The ideal gas equation $PV=nRT$ can be converted into real gas equation by compression factor $Z$ i.e $PV=Z~ nRT)$. My question is what is $Z$ and how does it arise? Is $PV/nRT$ a compression ratio of ...
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2answers
555 views

What are the units of these virial coefficients?

I'm reading some papers for calculating the vapor pressure of alkali metals as a function of temperature, and I've come across some familiar-looking virial expansions, but when I tried to work out the ...
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1answer
198 views

Calculating Air Density Lapse With Altitude (Specifically, pressures)

This might be a bit more of an engineering question, but I'm calculating air density drop-off with altitude, and I'm having some problems calculating the pressure (I'll run through my method). This ...
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382 views

Temperature change inside pressure chamber

Let's say there is a pressure chamber with some sort of sample / specimen (e.g. protein crystal) in it. Now I apply a certain amount of gas pressure, e.g. 10 or 20 atm. Let's say I use xenon as a gas. ...
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69 views

In $PdV$, what is the value of $P$? $P_1$ or $P_2$?

Say I have an ideal gas that has a known $P_1$, $P_2$, $T_1$, and $T_2$ undergoing a reversible adiabatic process. I want to find the work done so I must use $PV = RT$ to get the change in $V$, so ...
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387 views

Canonical partition of a boson gas

I have a 1D gas made of $N$ particles placed in a harmonic potential well, so the Hamiltonian is: $$ \mathcal H = \sum_{j=1}^N \left ( \frac{p_j^2}{2m} + \frac{1}{2}m\omega^2 x_j^2 \right )$$ The ...
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3k views

How to calculate the specific heat capacity of gases

Could someone explain why the Specific Heat Capacity (SHC) of dry air is 1.005kJ/kg.K whereas the accepted SHC for ventilation air is quoted 1.300kJ/kg.K? Assuming the air for the ventilation calc’s ...
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Root Mean Square Speed of Gas

The RMS speed of particles in a gas is $v_{rms} = \sqrt{\frac{3RT}{M}}$ where $M$ = molar mass; according to this Wiki entry: http://en.wikipedia.org/wiki/Root-mean-square_speed The gas laws ...
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236 views

Ideal gas temperature and pressure gradients?

Consider an ideal gas in a $d\times d\times L$ box with the $L$ dimension in the $x$-direction. Suppose that the opposite $d\times d$ sides of the box are held at temperatures $T_1$ and $T_2$ with ...
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336 views

Ideal gas concentration under temperature gradient

I'm trying to calculate the concentration of an ideal gas in an adiabatic container as a function of position where the top and bottom plates of the container are fixed at temperatures $T_1$ and ...
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2answers
694 views

With ideal gases, varying quantity of moles, and having a constant volume how do temperature and pressure behave?

I'm trying to build a simulation of gases so I ended-up trying to use law of ideal gases ($PV = nRT$). In my scenario: volume is constant ($V=1\rm{m}^3$); a known quantity of moles are being added ...
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Experimental data for gas flow through pipelines

Maybe some of you could point a good source of experimental data of gas flow through pipelines? What I need is a very simple flow of some gases through some diameter simple linear pipeline. A graph of ...
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Adiabatic process of an ideal gas derivation

I am working through the derivation of an adiabatic process of an ideal gas $pV^{\gamma}$ and I can't see how to go from one step to the next. Here is my derivation so far which I understand: ...
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571 views

Understanding mathematically the free expansion process of an ideal gas

I'm trying to understand mathematically that for the free expansion of an ideal gas the internal energy $E$ just depends on temperature $T$ and not volume $V$. In the free expansion process the ...
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1answer
70 views

Working out the mean velocity of particles in a gas

I'm trying to answer the following question: Air consists of molecules Oxygen (Molecular mass = 32$amu$) and Nitrogen (Molecular mass = 28$amu$). Calculate the two mean translational kinetic ...
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84 views

Using thermodynamics and Kinematics together to solve a parachuter problem?

I need to find a parachutist's displacement after a given height (nearly 37000m) and at a given latitude. I have his mass, area, parachute area, drop height, parachute deployment height, data about ...
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94 views

Problem evaluating moles in a an isochor transformation

I have a problem with an isochor transformation. Me and my group of study made an experiment that want to check Gay-Lussac’s law. We registered the equilibrium states and fitted the $P = nRT / V$, ...
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107 views

Thermodynamic process when nebula is heated

The basic thermodynamics problem is stated as follows. The nebula contains a very tenuous gas of a given number density (atoms per volume) that is being heated to a given temperature. What is the ...
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How to deduce E=(3/2)kT?

It says in my course notes that a particle has so-called "kinetic energy" $E=\frac{3}{2}kT=\frac{1}{2}mv^²$ Where does this formula come from? What is k?
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329 views

Velocity of real gas molecules?

It is known that the velocity of ideal gas molecules can be computed using Maxwell-Boltzmann law of distribution of molecular velocities, with average velocity given as: ...
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397 views

Will ideal gas law apply to plasma?

I have read that plasma is a state of matter that resembles gas but it consists of ions and electrons coexisting. So my question is : If plasma is just ionized gas, will ideal gas law apply for it ?
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Is it possible to find the number of gas atoms/molecules in a box when the number is small?

Given very low number of particles in a system (e.g. in the 100s), is there a way to accurately measure the number of particles in the system? Assume temperature, pressure and volume is constant and ...
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2answers
5k views

Calculating work done on an ideal gas

I am trying to calculate the work done on an ideal gas in a piston set up where temperature is kept constant. I am given the volume, pressure and temperature. I know from Boyle's law that volume is ...
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1answer
782 views

Adiabatic expansion [closed]

I'll start off by saying this is homework, but I ask because I don't understand how the math should work (I don't just want an answer, I'd like an explanation if possible). I understand if this is ...
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1answer
59 views

Performing work on a box of gas by lifting it, and first law of thermodynamics

What happens if we lift a box of ideal gas? Work is done to the box but no heat is getting into it. So does it's internal energy increase by the amount of work done? Or is it that lifting is not ...
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247 views

Ideal gas and diatomic gas with same temperature

If a box of ideal gas and another box of diatomic gas are in thermal equilibrium, does it mean that the average translational energy of ideal gas particle (A) is the same as that of diatomic gas ...
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3k views

Work Done by an Adiabatic Expansion

I am given the information that a parcel of air expands adiabatically (no exchange of heat between parcel and its surroundings) to five times its original volume, and its initial temperature is 20° C. ...
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2k views

Work Done in an Isobaric Process

I am given the information that an air parcel undergoes isobaric heating from 0° C to 20° C, and that's all I'm given. I have to determine the work done by the parcel on its surroundings. I know that ...
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1answer
189 views

Which heated, partially filled bottle will explode first?

This is in reference to a pasteurization discussion on a homebrewing forum. I have four closed bottles which will explode if containing too much pressure. Two of them are 50% full (A and B), and two ...
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3k views

Ideal gas law, pressure increase and temperature

If I had a container, full with air, and I suddenly decreased the volume of the container, forcing the air into a smaller volume, will it be considered as compression, will it result in an increase in ...