Could refer to (1) A hydrogen molecule; two hydrogen atoms bonded together or (2) A hydrogen atom; One electron electromagnetically interacting with a nucleus made of a single proton. Hydrogen atoms are the simplest atoms, and they are the only atoms for which we can exactly solve the Schrodinger ...

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3answers
2k views

How long will the Universe's hydrogen reserves last for?

I recently became really interested in learning about physics and cosmology, but I still know very little. Hopefully someone with more knowledge will be able to shed some light on my questions. Here ...
10
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5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
6
votes
2answers
277 views

How can one see that the Hydrogen atom has $SO(4)$ symmetry?

For solving hydrogen atom energy level by $SO(4)$ symmetry, where does the symmetry come from? How can one see it directly from the Hamiltonian?
5
votes
4answers
534 views

What does ionization of neutral Hydrogen have to do with “transparency”?

Most accounts of the early history of the Universe make some reference to (re)ionization as being the reason that the Universe becomes transparent after a period of opacity caused by the absence of ...
5
votes
1answer
257 views

Orthonormality of Radial Wave Function

Is the radial component $R_{n\ell}$ of the hydrogen wavefunction orthonormal? Doing out one of the integrals, I find that $$\int_0^{\infty} R_{10}R_{21}~r^2dr ~\neq~0$$ However, the link below says ...
5
votes
2answers
333 views

Technical detail in the solution of the hydrogen atom

I'm trying to do an exercise in which you solve the Schrödinger equation for the hydrogen atom. Through the exercise, I've already shown that the wavefunction is: $$ \psi_{n\ell m}(r,\theta,\varphi) ...
5
votes
1answer
114 views

How does one calculate where the “surface” of a gas-giant would be?

Okay, so Jupiter, Saturn, et. al are gas giants. I understand that they have large gassy atmospheres, which, due to the pressure would eventually become more and more dense as one approaches the ...
4
votes
3answers
612 views

Why is a proton assumed to be always at the center while applying the Schrödinger equation?

Why is a proton assumed to be always at the center while applying the Schrödinger equation? Isn't it a quantum particle?
4
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5answers
1k views

Hydrogen radial wave function infinity at r=0

When trying to solve the Schrödinger equation for hydrogen, one usually splits up the wave function into two parts: $\psi(r,\phi,\theta)= R(r)Y_{l,m}(\phi,\theta)$ I understand that the radial part ...
4
votes
2answers
364 views

What made Bohr quantise angular momentum and not some other quantity?

Bohr's second postulate in Bohr model of hydrogen atom deals with quantisation of angular momentum.But, I was wondering why he quantised angular momentum and any other quantity?
4
votes
1answer
112 views

Fusion: Why deuterium and tritium?

I would like to know why scientists try to use deuterium and tritium for fusion and not just the ordinary isotope of Hydrogen ${}^1H$?
4
votes
3answers
101 views

Hydrogen cloud at the universe's beginning?

What prevented all of the hydrogen at the universe's start from coalescing into one gigantic star?
4
votes
2answers
806 views

magnetic moment of proton

I just tried to calculate the magnetic moment of a proton. I took the proton g-Factor of $g=5.585694$ nuclear magneton of $\mu_k = 5.050783 * 10^{−27}$ J/T proton spin of $I=1/2$ At first I ...
4
votes
1answer
500 views

Reduced mass in quantum physics (Hydrogen Atom)

I've gone through an intermediate classical mechanics course, and in solving the two-body problem, we reduce it to a one-body between a larger stationary mass, and a smaller reduced mass. Most ...
4
votes
1answer
252 views

Scattering states of Hydrogen atom in non-relativistic perturbation theory

In doing second order time-independent perturbation theory in non-relativistic quantum mechanics one has to calculate the overlap between states $$E^{(2)}_n ~=~ \sum_{m \neq n}\frac{|\langle m | H' ...
4
votes
1answer
867 views

Stark Effect on the 1st excited state of Hydrogen

I know the ground state of hydrogen is unaffected by the Stark effect to first order. And I also know that the 1st excited state is split from 4 degenerate states to 2 distinct, and 1 degenerate state ...
4
votes
1answer
39 views

How did Lyman discover his series?

How did Lyman discover his series in hydrogen atom? How did he know that the final energy level is the first level and not the second or the third or etc.? Or how did the other scientists know which ...
4
votes
0answers
68 views

Is it reasonable to interpret the Lamb shift as vacuum induced Stark shifts?

This is a pretty hand-wavy question about interpretation of the Lamb shift. I understand that one can calculate the Lamb shift diagrammatically to get an accurate result, but there exist ...
3
votes
3answers
304 views

Bessel vs. modified Bessel in radial equation of hydrogen

I am trying to understand the difference between Bessel functions and modified Bessel functions (simply googling is yielding complicated, non-intuitive answers). I was under the impression that one ...
3
votes
4answers
555 views

Could hydrogen liberated from water provide lifting energy which exceeds the energy it took to liberate it from water

I was thinking about Hydrogen balloons and that large ones which are used for weather balloons which sometimes go up to 100,000 ft (approx 30km). Then I was wondering, how much potential energy has ...
3
votes
2answers
215 views

What is the expected distance of the electron from the nucleus in the hydrogen atom?

Specifically, I would like to know the general formula, in terms of $n$ and $l$, assuming the electron is in an orbital (i.e. simultaneous eigenstate of $H$, $L^2$, and $L_z$). I understand that it ...
3
votes
2answers
517 views

Where does the Pauli Repulsive Force come from that counteracts the attraction between atoms and ions? [duplicate]

I'm learning about such things as ionic and covalent bonds, and the reason given for the ionic bonds is electrostatic attraction. However, if that were true, then the two ions would accelerate toward ...
3
votes
1answer
224 views

How can we describe the electrons of multi-electron atoms (i.e. not Hydrogen) when equations/analytic solutions only exist for Hydrogen?

I've been digging into emission spectra of different elements and found that such things as the Rydberg equation, Bohr's model, and quantum mechanics can only fully describe the single electron in the ...
3
votes
2answers
853 views

Why is the binding energy per nucleon not zero for hydrogen atom?

The lone proton has not to be worked on against any electrostatic force. So where does the energy come from? What is mass defect for a hydrogen nucleus?
3
votes
2answers
568 views

Jupiter Core is Solid Hydrogen

I was watching a show on the science channel about gas giants; there is something I do not understand. I am not a scientist, so this may be obvious to some. I learned that there a three states of an ...
3
votes
1answer
67 views

Spin-orbit coupling from the rest frame of the proton?

When we calculate the spin-orbit interaction in a Hydrogen atom we just work in the electron's frame of reference: the proton is moving and produces a magnetic field which the electron's spin ...
2
votes
4answers
820 views

why ammonia is not a competitive energy carrier?

reading this article about Germany planning to store renewable energy as hydrogen gas, i'm left wondering why they deem so great this plan, compared with other alternatives like ammonia as a energy ...
2
votes
1answer
184 views

Orbital of Hydrogen molecule

does anybody here know an analytical approximation of the bonding hydrogen orbital MOLECULE? I am looking for a good approximation to this orbital, that might be in some textbooks to get an ...
2
votes
1answer
545 views

Hydrogen wave function in momentum space

We can seperate the wave function of an hydrogen atom in a radial and an angle part: $$ \phi_{n,l,m} (\mathbf{r}) = R_{n,l,m}(r) Y_{l,m}(\vartheta,\varphi) \, , $$ where $Y_{l,m}$ are the spherical ...
2
votes
1answer
122 views

can hydrogen stay frozen in vacuum?

I've look into the hydrogen state diagram, and it seems that it can be frozen under pressure. Question: Does this mean that hydrogen cannot be kept frozen in a vacuum chamber?
2
votes
4answers
2k views

How can one describe electron motion around hydrogen atom?

I remember from introductory Quantum Mechanics, that hydrogen atom is one of those systems that we can solve without too much ( embarrassing ) approximations. After a number of postulates, QM ...
2
votes
1answer
107 views

Volume charge density of H-atom

I have a problem where I am supposed to calculate the volume charge density of a neutral hydrogen atom. The potential is given to be $$ \Phi = k \frac{e^{-ar}}{r} \left(1 + \frac{ar}{2}\right) $$ Now ...
2
votes
1answer
210 views

Ground state energy of hydrogen molecule ion

In this paper, it is mentioned: Furthermore, since the energy of $H_2^+$in the ground state must be lower than that of an H atom in the ground state,the negative (attractive) forces in the ...
2
votes
2answers
244 views

Why the hydrogen radial wave function is real?

Why the hydrogen radial wave function is real? Is it a coincidence?
2
votes
2answers
278 views

Hydrogen atom in quantum mechanics

I have problems following the calculations in Griffiths' Introduction to Quantum Mechanics (Chapter 4.2.1): If you apply the Schrödinger equation to the Coulomb potential you get the following ...
2
votes
1answer
218 views

Electric dipole transitions/expectation value of position

Part of a homework question asks to show that for $\ell=0$ in both $\Psi_i$ and $\Psi_f$, we have $$ \int \Psi_i^\ast \vec{r} \Psi_f \; d\tau = 0 $$ for the position vector $\vec{r}$. (This is for ...
2
votes
1answer
255 views

How does the internuclear repulsion vary in Hydrogenic atom collision?

Hydrogen fusion requires two hydrogen nuclei to get close enough (typically a few fm) to fuse. Much of the problem of creating a fusion reactor is overcoming the Coulomb repulsion between a pair of ...
2
votes
2answers
101 views

Spin orbit coupling and fine structure of the Hydrogen atom

At university we have just derived the expression for the energy split due to spin-orbit coupling in the Hydrogen atom, i.e. what is known as the FINE structure of Hydrogen. To do this, we ...
2
votes
1answer
111 views

Strömgren Sphere of Sun

I have a homework problem: The Sun emits $ \sim5 x 10^{23}$ photons per second with $hν > 13.6$ $eV$. If the density of hydrogen atoms in interplanetary space is $n =$ $109 m^{-3}$, what ...
2
votes
1answer
107 views

Possible Outcomes from Measuring a Hydrogen Atom

A hydrogen atom is characterized by the wavefunction $$\mid \psi \rangle =\sqrt{\frac{2}{7}}\mid 4\,2\,1\rangle +\sqrt{\frac{1}{7}}\mid 2 \,1\,\bar{1}\rangle+\sqrt{\frac{4}{7}}\mid 3\,2\,0\rangle$$ ...
2
votes
1answer
77 views

Why does bringing N 1-orbital atoms together yield N levels?

A common example of this is that when bringing N hydrogen atoms together into a ring. Far apart, assume each electron exists in the 1s state. As we bring them together, instead of each electron ...
2
votes
2answers
242 views

What's the difference between two Hydrogen atoms?

If we are given two Hydrogen atoms, would the only difference between them would be their quantum state (Energy level or eigen value, and the corresponding Orbital or eigen state) and their location ...
2
votes
1answer
455 views

Theoretical treatment of Hydrogen bond?

I would like to understand how the Hydrogen bond can be described through the Schroedinger equation. I don't need numerical methods that one uses them to simulate it, rather I need its treatment from ...
2
votes
1answer
128 views

Hydrogen Hyperfine Structure: General Expression

I was looking at the hyperfine structure for the hydrogen atom. I checked pretty much every textbook I knew but none of them gave me the general expression for the energy correction due to the ...
2
votes
1answer
569 views

Wave function of hydrogen atom including spin of nucleus

How do I write the wave function of hydrogen atom taking into consideration of nucleus spin? For example consider $2S_{\frac{1}{2}}$ state with nucleus spin $I$, then wave function ...
2
votes
1answer
428 views

Metallic Hydrogen and Gaseous Planets

Jupiter has about twice the density of Saturn (1.33 versus 0.69 g/cm^3) because it apparently has a higher mass percentage of rocky core and of metallic hydrogen in its interior. Available density ...
2
votes
0answers
41 views

Limits of integration for the radial wave function of the Hydrogen atom in the WKB approximation

I am working a problem where we have to find the energy eigenvalues for the radial wave function of the hydrogen atom for $\ell=0$ using the WKB approximation. I am sure that I set up the integral ...
2
votes
1answer
60 views

Is a free proton a positive Hydrogen-1 ion?

The Hydrogen-1 isotope is a form of hydrogen with 1 electron, 1 proton, and 0 neutrons. If that isotope were to lose its electron (thus being a Hydrogen-1 ion with a positive charge) what would be ...
2
votes
0answers
93 views

Line-shape asymmetry in undergraduate Hydrogen-Deuterium experiment

I'm working as an LA (undergraduate TA) for an undergraduate physics laboratory experiment where students test the Bohr model and use reduced mass to determine the approximate mass of the neutron. In ...
1
vote
2answers
1k views

The probability of finding the electron in the H-atom

In the book Arthur Beiser - Concepts of modern physics [page 213] author separates the variables in the polar Schrödinger equation assuming: $$\psi_{nlm}=R(r)\Phi(\phi)\Theta(\theta)$$ then there a ...