Could refer to (1) A hydrogen molecule; two hydrogen atoms bonded together or (2) A hydrogen atom; One electron electromagnetically interacting with a nucleus made of a single proton. Hydrogen atoms are the simplest atoms, and they are the only atoms for which we can exactly solve the Schrodinger ...

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33 views

What exactly is closed orbit theory and what assumptions go into it?

I am just beginning a research project on the study of closed orbits, specifically as related to hydrogen, and I wanted a little bit more information on what exactly makes something a "closed orbit". ...
1
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0answers
19 views

Find the fraction of atoms in specific quantum state in stellar atmosphere [closed]

Consider gas consisting of hydrogen atoms at temperature about $T \sim 5 \cdot 10^6 \text{ K} \approx 431 \text{ eV}$ and concentration $N \sim 10^{11} \text{ cm}^{-3}$. I need to find the fraction of ...
0
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0answers
14 views

Wavenumber separation for a source containing hydrogen and deuterium [closed]

I'm trying to solve the following question: The hydrogen line at $656.3nm$ emitted from a source containing hydrogen and deuterium is studied using a Fabry-Perot etalon of $0.5mm$ spacing. The ...
-1
votes
0answers
31 views

Power output of a galaxy problem [closed]

A galaxy contains 10^9 M⊙ of neutral hydrogen. Given the transition rate for the hyperfine transition is 2.85*(10^-15) s^-1, calculate the galaxy’s power output (in W) in the 21-cm line. How ...
4
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2answers
185 views

Using the uncertainty principle to estimate the ground state energy of hydrogen

I have been reading through this estimate of the ground state energy of hydrogen and others like it. In this one it says it is using the uncertainty principal but then proceeded to use the following: ...
7
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3answers
2k views

What made Bohr quantise angular momentum and not some other quantity?

Bohr's second postulate in Bohr model of hydrogen atom deals with quantisation of angular momentum. I was wondering, though: why did he quantise angular momentum instead of some other quantity?
2
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1answer
61 views

Algebraic solution of Dirac equation for Coulomb potential

The Runge-Lenz operator enables an algebraic solution of Coulomb potential energy levels without a solution of a differential equation. What is the analog for the solution of the Dirac equation in a ...
3
votes
2answers
287 views

Hydrogen atom: potential well and orbit radii

I happened to open up an old solid-state electronics book by Sah, and in it he says: "it is evident that the electron orbit radius is half the well radius at the energy level En" The orbit radius is ...
0
votes
1answer
147 views

Difference between expectation values of $L^2$, $L_z$ and measuring $L^2$, $L_z$

I was given with this hydrogen radial wavefunction $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ and was asked to find a) What are the expectation values of the ...
0
votes
2answers
81 views

Meaning of the Angular Momentum in Quantum Mechanics

There was a discussion about the angular momentum in QM in an online course that I am attending now. The discussion and the answers did not satisfy me so I wanted to ask it on Physics SE. In the ...
1
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1answer
146 views

Size of hydrogenic atoms

Positronium consists of an electron and a positron. By what factor is a positronium atom bigger than a hydrogen atom? The solution has been explained to me. The characteristic length when solving ...
2
votes
3answers
240 views

Normalization problem with hydrogen wavefunction

Suppose you have a mix of states made up of the Hydrogen $\lvert nlm \rangle$ states where one of the coefficients is unknown. For example: $$ \lvert \psi\rangle=A\lvert 100\rangle + ...
0
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0answers
30 views

Experiment validating existence of virtual particle

I'm curious about virtual particle whether do they really exists, therefore I dug out an experimental theory called lamb shift by measuring the difference between the two energy levels of a hydrogen ...
1
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2answers
2k views

The probability of finding the electron in the H-atom

In the book Arthur Beiser - Concepts of modern physics [page 213] author separates the variables in the polar Schrödinger equation assuming: $$\psi_{nlm}=R(r)\Phi(\phi)\Theta(\theta)$$ then there a ...
1
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1answer
56 views

2s orbital wavefunction has non-zero probability at $r=0$? [duplicate]

The wavefunction for an electron within a hydrogen atom in the $2s$ state has the following wavefunction: ...
6
votes
5answers
1k views

Hydrogen radial wave function infinity at $r=0$

When trying to solve the Schrödinger equation for hydrogen, one usually splits up the wave function into two parts: $$\psi(r,\phi,\theta)= R(r)Y_{l,m}(\phi,\theta).$$ I understand that the radial ...
0
votes
2answers
61 views

How does the time evolution of a hydrogen atom work?

If I am given the initial stationary spatial wavefunction of a hydrogen atom, how does it change through time? I'm wondering if it is the same as the time evolution of any old stationary state, that ...
0
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0answers
28 views

Why does the spectrum for deuterium show a weak line at H-alpha?

I was wondering why the spectrum for deuterium shows a weak line at H-alpha, the first line in the hydrogen spectrum.
2
votes
1answer
67 views

Help in solving Schrödinger equation for Hydrogen

I have almost finished getting the solution to the Schrödinger equation for the hydrogen atom (got the theta and phi component equations), but am stuck on the r component equation. Can anyone help me ...
7
votes
2answers
429 views

Scattering states of Hydrogen atom in non-relativistic perturbation theory

In doing second order time-independent perturbation theory in non-relativistic quantum mechanics one has to calculate the overlap between states $$E^{(2)}_n ~=~ \sum_{m \neq n}\frac{|\langle m | H' ...
-1
votes
2answers
101 views

How do we know $\psi$ depends on $n,l,m$

Regarding the separation of $\psi$ to an angular and radial part, why does each part have a specific dependence of the quantum numbers? How can Schrodinger equation describe a system just from its ...
0
votes
1answer
39 views

Fine Structure Correction

The fine structure correction is composed of the relativistic correction and spin-orbit coupling. The lowest-order relativistic correction to the Hamiltonian is $$ H_r' = -\frac{p^4}{8m^3c^2}$$ ...
0
votes
2answers
69 views

Photon propagation direction prediction possible after interacting with neutral hydrogen?

My current line of research deals a lot with hydrogen's Lyman-alpha emission and subsequent interactions of the Lyman-alpha photons with the surrounding hydrogen gas. My question is whether ...
1
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1answer
102 views

Describe proton and electron by one wavefunction

when I was new into quantum mechanics, I thought we can describe helium atom by two wavefunctions - one for every electron. After some time I discovered how wrong I was - first, because electrons are ...
1
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1answer
56 views

Can hydrogen atom state be a superposition of 2 pure states with opposite spin?

The task is: We are performing measurements on hydrogen atom, that is in an unknown state $\psi$. $\psi$ is a superposition of $n=1$ and $n=2$ pure states and is orthogonal to ...
0
votes
1answer
23 views

What is “$f$” in deuterium-hydrogen ratio measurements?

On D-H ratio plots, $f$ seems to be used as a reference point, e.g. on the right axis in this plot of D/H ratios around the solar system from a 67/P paper: What exactly is $f$ and how is it ...
0
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0answers
40 views

Is the associated Laguerre polynomial $L_1^1(x)$ equal to $-1$ or $2 - x$?

I've been reading a book by Normand M. Laurendeau, Statistical Thermodynamics: Fundamentals and Applications, about hydrogen orbitals and in it is an equation that explains how to calculate the ...
3
votes
2answers
123 views

How do you determine the “phase” of a hydrogen eigenfunction?

I've been reading the wikipedia article on the atomic orbitals of hydrogen. They have a nice collection of diagrams, such as this one for n,l,m = 3,1,1 This is apparently showing the wavefunction, ...
1
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0answers
97 views

Is hydrogen atom in a box solvable analytically?

Schrödinger's equation for hydrogen atom in free space can be easily solved by switching to center of mass frame, introducing reduced mass and separating variables in the resulting 3D problem. But ...
0
votes
4answers
3k views

Collision between electron and proton?

What would happen if an electron collided with a proton such that the two do not collapse? Would the two become a unit, or would some force prevent them from bonding thus forcing the electron to orbit ...
1
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0answers
77 views

Hydrogen 2p3/2 -> 1s1/2 transition polarisation and angular distribution

Could you please help me. I have to calculate the intensity angular and polarisation distribution in hydrogen electric dipole transition $\text{2p}_{3/2}\rightarrow \text{1s}_{1/2}$. To do this I ...
1
vote
1answer
70 views

Nuclear fusion - Hydrogen isotopes

What is the isotope composition of hydrogen atoms in the sun? Are the ratios of protium:deuterium:tritium similar to those we find on earth? What does the nuclear fusion of hydrogen atoms in the sun ...
0
votes
2answers
136 views

Quantised Angular Momentum?

So when learning about the Bohr model of hydrogen and de Broglie waves, it was shown that treating the electron of hydrogen as a de Broglie wave results in the relationship $$L=n\hbar, \qquad ...
3
votes
3answers
745 views

Why do we use the Coulomb potential for the hydrogen atom?

When solving the Schrodinger equation for the hydrogen atom, the Coulomb potential $V = \frac{e^2}{4 \pi \epsilon_0 r}$ is used. The Coulomb potential comes from classical electrodynamics, so why ...
-1
votes
1answer
91 views

Angular momentum Bohr's model

I have been trying to derive speed, radius etc. in hydrogen atom using Bohr's postulates and not neglecting the coulombic attraction on proton. I know that they will be revolving around their centre ...
1
vote
5answers
922 views

How does the electron jump across “gaps” in its orbital?

I saw on perhaps COSMOS, and have heard mention from other professors, that electrons sort of "teleport" or something, in their orbital and the quantum level. So looking at the orbitals for a lone ...
1
vote
2answers
258 views

Centrifugal force in the Hydrogen atom for $L=0$

I have found the following interesting article: http://arxiv.org/abs/0706.0924 The authors examine the radial momentum operator in detail, in particular its time evolution due to the forces acting ...
4
votes
1answer
523 views

What are independent parameters in Hellmann–Feynman theorem?

A typical example in textbooks about the application of Hellmann–Feynman theorem is calculating $\left\langle\frac{1}{r^2}\right\rangle$ in hydrogen-like atoms. Wikipedia has a nice demonstration of ...
0
votes
1answer
356 views

Difference between a hydrogen ion and a proton

I've run into a bit of a problem on this weeks coursework. A proton and an electron initially at rest combine to form hydrogen. Find the wavelength of the emitted photon? So, as far as I can ...
2
votes
0answers
30 views

What symmetry operation mixes states with different $\ell$ in hydrogen atom? [duplicate]

We can mix states with different $m$ in hydrogen atom by rotating it around some axis (not coinciding with $z$). Thus rotation is the symmetry operation which mixes states with different $m$. As ...
8
votes
3answers
708 views

Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
5
votes
2answers
262 views

Spin-orbit coupling from the rest frame of the proton?

When we calculate the spin-orbit interaction in a Hydrogen atom we just work in the electron's frame of reference: the proton is moving and produces a magnetic field which the electron's spin ...
4
votes
4answers
237 views

How big is an excited hydrogen atom?

Suppose an empty universe with the exception of a single hydrogen atom (1 proton, 1 electron). The electron may be in its ground state or it may be excited a certain number of levels. Suppose it is at ...
2
votes
1answer
64 views

Choice of the z-axis in the Schrödinger equation for the hydrogen atom

I am reading about the solution of the Schrödinger equation for the hydrogen atom and have a question about the choice of the z-axis. Most websites say that the z-axis is arbitrarily chosen. If so, ...
3
votes
2answers
62 views

Behavior of Ortho- and Para-hydrogen in a Magnetic Field

At low enough temperature, at equillbrium, the dihydrogen molecule is predominately parahydrogen, with the spins of the two protons opposite. Does an external magnetic field alter the ortho-para ...
15
votes
1answer
1k views

How would one detect antihydrogen in the universe?

Since the spectra of hydrogen and antihydrogen are the same, how do astronomers know which one they're detecting? Is, perhaps, the Lamb shift in antihydrogen different?
1
vote
0answers
90 views

The classical hydrogen atom

Suppose we want to analyze a hydrogen atom using purely classical mechanics. This obviously is not exactly how things work - quantum mechanics plays a huge role and probability distributions are ...
2
votes
0answers
87 views

Why is metallic hydrogen degenerate matter?

Why is metallic hydrogen considered a form of degenerate matter, akin to neutronium and electron-degenerate matter? I can understand that for the other two, degeneracy pressure is the only force ...
1
vote
1answer
10k views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
0
votes
0answers
80 views

Greens function/resolvent of hydrogen Hamiltonian

Let $H$ be the Hamiltonian for the nonrelativistic hydrogen atom, i.e. $$H=-\frac{1}{2}\Delta-\frac{1}{r}$$ I am searching for an asymptototic expansion of the Greens function or respectively the ...