0
votes
0answers
6 views

Schrodingers Equation for Helium ion

Since an analytical solution exists for a Hydrogen atom and the primary problem with solving the Helium atom is the coulombic interactions between the electrons, why is it that no analytical solution ...
3
votes
1answer
146 views

Is there only radial motion in the Hydrogen ground state?

The ground state of the Hydrogen atom is spherically symmetric. In other words, the wave function Psi depends only on the distance r of the electron from the nucleus. As a consequence all ...
1
vote
1answer
320 views

What is the difference between the Bohr model of the atom and Schrödinger's model?

What is the difference between the Bohr model of the atom and The solution of the Schrödinger equation for the hydrogen atom? Are there any difference between definition of the electric potential ...
1
vote
4answers
182 views

How does the electron jump across “gaps” in its orbital?

I saw on perhaps COSMOS, and have heard mention from other professors, that electrons sort of "teleport" or something, in their orbital and the quantum level. So looking at the orbitals for a lone ...
1
vote
1answer
46 views

Eigenfunctions for $1s$ hydrogen Schrodinger equation

I am a computer scientist and started my Phd in material science. The second course os my Phd is material simulation by computer. One the task is show the verification of the eigenfunction $1s$ from ...
0
votes
0answers
24 views

Quantum mechanics for macroscopic charges?

OK first off tell me if my understanding of the following is correct: In a Hydrogen atom, one would expect that the opposite charges (electron and nucleus) to attract each other, according to ...
1
vote
2answers
76 views

Stability of the hydrogen atom and positronium

I am trying to get a better understanding of why positronium decays while a hydrigen atom is stable. In the case of positronium, I can write an elementary process were the leptons annihilate into two ...
4
votes
2answers
290 views

Neil deGrasse Tyson says that electrons “teleport” between energy levels?

This page: https://blog.afach.de/?p=62 Discusses the error Neil deGrasse Tyson made when talking about electronic transitions (video included there). Tyson clearly said in his Cosmos series that ...
0
votes
2answers
77 views

Estimating the radius of the Hydrogen atom

I've seen people estimate the Bohr radius using the uncertainty principle by assuming that $$\Delta x \sim r$$ and $$\Delta p \sim p$$ then $$p \approx \frac{\hbar}{r}$$ Using this assumption will ...
4
votes
1answer
79 views

Does first quantization perturbation theory imply a large scale web of electron entanglement?

My question may seem quite esoteric given the title, but I think it's relatively straightforward when explained properly. Imagine a relatively simple situation of 2 hydrogen atoms (numbered 1 and 2), ...
0
votes
0answers
67 views

Why is the $SO(4)$ symmetry of the Hydrogen atom called dynamical?

Why dynamical? My previous quantum mechanics teacher could not answer it.
1
vote
1answer
84 views

I am trying to calculate how $<r>$ in the hydrogen atom evolves with time

I am working on the Hydrogen atom and I was trying to calculate $\frac{d<r>}{dt}$ using $$\frac{d<r>}{dt} = \frac{i}{\hbar} <[\hat{H} , \hat{r}]>.$$ Here $r = \sqrt(x^2 + y^2 + z^2)$ ...
1
vote
0answers
94 views

tritium beta decay - probability of being in 1s state

Hydrogen-like wavefunctions have the form: $$R_{10} = \left(\frac{Z}{a_0}\right)^{\frac{3}{2}} 2\space e^{-\frac{Zr}{a_0}}$$ $$Y_{00} = \frac{1}{\sqrt {4\pi}} $$ where $a_0 = \frac{4\pi \epsilon_0 ...
3
votes
3answers
176 views

Why are hydrogen energy levels degenerate in $\ell$ and $m$?

Is there a good physical picture of why the energy levels in a hydrogen atom are independent of the angular momentum quantum number $\ell$ and $m$?
3
votes
1answer
61 views

State with non-zero angular momentum - cannot be described by spherical harmonic?

For a state with non-zero angular momentum, why is it that it cannot be described by the spherically symmetric spherical harmonic?
0
votes
1answer
104 views

Is it possible to find the hydrogen atom's radial wavefunctions?

Is there a way to actually find the equation of $R(r)$ without looking at a table with these equations already given? I'm given $n$, $\ell$, and $m$.
1
vote
1answer
72 views

Obtain the eigenfunction of Jz for the wave function of an electron in a hydrogen atom? [closed]

The wave function of an electron in a hydrogen atom is given by Is this wave function an eigenfunction of Jz , the z-component of the electron’s total angular momentum? If yes, find the ...
5
votes
1answer
143 views

Spin-orbit coupling from the rest frame of the proton?

When we calculate the spin-orbit interaction in a Hydrogen atom we just work in the electron's frame of reference: the proton is moving and produces a magnetic field which the electron's spin ...
2
votes
2answers
579 views

Calculating the most probable radius for an electron of a hydrogen atom in the ground state

This link describes a method for determining the most probable radius of an electron for a Hydrogen atom in the ground state. It states that : The radial probability density for the hydrogen ...
11
votes
5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
1
vote
1answer
48 views

Can scientists tell the energy levels of the atom?

In the hydrogen spectral series how did the scientists know the number of the energy level which the electron is moving from or to?
2
votes
0answers
70 views

Limits of integration for the radial wave function of the Hydrogen atom in the WKB approximation

I am working a problem where we have to find the energy eigenvalues for the radial wave function of the hydrogen atom for $\ell=0$ using the WKB approximation. I am sure that I set up the integral ...
0
votes
0answers
93 views

Difference between expectation values of $L^2$, $L_z$ and measuring $L^2$, $L_z$

I was given with this hydrogen radial wavefunction $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ and was asked to find a) What are the expectation values of the ...
0
votes
1answer
171 views

Expectation value of energy from the position state of hydrogen atom [closed]

I was given with the position state of hydrogen atom: $$ R_{21} =\left(\sqrt{\frac{1}{3}}Y^0_1 + \sqrt{\frac{2}{3}}Y^1_1\right) $$ I am getting confused about getting the expectation value of ...
3
votes
2answers
347 views

What is the expected distance of the electron from the nucleus in the hydrogen atom?

Specifically, I would like to know the general formula, in terms of $n$ and $l$, assuming the electron is in an orbital (i.e. simultaneous eigenstate of $H$, $L^2$, and $L_z$). I understand that it ...
2
votes
2answers
145 views

Hydrogen atom: potential well and orbit radii

I happened to open up an old solid-state electronics book by Sah, and in it he says: "it is evident that the electron orbit radius is half the well radius at the energy level En" The orbit radius is ...
0
votes
0answers
83 views

Perturbation of a Hydrogen Atom in a Quadrupole Field

Question: A hydrogen atom is located in a quadrupole field, which gives it a perturbation $$H_1=A(x^2-y^2)$$ where $A$ is some constant. Calculate the ...
1
vote
3answers
256 views

Is there any time-dependent hydrogen atom Schrödinger equation, solvable analytically?

It's well-known that hydrogen atom described by time-independent Schrödinger equation (neglecting any relativistic effects) is completely solvable analytically. But are any initial value problems for ...
0
votes
1answer
95 views

Angular momentum of hydrogen from $n,l,m$ values

Given a wavefunction for hydrogen $\psi(n,l,m)$ it is possible to calculate its associated energy from $E=-13.6/n^2$. Does a similar equation exist for $L^2$ and $L_z$? That is, if we are given the ...
5
votes
3answers
694 views

Why is a proton assumed to be always at the center while applying the Schrödinger equation?

Why is a proton assumed to be always at the center while applying the Schrödinger equation? Isn't it a quantum particle?
7
votes
2answers
452 views

How can one see that the Hydrogen atom has $SO(4)$ symmetry?

For solving hydrogen atom energy level by $SO(4)$ symmetry, where does the symmetry come from? How can one see it directly from the Hamiltonian?
5
votes
2answers
1k views

What made Bohr quantise angular momentum and not some other quantity?

Bohr's second postulate in Bohr model of hydrogen atom deals with quantisation of angular momentum.But, I was wondering why he quantised angular momentum and any other quantity?
2
votes
1answer
138 views

Possible Outcomes from Measuring a Hydrogen Atom

A hydrogen atom is characterized by the wavefunction $$\mid \psi \rangle =\sqrt{\frac{2}{7}}\mid 4\,2\,1\rangle +\sqrt{\frac{1}{7}}\mid 2 \,1\,\bar{1}\rangle+\sqrt{\frac{4}{7}}\mid 3\,2\,0\rangle$$ ...
5
votes
1answer
549 views

Orthonormality of Radial Wave Function

Is the radial component $R_{n\ell}$ of the hydrogen wavefunction orthonormal? Doing out one of the integrals, I find that $$\int_0^{\infty} R_{10}R_{21}~r^2dr ~\neq~0$$ However, the link below says ...
1
vote
1answer
608 views

Writing a Wavefunction as a Linear Combination of Eigenstates

We have the following wavefunction for the hydrogen atom: $$\psi(r,\theta,\phi)=\frac{1}{\sqrt{4\pi}}\frac{1}{(2a)^{3/2}}\frac{r}{a}e^{-r/2a}\sin(\theta)\sin(\phi)$$ where $a$ is the Bohr radius. ...
0
votes
0answers
265 views

Orthonormality of Radial Wave Function in the Hydrogen Atom

Question: Show that the radial wave function for the hydrogen atom are orthogonal with no exceptions. Attempt: We know that ...
5
votes
1answer
545 views

Reduced mass in quantum physics (Hydrogen Atom)

I've gone through an intermediate classical mechanics course, and in solving the two-body problem, we reduce it to a one-body between a larger stationary mass, and a smaller reduced mass. Most ...
2
votes
1answer
84 views

Why does bringing N 1-orbital atoms together yield N levels?

A common example of this is that when bringing N hydrogen atoms together into a ring. Far apart, assume each electron exists in the 1s state. As we bring them together, instead of each electron ...
2
votes
1answer
160 views

Volume charge density of H-atom

I have a problem where I am supposed to calculate the volume charge density of a neutral hydrogen atom. The potential is given to be $$ \Phi = k \frac{e^{-ar}}{r} \left(1 + \frac{ar}{2}\right) $$ Now ...
1
vote
1answer
317 views

Hydrogen ground state energy calculation?

We want to find the energy of a hydrogen atom ($Z=1$) in the ground state $$ \psi_{100} = \frac{1}{\sqrt{\pi}}e^{-r}\ \ \ \ \ \ (\mbox{atomic units}) $$ with Hamiltonian $$ H = ...
1
vote
2answers
147 views

Transition integral from 1-D cartesian into 3-D polar coordinate system

Lets say we have an electron which can be in two states. Its wavefunction for two states is then $\Psi=A\Psi_n + B\Psi_m$, where $\Psi$ is time dependent wave function. I know that the transition ...
1
vote
2answers
1k views

The probability of finding the electron in the H-atom

In the book Arthur Beiser - Concepts of modern physics [page 213] author separates the variables in the polar Schrödinger equation assuming: $$\psi_{nlm}=R(r)\Phi(\phi)\Theta(\theta)$$ then there a ...
2
votes
1answer
206 views

Orbital of Hydrogen molecule

does anybody here know an analytical approximation of the bonding hydrogen orbital MOLECULE? I am looking for a good approximation to this orbital, that might be in some textbooks to get an ...
0
votes
1answer
204 views

How to determine the region that would contain a quantum particle

(a) A hydrogen atom is in its ground state. If space is divided into identical infinitesimal cubes, in which cube is the electron most likely to be found? If instead space is divided into 31 ...
1
vote
1answer
523 views

Solution of 1-D Schrodinger equation for the potential $V(x) = -\frac{1}{|x|}$

May be this question might have already been asked but i couldn't find it, so let me know if its already there. Consider a potential, $V(x) = -\frac{1}{|x|}$ and if we apply this to a one dimensional ...
5
votes
1answer
369 views

How can we describe the electrons of multi-electron atoms (i.e. not Hydrogen) when equations/analytic solutions only exist for Hydrogen?

I've been digging into emission spectra of different elements and found that such things as the Rydberg equation, Bohr's model, and quantum mechanics can only fully describe the single electron in the ...
4
votes
1answer
1k views

Stark Effect on the 1st excited state of Hydrogen

I know the ground state of hydrogen is unaffected by the Stark effect to first order. And I also know that the 1st excited state is split from 4 degenerate states to 2 distinct, and 1 degenerate state ...
1
vote
1answer
568 views

Finding the wavelength of an electron in its ground state?

To find the wavelength of an electron in its ground state in a hydrogen atom, would I or could I do the following? Use the ground state energy (-13.6eV) in $E^2 = m^2c^4 + p^2c^2$ Solve for $p$ Use ...
2
votes
1answer
242 views

Ground state energy of hydrogen molecule ion

In this paper, it is mentioned: Furthermore, since the energy of $H_2^+$in the ground state must be lower than that of an H atom in the ground state,the negative (attractive) forces in the ...
2
votes
2answers
283 views

Why the hydrogen radial wave function is real?

Why the hydrogen radial wave function is real? Is it a coincidence?