11
votes
5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
1
vote
1answer
611 views

Writing a Wavefunction as a Linear Combination of Eigenstates

We have the following wavefunction for the hydrogen atom: $$\psi(r,\theta,\phi)=\frac{1}{\sqrt{4\pi}}\frac{1}{(2a)^{3/2}}\frac{r}{a}e^{-r/2a}\sin(\theta)\sin(\phi)$$ where $a$ is the Bohr radius. ...
4
votes
1answer
319 views

Scattering states of Hydrogen atom in non-relativistic perturbation theory

In doing second order time-independent perturbation theory in non-relativistic quantum mechanics one has to calculate the overlap between states $$E^{(2)}_n ~=~ \sum_{m \neq n}\frac{|\langle m | H' ...