Applies also to pre-Hilbert spaces, rigged Hilbert spaces, and spaces with negative norm or zero-norm states.

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185 views

Transition Between Position and Momentum Basis

I'm having some trouble following pages 55-56 of Sakurai's Modern Quantum Mechanics. We're trying to transfer from position space into momentum space. Here's a quote: Let us now establish the ...
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3answers
110 views

Can one construct a new operator in terms of the powers of another operator?

Suppose we have a quantum state, well described by its time-independent wave function Psi. And we have a well-defined Hermitian (self-adjoint) operator $A$. We successfully evaluate the expectation ...
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46 views

Self-adjoint extensions with 'teletransporting' boundary conditions

When choosing a self-adjoint extension of a Hamiltonian, in general one can obtain domains in which (i) the probabilities teleport* between points on the boundary and (ii) boundary conditions ...
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2answers
204 views

Ground state of a quantum mechanical system

When looking back at my courses of quantum mechanics, I noticed that assumptions about the ground state of a quantum mechanical system where rather vague and unprecise. It is always assumed that a ...
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1answer
101 views

Expectation value of an operator

Suppose we have: $$ \hat{Q}|\psi_1\rangle=q_1|\psi_1\rangle \\ \hat{Q}|\psi_2\rangle=q_2|\psi_2\rangle $$ with $q_1 \neq q_2$. Then consider the state: $$ ...
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2answers
128 views

Representations in quantum mechanics [closed]

This might be a very simple question. I just want someone to point me the right direction to understand things like this: $$ \langle x|x'\rangle=\delta(x-x') \\ \psi(x)=\langle x|\psi\rangle \\ ...
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1answer
58 views

Atom state vectors kets

An atom with two energy levels has 2 states (excited and ground), represented by kets $|e\rangle$ and $|g\rangle$ respectively. The atom has energy $\frac{1}{2}E_\theta$ when excited and ...
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2answers
80 views

Query on an operator acting on a function

I have a naive question about an operator acting on a well-behaved function. Let us say, we are talking about space translation operator acting on a function $\psi(x)$: ...
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1answer
203 views

Time derivative of the state vector as expressed in abstract Hilbert space vs. as a wavefunction

The Schrodinger equation in Hilbert space is expressed as : $$\frac{\partial}{\partial t} \psi(t) = \frac{-i}{\hbar}H\psi(t). $$ Here $\frac{\partial}{\partial t} \psi(t) \equiv \psi'(t) \equiv\lim ...
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1answer
201 views

How are matrices used to represent quantities, and what is the meaning of a matrix?

So I'm reading this text on Quantum Mechanics, and it goes through a few chapters that I understand fairly well including probability. But then it says that all quantities, like position and energy ...
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2answers
158 views

Representation of indistinguishability in quantum mechanics

I was wondering that if particles are indistinguishable in quantum mechanics, then why do we still express their states $\left| \uparrow \downarrow \right\rangle$, as meaning particle 1 (in the first ...
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1answer
221 views

After using annihilation operator on vacuum state, why it is $0$ instead of vacuum?

For bosonic systems, why $a|0\rangle=0$ and not $a|0\rangle=|0\rangle$?
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76 views

How to make a base tranformation for a linear operator in QM? [closed]

I have 2 bases A and B with the following kets: Base A: $|a_1\rangle$ and $|a_2\rangle$ Base B: $|b_1\rangle = \frac{1}{\sqrt2} \cdot(|a_1\rangle + i\cdot|a_2\rangle)$ $|b_2\rangle = ...
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0answers
84 views

Quantum Rigid Rotor Perturbation

As the title says, I have a rigid rotor with a perturbation given below $$H=\frac{L^2}{2I}-\alpha B L_z.$$ So I know that the eigenvalues of $H$ will be $\ell(\ell+1)/2I -\alpha B m$ where $m$ is our ...
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2answers
163 views

What is the precise definition of state of a quantum system?

On studying quantum states of the hydrogen atom, I came with a question: what is the precise definition of a quantum state? Particularly, when solving the Schroedinger eq for the H using separation of ...
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1answer
115 views

Are there two different ways to express the position operator $x$ in terms of the creation and annihilation operator?

As we known, to express the position operator $x$ in terms of the creation and annihilation operator $a^{+}$ and $a$, one way is: $$x= \sqrt{\frac{\hbar}{2\mu\omega}}(a^++a);$$ $$p= ...
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2answers
165 views

Lippmann-Schwinger solution

What's wrong with this general solution of the Lippmann-Schwinger equation: $$ |\psi_k \rangle=|\phi_k \rangle+G_k V|\psi_k \rangle $$ Taking the inner product with $\langle\phi_{k'}|$ \begin{align} ...
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1answer
198 views

A question about the energy of turning on and off interaction adiabatically in QFT

I read a saying as follows: In a theory with no particles which decay and no bound states, the turning on and off of the interactions merely serves to limit the effective range of forces. In this ...
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4answers
899 views

Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ ...
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0answers
145 views

What are you studying when you study a Harmonic Oscillator in QM?

This probably is a naive question - so please forgive a self-studier. In the text I am studying, one builds a HO by placing a particle in a potential that increases quadratically from the origin. The ...
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2answers
115 views

Is there any non-hermitian operator on Hilbert Space with all real eigenvalues?

The property of hermitian is the sufficient condition for eigenvalue being real. Is there any non-hermitian operator on Hilbert Space with all real eigenvalues? If there exist, then can all ...
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2answers
185 views

Understanding Well Defined States

I am self-studying from a text in QM. Well defined states are mentioned several times. By and large these are consistent and seem to be readily apparent: states of well defined energy are basis ...
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1answer
65 views

Converting between (abstract) linear operators and their position representations

Just as we have an abstract state vector $|\psi\rangle$ and its position representation $\psi(\vec{x}) = \langle \vec{x} | \psi \rangle$, how do we transform between a linear operator, say $H$, that ...
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1answer
125 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
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2answers
134 views

Quantum Mechanics - Observable

If $O$ represents an operator corresponding to an observable why does the following equality hold? $$\langle f(x)\, |\, O g(x)\rangle = \langle g(x) \,|\, O f(x) \rangle$$ It is used on the last ...
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1answer
503 views

Diagonalization of Hamiltonian

Typically, one way of understanding the physics of an interacting quantum system is by diagonalizing the Hamiltonian. In principle, can we always diagonalize a Hamiltonian, such that it is expressed ...
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2answers
181 views

Projection operators and their subspaces (of Hilbert space)

I've been watching Susskind's lectures on Quantum Entanglement, and something he said regarding (non-)commuting projection operators confused me. Consider two subspaces {$|a>$} and {$|b>$} of ...
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1answer
143 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
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3answers
647 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
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5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
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1answer
208 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
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2answers
114 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
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107 views

Unitary transformation between complete + orthonormal bases

Suppose the complete orthonormal bases $\{|\psi_n\rangle\}$ and $\{|\psi{'}_n\rangle\}$ are related by the transformation matrix $U$: $$ |\psi{'}_n\rangle = U|\psi_n\rangle \\ \langle\psi{'}_n| = ...
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1answer
165 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
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1answer
36 views

Uncertainty Definition QM

On my introductory course in Quantum Mechanics, the uncertainty of an operator $A$ in the state $\psi$ is defined by $$(\Delta A)^2_{\psi}=\langle(A-\langle A \rangle_{\psi})^2\rangle _{\psi}$$ I'm ...
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2answers
144 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
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2answers
525 views

Hilbert space in quantum mechanics

I think in quantum mechanics we assign to each system a specific Hilbert space i.e. if systems are different then their Hilbert spaces are different. Is this true? If not why? For differernt system I ...
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1answer
310 views

Quantum Mechanics - Rectangular Potential Barrier - Normalisation

I have a quick question regarding the normalisation of the wave function of a particle incident on a potential barrier specifically regarding the normalisation of the wave functions. The problem is ...
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1answer
509 views

Non-Hermitian operator with real eigenvalues?

So we know that in Quantum Mechanics we require the operators to be Hermitian, so that their eigenvalues are real ($\in \mathbb{R}$) because they correspond to observables. What about a non-Hermitian ...
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96 views

Momentum and position operators in Schrödinger representation

I was going through some intro notes on path integral (for QFT), and am stuck with this equation for position and momentum in Schrödinger (position) representation, $$ \hat{1} =\int ...
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3answers
699 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
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1answer
122 views

Comparing two infinite sets

All the linearly independent eigenfunctions of the parity operator $\mathcal{P}$ form an infinite set and all the linearly independent eigenfunctions of the unit operator $\bf 1$ also form an ...
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2answers
275 views

Matrix elements of linear operators - orthonormal basis required?

In an early linear algebra class of mine, I learnt that a linear map $\mathcal{A}$ acting on a vector space could be represented by a matrix $A_{ij}$ according to the rule: $$\mathcal{A}({e_j}) = ...
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2answers
165 views

Precise meaning of composition of ket and bra, e.g. $|\psi\rangle\langle\psi|$

I'm currently studying density matrices, and have been frequently coming across the construction $$|\psi\rangle\langle\psi| \,.$$ What is the formal meaning of this composition? I understand ...
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1answer
556 views

Correspondence between wave function and state vector

I am confused with connection between state $| \psi \rangle$ of a quantum system and corresponding wave function $\psi(x)$ (at a given time). I have been told that for every state $| \psi \rangle$ we ...
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55 views

How do I properly express adding perturbed states to unperturbed states?

I have a problem set due tomorrow, and the last problem is driving me nuts. Been combing through griffiths trying to find similar examples to no avail, so it'd be greatly appreciated if stackexchange ...
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172 views

Why do some terms vanish in first-order perturbation theory?

In first order perturbation theory, we usually express the first order perturbation in the eigenket of the perturbed Hamiltonian in the basis of the unperturbed Hamiltonian $H_{0}$: ...
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1answer
293 views

Writing an arbitrary operator in bra-ket notation

An annoying fact about my physics textbook (Griffiths' Introduction to Quantum Mechanics) is that it introduces bra-ket notation without telling us how to use it. So I have a two-part question for SE: ...
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1answer
86 views

How to find different operator representations in QM?

I read that any observable operator may be represented as: $$\Omega = \sum_n \omega _n | \omega _n \rangle \langle \omega_n |$$ Where the little omegas are the eigenvectors/eigenvalues of the ...
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1answer
663 views

Self-adjoint and unbounded operators in QM

An operator $A$ is said to be self-adjoint if $(\chi,A\psi)=(A\chi,\psi)$ for $\psi, \chi \in D_A$ and $D_A=D_{A^\dagger}$. But for the free particle momentum operator $\hat{p}$ these inner products ...