Applies also to pre-Hilbert spaces, rigged Hilbert spaces, and spaces with negative norm or zero-norm states.

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8
votes
1answer
175 views

Time derivative of the state vector as expressed in abstract Hilbert space vs. as a wavefunction

The Schrodinger equation in Hilbert space is expressed as : $$\frac{\partial}{\partial t} \psi(t) = \frac{-i}{\hbar}H\psi(t). $$ Here $\frac{\partial}{\partial t} \psi(t) \equiv \psi'(t) \equiv\lim ...
4
votes
1answer
130 views

How are matrices used to represent quantities, and what is the meaning of a matrix?

So I'm reading this text on Quantum Mechanics, and it goes through a few chapters that I understand fairly well including probability. But then it says that all quantities, like position and energy ...
5
votes
2answers
106 views

Representation of indistinguishability in quantum mechanics

I was wondering that if particles are indistinguishable in quantum mechanics, then why do we still express their states $\left| \uparrow \downarrow \right\rangle$, as meaning particle 1 (in the first ...
1
vote
0answers
60 views

How to make a base tranformation for a linear operator in QM? [closed]

I have 2 bases A and B with the following kets: Base A: $|a_1\rangle$ and $|a_2\rangle$ Base B: $|b_1\rangle = \frac{1}{\sqrt2} \cdot(|a_1\rangle + i\cdot|a_2\rangle)$ $|b_2\rangle = ...
1
vote
0answers
48 views

Quantum Rigid Rotor Perturbation

As the title says, I have a rigid rotor with a perturbation given below $$H=\frac{L^2}{2I}-\alpha B L_z.$$ So I know that the eigenvalues of $H$ will be $\ell(\ell+1)/2I -\alpha B m$ where $m$ is our ...
4
votes
2answers
132 views

What is the precise definition of state of a quantum system?

On studying quantum states of the hydrogen atom, I came with a question: what is the precise definition of a quantum state? Particularly, when solving the Schroedinger eq for the H using separation of ...
4
votes
1answer
99 views

Are there two different ways to express the position operator $x$ in terms of the creation and annihilation operator?

As we known, to express the position operator $x$ in terms of the creation and annihilation operator $a^{+}$ and $a$, one way is: $$x= \sqrt{\frac{\hbar}{2\mu\omega}}(a^++a);$$ $$p= ...
0
votes
1answer
96 views

Lippmann-Schwinger solution

What's wrong with this general solution of the Lippmann-Schwinger equation: $$ |\psi_k \rangle=|\phi_k \rangle+G_k V|\psi_k \rangle $$ Taking the inner product with $\langle\phi_{k'}|$ \begin{align} ...
4
votes
1answer
120 views

A question about the energy of turning on and off interaction adiabatically in QFT

I read a saying as follows: In a theory with no particles which decay and no bound states, the turning on and off of the interactions merely serves to limit the effective range of forces. In this ...
4
votes
4answers
262 views

Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ ...
2
votes
0answers
122 views

What are you studying when you study a Harmonic Oscillator in QM?

This probably is a naive question - so please forgive a self-studier. In the text I am studying, one builds a HO by placing a particle in a potential that increases quadratically from the origin. The ...
1
vote
1answer
54 views

Is there any non-hermitian operator on Hilbert Space with all real eigenvalues?

The property of hermitian is the sufficient condition for eigenvalue being real. Is there any non-hermitian operator on Hilbert Space with all real eigenvalues? If there exist, then can all ...
3
votes
2answers
138 views

Understanding Well Defined States

I am self-studying from a text in QM. Well defined states are mentioned several times. By and large these are consistent and seem to be readily apparent: states of well defined energy are basis ...
1
vote
1answer
48 views

Converting between (abstract) linear operators and their position representations

Just as we have an abstract state vector $|\psi\rangle$ and its position representation $\psi(\vec{x}) = \langle \vec{x} | \psi \rangle$, how do we transform between a linear operator, say $H$, that ...
1
vote
1answer
107 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
0
votes
2answers
124 views

Quantum Mechanics - Observable

If $O$ represents an operator corresponding to an observable why does the following equality hold? $$\langle f(x)\, |\, O g(x)\rangle = \langle g(x) \,|\, O f(x) \rangle$$ It is used on the last ...
3
votes
1answer
169 views

Diagonalization of Hamiltonian

Typically, one way of understanding the physics of an interacting quantum system is by diagonalizing the Hamiltonian. In principle, can we always diagonalize a Hamiltonian, such that it is expressed ...
0
votes
2answers
102 views

Projection operators and their subspaces (of Hilbert space)

I've been watching Susskind's lectures on Quantum Entanglement, and something he said regarding (non-)commuting projection operators confused me. Consider two subspaces {$|a>$} and {$|b>$} of ...
1
vote
1answer
110 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
2
votes
3answers
171 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
11
votes
5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
1
vote
1answer
95 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
1
vote
2answers
100 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
1
vote
2answers
77 views

Unitary transformation between complete + orthonormal bases

Suppose the complete orthonormal bases $\{|\psi_n\rangle\}$ and $\{|\psi{'}_n\rangle\}$ are related by the transformation matrix $U$: $$ |\psi{'}_n\rangle = U|\psi_n\rangle \\ \langle\psi{'}_n| = ...
4
votes
1answer
98 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
1
vote
1answer
33 views

Uncertainty Definition QM

On my introductory course in Quantum Mechanics, the uncertainty of an operator $A$ in the state $\psi$ is defined by $$(\Delta A)^2_{\psi}=\langle(A-\langle A \rangle_{\psi})^2\rangle _{\psi}$$ I'm ...
1
vote
2answers
91 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
1
vote
2answers
301 views

Hilbert space in quantum mechanics

I think in quantum mechanics we assign to each system a specific Hilbert space i.e. if systems are different then their Hilbert spaces are different. Is this true? If not why? For differernt system I ...
1
vote
1answer
105 views

Quantum Mechanics - Rectangular Potential Barrier - Normalisation

I have a quick question regarding the normalisation of the wave function of a particle incident on a potential barrier specifically regarding the normalisation of the wave functions. The problem is ...
2
votes
1answer
154 views

Non-Hermitian operator with real eigenvalues?

So we know that in Quantum Mechanics we require the operators to be Hermitian, so that their eigenvalues are real ($\in \mathbb{R}$) because they correspond to observables. What about a non-Hermitian ...
0
votes
0answers
45 views

Completeness of the state space and Hilbert space [duplicate]

I am wondering just why is it supposed that quantum states lie in a Hilbert space, which mathematically requires completeness? In other words, what does completeness (defined in terms of Cauchy ...
1
vote
0answers
78 views

Momentum and position operators in Schrödinger representation

I was going through some intro notes on path integral (for QFT), and am stuck with this equation for position and momentum in Schrödinger (position) representation, $$ \hat{1} =\int ...
3
votes
3answers
226 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
0
votes
1answer
114 views

Comparing two infinite sets

All the linearly independent eigenfunctions of the parity operator $\mathcal{P}$ form an infinite set and all the linearly independent eigenfunctions of the unit operator $\bf 1$ also form an ...
3
votes
2answers
119 views

Matrix elements of linear operators - orthonormal basis required?

In an early linear algebra class of mine, I learnt that a linear map $\mathcal{A}$ acting on a vector space could be represented by a matrix $A_{ij}$ according to the rule: $$\mathcal{A}({e_j}) = ...
6
votes
2answers
110 views

Precise meaning of composition of ket and bra, e.g. $|\psi\rangle\langle\psi|$

I'm currently studying density matrices, and have been frequently coming across the construction $$|\psi\rangle\langle\psi| \,.$$ What is the formal meaning of this composition? I understand ...
0
votes
0answers
14 views

Is the additivity property of the quantum states valid only for countable families of pairwise orthogonal projections?

Consider a generic Hilbert spaces and a map $$ \mu:P(H)\longrightarrow [0,1] $$ such that $\mu(I)=1$ and $$ \mu\left(\mbox{s-}\sum_{i\in\mathcal{I}}P_i\right)=\sum_{i\in\mathcal{I}}\mu(P_i) $$ for ...
1
vote
1answer
191 views

Correspondence between wave function and state vector

I am confused with connection between state $| \psi \rangle$ of a quantum system and corresponding wave function $\psi(x)$ (at a given time). I have been told that for every state $| \psi \rangle$ we ...
1
vote
0answers
48 views

How do I properly express adding perturbed states to unperturbed states?

I have a problem set due tomorrow, and the last problem is driving me nuts. Been combing through griffiths trying to find similar examples to no avail, so it'd be greatly appreciated if stackexchange ...
2
votes
0answers
152 views

Why do some terms vanish in first-order perturbation theory?

In first order perturbation theory, we usually express the first order perturbation in the eigenket of the perturbed Hamiltonian in the basis of the unperturbed Hamiltonian $H_{0}$: ...
0
votes
1answer
130 views

Writing an arbitrary operator in bra-ket notation

An annoying fact about my physics textbook (Griffiths' Introduction to Quantum Mechanics) is that it introduces bra-ket notation without telling us how to use it. So I have a two-part question for SE: ...
0
votes
1answer
79 views

How to find different operator representations in QM?

I read that any observable operator may be represented as: $$\Omega = \sum_n \omega _n | \omega _n \rangle \langle \omega_n |$$ Where the little omegas are the eigenvectors/eigenvalues of the ...
8
votes
1answer
261 views

Self-adjoint and unbounded operators in QM

An operator $A$ is said to be self-adjoint if $(\chi,A\psi)=(A\chi,\psi)$ for $\psi, \chi \in D_A$ and $D_A=D_{A^\dagger}$. But for the free particle momentum operator $\hat{p}$ these inner products ...
0
votes
3answers
107 views

Position and momentum bases in quantum mechanics

I have seen the following two descriptions of the position basis: $$\tag{1}| x\rangle=\delta(x-x_0)$$ and also $$\tag{2}\langle x_0| x\rangle=\delta(x-x_0),$$ which (if either) of these is ...
2
votes
1answer
81 views

Normal ordering of the identity operator

I'm puzzled about what should be the normal ordering of the identity operator (or any proportional operator): looking at it from the "Fock space operators POV",the prescription is to move all the ...
2
votes
1answer
69 views

Eigenfunction associated with the $\hat{x}$ operator

Consider the following operator $\hat{x}=i\hbar \frac{\partial}{\partial p}$. I am trying to show that the eigenfunctions of $\hat{x}$ are not square-normalizable. I am interested in doing so since ...
3
votes
1answer
140 views

Bounded and Unbounded Operator

Can someone explain with a concrete example of how can I can check whether a quantum mechanical operator is bounded or unbounded? EDIT: For example., I would like to check whether $\hat ...
3
votes
1answer
71 views

Self-adjoint and nonpositive differential operators

I recently tumbled over a statement in a geophysics paper (PDF here). They have a wave equation which they formulate as $$ \frac{1}{v_0}\frac{\partial^2}{\partial t^2} \begin{pmatrix}p \\ ...
5
votes
1answer
219 views

Self-adjoint differential operators

I'm having a hard time understanding the deal with self-adjoint differential opertors used to solve a set of two coupled 2nd order PDEs. The thing is, that the solution of the PDEs becomes ...
7
votes
1answer
400 views

Boosts are non-unitary!

The boost transformations are not unitary unlike rotations, the boost generators are not Hermitian. When this induces transformations in the Hilbert space, will those transformation be unitary? I ...