0
votes
1answer
28 views

(Level: Undergrad) Continuity Conditions on the Wavefunction and Initial Values

I know that a physically meaningful $\Psi$ needs to be continuous. However, recently I came across a problem in which they were considering a wavefunction for the infinite square well potential and ...
3
votes
5answers
203 views

About the definition of expectation value in quantum mechanics

In quantum mechanics, the expectation value of a observable $A$ is defined as $$\int\Psi^*\hat A\Psi$$ But in probability theory the expectation is a property of a random variable, with respect to a ...
0
votes
1answer
92 views

Quantum states and state vectors

Does a state vector correspond to only one quantum states and the components in the state vector correspond to different states of this quantum state or is it that the components of the state vector ...
0
votes
1answer
66 views

Are operators in quantum mechanics linear transformations?

Observables in quantum mechanics correspond to self-adjoint linear operators. If $\psi$ is an eigenvector of $\hat A$, then $\hat A\psi=\alpha\psi$ where $\alpha$ is the eigenvalue of $\psi$. ...
2
votes
2answers
80 views

Expanding a ket in the position basis?

My textbook says that to find the ket $|ψ\rangle$ in the same position basis as the ket $|ø\rangle$ we do the following: $$|ψ\rangle=\int dø|ø\rangle \langle ø|ψ\rangle$$ Firstly can $|ø\rangle$ be ...
3
votes
2answers
102 views

What is the analogy of $|x\rangle$ in quantum field theory?

Let me start from path integral formulation in quantum mechanics and quantum field theory. In QM, we have $$ U(x_b,x_a;T) = \langle x_b | U(T) |x_a \rangle= \int \mathcal{D}q e^{iS} \tag{1} $$ ...
5
votes
3answers
300 views

Basis in quantum mechanics

My quantum mechanics textbook (Primer of Quantum Mechanics, by Marvin Chester) says that both the momentum space and the position space are basis spaces. It also says that the momentum space is ...
0
votes
2answers
62 views

Eigenstates of an observable

Can we use eigenstates of ANY observable as base of the Hilbert space? If we can, is this equal to the statement that those eigenstates are orthogonal to each other and normalizable?
1
vote
1answer
30 views

Why does the probability of obtaining a value of a measurement follow from Dirac's general assumption?

In Dirac's The Principle of Quantum Mechanics he makes the general assumption that "if the measurement of the observable $\xi$ for the system in the state corresponding to $|x\rangle$ is made a large ...
3
votes
2answers
167 views

Position Representation in Quantum Mechanics

How does the 3d position operator look like in position representation? I know that in 1d the position operator $\hat{x}$ is just multiplication by $x$.
2
votes
3answers
103 views

I am learning Quantum Mechanics and I have some questions about some basic concept [closed]

What does a "STATE" exactly mean in quantum mechanics? What is the equivalence of "STATE" in classical mechanics? If we have a wave function $\Psi$ , its absolute square $|\Psi|^2$ is the ...
3
votes
1answer
184 views

Explanation of Dirac's proof of arbitrary ket being expressible with eigenkets of observable

In P.A.M. Dirac's The Principles of Quantum Mechanics, Chapter 10 (Observables), pp. 40, at the end of the chapter there is a proof that I don't understand at all. Here is a pdf link to the book ...
3
votes
1answer
94 views

From Symmetry Group to Physics Equations

To the extent that I know: There are symmetry groups like the rotation groups SO(3), the Groups of Poincare Transformations,... If the physics of a system has a symmetry group G, then it can be ...
1
vote
1answer
71 views

How can one calculate the phase difference between two quantum harmonic oscillator (Hermite-Gauss) states?

The analytic solutions of a quantum harmonic oscillator are given by Hermite-Gauss states, which differ in the order $n$ of the Hermite polynomials. If two such states are plotted, there will be a ...
1
vote
1answer
88 views

Infinite-dimensional Hilbert spaces in physical systems

Can anyone give an example of when infinite-dimensional Hilbert spaces are required to describe a physical system? The standard answer to this question is yes, and I'm sure some of you will be quick ...
14
votes
4answers
470 views

Density matrix formalism

The density matrix $\hat{\rho}$ is often introduced in textbooks as a mathematical convenience that allows us to describe quantum systems in which there is some level of missing information. ...
10
votes
4answers
349 views

Applying an operator to a function vs. a (ket) vector

I have a question regarding the effect of quantum mechanical operators. The definition that I'm familiar with says that an operator $A$ acts on a vector from a Hilbert space, $|\psi\rangle$, and the ...
1
vote
1answer
71 views

Inner product of position and momentum eigenkets

Let's define $\hat{q},\ \hat{p}$ the positon and momentum quantum operators, $\hat{a}$ the annihilation operator and $\hat{a}_1,\ \hat{a}_2$ with its real and imaginary part, such that $$ \hat{a} = ...
2
votes
2answers
95 views

Bloch Sphere and $SU(2) \to SO(3)$ map

For any matrix $U \in SU(2)$ there is an associated map from $S^2$ (the surface of a 3-disk) to itself defined by $\pi \circ U$, where $\pi$ is the projection map from $\mathbb{C}^2$ to $CP(1)$, that ...
0
votes
0answers
32 views

Experimental proof of the principle of superposition in QM [duplicate]

I have read that we need all operators in QM to be linear to confirm the principle of superposition which is experimentally well proven. I wonder how such an experiment could be made?
2
votes
1answer
98 views

What exactly is a coherent state and why is it interesting?

Please note that I do not have a background in physics, so if possible please refrain from a bunch of $ |x\rangle $ notations, unless clearly specifying what it symbolically means. So I have been ...
1
vote
0answers
36 views

Transition Between Position and Momentum Basis

I'm having some trouble following pages 55-56 of Sakurai's Modern Quantum Mechanics. We're trying to transfer from position space into momentum space. Here's a quote: Let us now establish the ...
1
vote
3answers
88 views

Can one construct a new operator in terms of the powers of another operator?

Suppose we have a quantum state, well described by its time-independent wave function Psi. And we have a well-defined Hermitian (self-adjoint) operator $A$. We successfully evaluate the expectation ...
2
votes
0answers
35 views

Self-adjoint extensions with 'teletransporting' boundary conditions

When choosing a self-adjoint extension of a Hamiltonian, in general one can obtain domains in which (i) the probabilities teleport* between points on the boundary and (ii) boundary conditions ...
1
vote
2answers
101 views

Ground state of a quantum mechanical system

When looking back at my courses of quantum mechanics, I noticed that assumptions about the ground state of a quantum mechanical system where rather vague and unprecise. It is always assumed that a ...
1
vote
1answer
79 views

Expectation value of an operator

Suppose we have: $$ \hat{Q}|\psi_1\rangle=q_1|\psi_1\rangle \\ \hat{Q}|\psi_2\rangle=q_2|\psi_2\rangle $$ with $q_1 \neq q_2$. Then consider the state: $$ ...
0
votes
2answers
109 views

Representations in quantum mechanics [closed]

This might be a very simple question. I just want someone to point me the right direction to understand things like this: $$ \langle x|x'\rangle=\delta(x-x') \\ \psi(x)=\langle x|\psi\rangle \\ ...
1
vote
1answer
50 views

Atom state vectors kets

An atom with two energy levels has 2 states (excited and ground), represented by kets $|e\rangle$ and $|g\rangle$ respectively. The atom has energy $\frac{1}{2}E_\theta$ when excited and ...
3
votes
2answers
71 views

Query on an operator acting on a function

I have a naive question about an operator acting on a well-behaved function. Let us say, we are talking about space translation operator acting on a function $\psi(x)$: ...
8
votes
1answer
169 views

Time derivative of the state vector as expressed in abstract Hilbert space vs. as a wavefunction

The Schrodinger equation in Hilbert space is expressed as : $$\frac{\partial}{\partial t} \psi(t) = \frac{-i}{\hbar}H\psi(t). $$ Here $\frac{\partial}{\partial t} \psi(t) \equiv \psi'(t) \equiv\lim ...
4
votes
1answer
123 views

How are matrices used to represent quantities, and what is the meaning of a matrix?

So I'm reading this text on Quantum Mechanics, and it goes through a few chapters that I understand fairly well including probability. But then it says that all quantities, like position and energy ...
5
votes
2answers
100 views

Representation of indistinguishability in quantum mechanics

I was wondering that if particles are indistinguishable in quantum mechanics, then why do we still express their states $\left| \uparrow \downarrow \right\rangle$, as meaning particle 1 (in the first ...
1
vote
0answers
60 views

How to make a base tranformation for a linear operator in QM? [closed]

I have 2 bases A and B with the following kets: Base A: $|a_1\rangle$ and $|a_2\rangle$ Base B: $|b_1\rangle = \frac{1}{\sqrt2} \cdot(|a_1\rangle + i\cdot|a_2\rangle)$ $|b_2\rangle = ...
1
vote
0answers
47 views

Quantum Rigid Rotor Perturbation

As the title says, I have a rigid rotor with a perturbation given below $$H=\frac{L^2}{2I}-\alpha B L_z.$$ So I know that the eigenvalues of $H$ will be $\ell(\ell+1)/2I -\alpha B m$ where $m$ is our ...
4
votes
2answers
127 views

What is the precise definition of state of a quantum system?

On studying quantum states of the hydrogen atom, I came with a question: what is the precise definition of a quantum state? Particularly, when solving the Schroedinger eq for the H using separation of ...
4
votes
1answer
95 views

Are there two different ways to express the position operator $x$ in terms of the creation and annihilation operator?

As we known, to express the position operator $x$ in terms of the creation and annihilation operator $a^{+}$ and $a$, one way is: $$x= \sqrt{\frac{\hbar}{2\mu\omega}}(a^++a);$$ $$p= ...
0
votes
1answer
77 views

Lippmann-Schwinger solution

What's wrong with this general solution of the Lippmann-Schwinger equation: $$ |\psi_k \rangle=|\phi_k \rangle+G_k V|\psi_k \rangle \\ \langle \phi_{k'}|\psi_k \rangle=\langle \phi_{k'} |\phi_k ...
4
votes
4answers
247 views

Complex conjugate of momentum operator

Consider momentum operator representation in position space. $$\hat{p}=-i\frac{\partial}{\partial x} \,\ \text{and its eigen functions are } e^{ipx} \,\text{and} \,\ e^{-ipx}.$$ ...
2
votes
0answers
116 views

What are you studying when you study a Harmonic Oscillator in QM?

This probably is a naive question - so please forgive a self-studier. In the text I am studying, one builds a HO by placing a particle in a potential that increases quadratically from the origin. The ...
1
vote
1answer
53 views

Is there any non-hermitian operator on Hilbert Space with all real eigenvalues?

The property of hermitian is the sufficient condition for eigenvalue being real. Is there any non-hermitian operator on Hilbert Space with all real eigenvalues? If there exist, then can all ...
3
votes
2answers
130 views

Understanding Well Defined States

I am self-studying from a text in QM. Well defined states are mentioned several times. By and large these are consistent and seem to be readily apparent: states of well defined energy are basis ...
1
vote
1answer
47 views

Converting between (abstract) linear operators and their position representations

Just as we have an abstract state vector $|\psi\rangle$ and its position representation $\psi(\vec{x}) = \langle \vec{x} | \psi \rangle$, how do we transform between a linear operator, say $H$, that ...
1
vote
1answer
95 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
0
votes
2answers
123 views

Quantum Mechanics - Observable

If $O$ represents an operator corresponding to an observable why does the following equality hold? $$\langle f(x)\, |\, O g(x)\rangle = \langle g(x) \,|\, O f(x) \rangle$$ It is used on the last ...
1
vote
1answer
106 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
2
votes
3answers
154 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
10
votes
5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
1
vote
2answers
95 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
1
vote
2answers
76 views

Unitary transformation between complete + orthonormal bases

Suppose the complete orthonormal bases $\{|\psi_n\rangle\}$ and $\{|\psi{'}_n\rangle\}$ are related by the transformation matrix $U$: $$ |\psi{'}_n\rangle = U|\psi_n\rangle \\ \langle\psi{'}_n| = ...
4
votes
1answer
89 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...