8
votes
1answer
168 views

Time derivative of the state vector as expressed in abstract Hilbert space vs. as a wavefunction

The Schrodinger equation in Hilbert space is expressed as : $$\frac{\partial}{\partial t} \psi(t) = \frac{-i}{\hbar}H\psi(t). $$ Here $\frac{\partial}{\partial t} \psi(t) \equiv \psi'(t) \equiv\lim ...
10
votes
5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
2
votes
2answers
164 views

Harmonic Oscillator - Energy quantisation

The one-dimensional quantum HO can be solved in Schrodinger representation by getting Hermite Differential Equation $$ \frac{d^2y}{dx^2} - 2x \frac{dy}{dx} + \lambda y = 0 $$ with solutions $$ y(x) = ...
1
vote
2answers
240 views

General wavefunction and Schrödinger Equation

I'm starting with quantum mechanics and the book I follow (Griffiths) first introduces the wavefunction as the probability density of the position of a 0-spin single particle. Later on I've realized ...
3
votes
2answers
109 views

Observable Operator on a Superposition?

I'm probably missing something obvious and basic here but I can't make sense of certain usages of Observables as present in basic treatments of Quantum Mechanics that i've come across. $$ ...
3
votes
1answer
359 views

How does a state in quantum mechanics evolve?

I have a question about the time evolution of a state in quantum mechanics. The time-dependent Schrodinger equation is given as $$ i\hbar\frac{d}{dt}|\psi(t)\rangle = H|\psi(t)\rangle $$ I am ...
3
votes
3answers
621 views

Can we have discontinuous wavefunctions in the Infinite Square well?

The energy eigenstates of the infinite square well problem look like the Fourier basis of L2 on the interval of the well. So then we should be able to for example make square waves that are an ...