Applies also to pre-Hilbert spaces, rigged Hilbert spaces, and spaces with negative norm or zero-norm states.

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12 views

Converting between (abstract) linear operators and their position representations

Just as we have an abstract state vector $|\psi\rangle$ and its position representation $\psi(\vec{x}) = \langle \vec{x} | \psi \rangle$, how do we transform between a linear operator, say $H$, that ...
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0answers
43 views

Quantum vector space - A complex vector space [duplicate]

Why is vector space of states, a complex vector space? and not a real vector space or perhaps a space based on a new field altogether, which we would have to create specifically for quantum mechanics? ...
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0answers
44 views

Wave Function Integral I need help conceptually and Mathematically

$$\int_{-\infty}^{\infty}\frac{\partial^2\bar{\psi}}{\partial{x^2}}\frac{\partial\psi}{\partial{x}}~dx.$$ I have read that this is equal to Zero. Only problem is that what I am reading about doesn't ...
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1answer
67 views

Diagonalization of Hamiltonian

Typically, one way of understanding the physics of an interacting quantum system is by diagonalizing the Hamiltonian. In principle, can we always diagonalize a Hamiltonian, such that it is expressed ...
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2answers
38 views

Projection operators and their subspaces (of Hilbert space)

I've been watching Susskind's lectures on Quantum Entanglement, and something he said regarding (non-)commuting projection operators confused me. Consider two subspaces {$|a>$} and {$|b>$} of ...
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1answer
81 views

Singular wave function

Given a wavefunction, $\psi(x)$, is it possible for $\psi$ to be singular at a point? Are there any rules against a wavefunctions having any singularities? For instance if $$\psi(x) ...
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3answers
112 views

Wave function not normalizable

Does the solution of the Schrodinger equation always have to be normalizable? By normalizable I mean, given a wavefunction $\psi(x)$ $$\int_{-\infty}^{\infty}|\psi(x)|^2 dx<\infty \qquad ...
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5answers
1k views

How does the hydrogen atom know which frequencies it can emit photons at?

At university, I was shown the Schrodinger Equation, and how to solve it, including in the $1/r$ potential, modelling the hydrogen atom. And it was then asserted that the differences between the ...
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1answer
58 views

Normalisation of Linear Harmonic Oscillator - Ladder Operator Method

I was watching the following video on the harmonic oscillator using ladder operators : http://youtu.be/gRdCV9p8sAU?t=30m9s Clicking on the video above will take you to the exact point where my ...
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2answers
81 views

Quantum Mechanics: Momentum operator questions [closed]

I'm asked to determine $\hat{P}|\Psi_0\rangle$, $\langle{\hat{P}}\rangle$, and $\langle\hat{P}^2\rangle$ for $$\Psi_0(u) = \psi_0 + 2\psi_1$$ I understand how to make the matrix for $P$ in regards ...
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2answers
45 views

Unitary transformation between complete + orthonormal bases

Suppose the complete orthonormal bases $\{|\psi_n\rangle\}$ and $\{|\psi{'}_n\rangle\}$ are related by the transformation matrix $U$: $$ |\psi{'}_n\rangle = U|\psi_n\rangle \\ \langle\psi{'}_n| = ...
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1answer
69 views

Orthogonality of summed wave functions

Problem. I know that the two wave functions $\Psi_1$ and $\Psi_2$ are all normalized and orthogonal. I now want to prove that this implies that $\Psi_3=\Psi_1+\Psi_2$ is orthogonal to ...
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1answer
30 views

Uncertainty Definition QM

On my introductory course in Quantum Mechanics, the uncertainty of an operator $A$ in the state $\psi$ is defined by $$(\Delta A)^2_{\psi}=\langle(A-\langle A \rangle_{\psi})^2\rangle _{\psi}$$ I'm ...
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2answers
66 views

Quantum Expectation Values

I'm having trouble understanding the motivation for the definition of the expectation of a self adjoint operator $A$: $$\langle A \rangle _\psi=\int_{\mathbb{R}}\psi^*A\hspace{0.2cm} \psi ...
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1answer
167 views

Hilbert space in quantum mechanics

I think in quantum mechanics we assign to each system a specific Hilbert space i.e. if systems are different then their Hilbert spaces are different. Is this true? If not why? For differernt system I ...
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1answer
40 views

Quantum Mechanics - Rectangular Potential Barrier - Normalisation

I have a quick question regarding the normalisation of the wave function of a particle incident on a potential barrier specifically regarding the normalisation of the wave functions. The problem is ...
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1answer
89 views

Non-Hermitian operator with real eigenvalues?

So we know that in Quantum Mechanics we require the operators to be Hermitian, so that their eigenvalues are real ($\in \mathbb{R}$) because they correspond to observables. What about a non-Hermitian ...
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0answers
43 views

Completeness of the state space and Hilbert space [duplicate]

I am wondering just why is it supposed that quantum states lie in a Hilbert space, which mathematically requires completeness? In other words, what does completeness (defined in terms of Cauchy ...
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0answers
65 views

Momentum and position operators in Schrödinger representation

I was going through some intro notes on path integral (for QFT), and am stuck with this equation for position and momentum in Schrödinger (position) representation, $$ \hat{1} =\int ...
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3answers
113 views

Can the expectation value of the square of momentum be negative?

I've been solving a problem in quantum mechanics, and I was deriving the standard deviation of $P$, knowing that $\langle P\rangle=0$. Because $\Delta P=\sqrt{\langle P^2 \rangle - \langle P \rangle ...
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1answer
73 views

Comparing two infinite sets

All the linearly independent eigenfunctions of the parity operator $\mathcal{P}$ form an infinite set and all the linearly independent eigenfunctions of the unit operator $\bf 1$ also form an ...
3
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2answers
66 views

Matrix elements of linear operators - orthonormal basis required?

In an early linear algebra class of mine, I learnt that a linear map $\mathcal{A}$ acting on a vector space could be represented by a matrix $A_{ij}$ according to the rule: $$\mathcal{A}({e_j}) = ...
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2answers
84 views

Precise meaning of composition of ket and bra, e.g. $|\psi\rangle\langle\psi|$

I'm currently studying density matrices, and have been frequently coming across the construction $$|\psi\rangle\langle\psi| \,.$$ What is the formal meaning of this composition? I understand ...
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0answers
10 views

Is the additivity property of the quantum states valid only for countable families of pairwise orthogonal projections?

Consider a generic Hilbert spaces and a map $$ \mu:P(H)\longrightarrow [0,1] $$ such that $\mu(I)=1$ and $$ \mu\left(\mbox{s-}\sum_{i\in\mathcal{I}}P_i\right)=\sum_{i\in\mathcal{I}}\mu(P_i) $$ for ...
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1answer
82 views

Correspondence between wave function and state vector

I am confused with connection between state $| \psi \rangle$ of a quantum system and corresponding wave function $\psi(x)$ (at a given time). I have been told that for every state $| \psi \rangle$ we ...
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0answers
39 views

How do I properly express adding perturbed states to unperturbed states?

I have a problem set due tomorrow, and the last problem is driving me nuts. Been combing through griffiths trying to find similar examples to no avail, so it'd be greatly appreciated if stackexchange ...
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0answers
100 views

Why do some terms vanish in first-order perturbation theory?

In first order perturbation theory, we usually express the first order perturbation in the eigenket of the perturbed Hamiltonian in the basis of the unperturbed Hamiltonian $H_{0}$: ...
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1answer
71 views

Writing an arbitrary operator in bra-ket notation

An annoying fact about my physics textbook (Griffiths' Introduction to Quantum Mechanics) is that it introduces bra-ket notation without telling us how to use it. So I have a two-part question for SE: ...
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1answer
73 views

How to find different operator representations in QM?

I read that any observable operator may be represented as: $$\Omega = \sum_n \omega _n | \omega _n \rangle \langle \omega_n |$$ Where the little omegas are the eigenvectors/eigenvalues of the ...
7
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1answer
124 views

Self-adjoint and unbounded operators in QM

An operator $A$ is said to be self-adjoint if $(\chi,A\psi)=(A\chi,\psi)$ for $\psi, \chi \in D_A$ and $D_A=D_{A^\dagger}$. But for the free particle momentum operator $\hat{p}$ these inner products ...
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3answers
96 views

Position and momentum bases in quantum mechanics

I have seen the following two descriptions of the position basis: $$\tag{1}| x\rangle=\delta(x-x_0)$$ and also $$\tag{2}\langle x_0| x\rangle=\delta(x-x_0),$$ which (if either) of these is ...
2
votes
1answer
56 views

Normal ordering of the identity operator

I'm puzzled about what should be the normal ordering of the identity operator (or any proportional operator): looking at it from the "Fock space operators POV",the prescription is to move all the ...
2
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1answer
56 views

Eigenfunction associated with the $\hat{x}$ operator

Consider the following operator $\hat{x}=i\hbar \frac{\partial}{\partial p}$. I am trying to show that the eigenfunctions of $\hat{x}$ are not square-normalizable. I am interested in doing so since ...
3
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1answer
123 views

Bounded and Unbounded Operator

Can someone explain with a concrete example of how can I can check whether a quantum mechanical operator is bounded or unbounded? EDIT: For example., I would like to check whether $\hat ...
3
votes
1answer
64 views

Self-adjoint and nonpositive differential operators

I recently tumbled over a statement in a geophysics paper (PDF here). They have a wave equation which they formulate as $$ \frac{1}{v_0}\frac{\partial^2}{\partial t^2} \begin{pmatrix}p \\ ...
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1answer
152 views

Self-adjoint differential operators

I'm having a hard time understanding the deal with self-adjoint differential opertors used to solve a set of two coupled 2nd order PDEs. The thing is, that the solution of the PDEs becomes ...
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1answer
351 views

Boosts are non-unitary!

The boost transformations are not unitary unlike rotations, the boost generators are not Hermitian. When this induces transformations in the Hilbert space, will those transformation be unitary? I ...
3
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1answer
48 views

Eigenvalues of Infinite Dimensional Matrix [duplicate]

If I take a infinite-dimensional square matrix, what can I say about its eigenvalue spectrum? Will they have a discrete infinity of eigenvalues or continuous infinity of them?
4
votes
1answer
220 views

Imaginary Eigenvalue Of A Hermitian Operator

The eigenfunctions of a Hermitian operator are real. But consider a function $\psi(x)=e^{-\kappa x}$, $x\in\mathbb{R}$, where $\kappa$ is a real constant. Then, $$\hat p \psi(x)=-i\hbar ...
7
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3answers
214 views

Use of 'complete' as in 'complete set of states' or 'complete basis'

Question. In the context of QM, I hear the phrases 'complete set of states' and 'complete basis' (among other similar expressions) thrown around rather a lot. What exactly is meant by 'complete'? ...
8
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1answer
210 views

Conceptual difficulty in understanding Continuous Vector Space

I have an extremely ridiculous doubt that has been bothering me, since I started learning quantum mechanics. If we consider the finite dimensional vector space for the spin$\frac{1}{2}$ particles, ...
0
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1answer
48 views

Admixtures of longitudinal and timelike photons!

In the quantization of electromagnetic field the physical states $|\psi\rangle$ are found to obey the following relation: $[a^{(0)}(k)-a^{(3)}(k)]|\psi\rangle=0$ It is explained as the physical ...
3
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1answer
119 views

Example of application of creation/annihilation operators in matrix form

I was wondering how it would sound like the creation/annihilation of particles that we usually do in the context of Dirac formalism, with matrices and vectors. As a reminder we know that: ...
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1answer
185 views

Understanding Triplet And Singlet States

We know, $2\otimes 2=3\oplus 1$. Thus we have a spin triplet of states and a spin singlet. Can we regard these states as the spin part of wavefunction for the excited states and the ground state of ...
3
votes
1answer
171 views

Representation of operators in quantum mechanics

For which systems we represent the Hamiltonian as a differential operator and for which system we represent it by a matrix? Can the momentum be represented by a matrix operator?
4
votes
1answer
105 views

Continuity domain for momentum operator

I know this is essentially a mathematic question, but I received no answer on math SE. Moreover it has a direct application in physics, so I thought to ask this here too. The momentum operator in one ...
2
votes
2answers
130 views

Harmonic Oscillator - Energy quantisation

The one-dimensional quantum HO can be solved in Schrodinger representation by getting Hermite Differential Equation $$ \frac{d^2y}{dx^2} - 2x \frac{dy}{dx} + \lambda y = 0 $$ with solutions $$ y(x) = ...
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1answer
89 views

Linear Operators and their representations

I am currently learning Quantum mechanics on a slightly advanced level. I am curious in knowing if there are Linear Operators (Linear Maps) in the Hilbert Space (finite dimensional ones) that don't ...
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1answer
187 views

Showing that an operator is Hermitian

Consider the operator $$T=pq^3+q^3p=-i\frac{d}{dq}q^3-iq^3\frac{d}{dq}$$ defined to act on the Hilbert Space $H=L^2(\mathbb{R},dq)$ with the common dense domain $S(\mathbb{R})$. Here $S(\mathbb{R})$ ...
4
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1answer
104 views

Algebraic formulation of QFT and unbounded operators

In AQFT one specifies the structure of the observables as a $C^*$-algebra. This seems to excludes algebras that don't have a norm, such as the Heisenberg algebra. Fortunately for this case one turns ...