The central term in the hamiltonian formalism. Can be interpreted as an energy input, or "true" energy.

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Conservation of Hamiltonian vs Conservation of Energy

What is the difference between conservation of the Hamiltonian and conservation of energy?
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323 views

Hamiltonian of polymer chain

I'm reading up on classical mechanics. In my book there is an example of a simple classical polymer model, which consists of N point particles that are connected by nearest neighbor harmonic ...
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8k views

Two expressions for expectation value of energy

I was looking up expectation value of energy for a free particle on the following webpage: http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/expect.html It says that $E=\frac{p^2}{2m}$ and ...
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296 views

Perturbation method & eigenvalues

I have a problem but I don't understand the question. It says: "Show that, to first order in energy, the eigenvalues ​​are unchanged." What does it mean? It means that if the Hamiltonian has the ...
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1k views

Solving time dependent Schrodinger equation in matrix form

If we have a Hilbert space of $\mathbb{C}^3$ so that a wave function is a 3-component column vector $$\psi_t=(\psi_1(t),\psi_2(t),\psi_3(t))$$ With Hamiltonian $H$ given by $$H=\hbar\omega ...
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208 views

Quantum Stat-Mech Proof of an Inequality for the Partition Function

I have the following problem that I was unable to solve for class, but I had a couple first steps that I started with that I am unable to finish. I know I can't get this since it's already been ...
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152 views

What really generates time evolution?

A fundamental principle of quantum mechanics, as far as I can tell, states that the Hamiltonian generates time evolution. A common result about generators are the following: let $\mathrm T$ be the ...
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282 views

Hamiltonian form of Noether's Theorem

I understand that Noether's Theorem has a Hamiltonian form, whereby {X, H} = 0 iff {H, X} = 0. The proof of this is trivial, as it follows from the antisymmetry of the Poisson Brackets. First ...
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1k views

Confusion about Free Energy and the Hamiltonian

I'm probably making a relatively basic mistake here, but I'm a bit confused about the relation between the Hamiltonian and Helmholtz free energy. From what I can see, the free energy can be written ...
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582 views

Computing a density of states of Hamiltonian $ H=xp$

How could I compute the integral $$ N(E)~=~ \int dx \int dp~ H(E-xp) $$ the 'Area' inside the Phase space is taken for $ x \ge 0 $ and $ p\ge 0 $? The result should be $$ N(E)~=~ ...
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143 views

Poisson brackets and magnetic field [closed]

I'm a maths student trying to teach myself some physics so sorry if I'm missing something simple here. I think the main problem is lack of experience with the Levi-Cevita symbol. We have a particle ...
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107 views

Do time-invariant Hamiltonians define closed systems?

In classical mechanics, every time-invariant Hamiltonian represents a closed dynamical system? Can every closed dynamical system be represented as a time-invariant Hamiltonian? Or are there closed ...
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174 views

Differentiating the Hamiltonian Operator, $\hat{H}$

Firstly let $\hat{H}$ denote the full energy of the electromagnetic wave. I'm trying to differentiate the Hamiltonian operator with respect to the components of momentum, i.e. $$\frac{d}{dp_x} ...
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271 views

Quick question on perturbation theory

Suppose we have a particle in an infinite potential well, with $V(x) = 0,\space 0< x < a $ and infinity everywhere else. Now suppose we have a perturbation on the LHS of the well: $V_1(x) = v, ...
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2k views

How do I show that the eigenstates of a Hamiltonian can be made orthonormal?

I've been tearing my hair out over this all evening. It should be simple but I must be missing something somewhere. Can someone show me how to prove that the eigenstates of a Hamiltonian can be made ...
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1answer
158 views

Does a constant of motion always imply a Hamiltonian formulation?

If a continuous dynamical system has a constant of motion that is a function of all its variables, and is not already evidently Hamiltonian, is it always possible to use a change of variables and ...
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71 views

How does the Hamiltonian change when going to a moving frame?

The Hamiltonian of a free particle in a rotating frame is given by $$ H = H_0 - \omega \cdot J, $$ where $H_0$ is the Hamiltonian in the non-rotating frame, $\omega$ is the angular velocity of the ...
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122 views

On use of Hamiltonians for Helium

The Hamiltonian of helium can be expressed as the sum of two hydrogen Hamiltonians and that of the Coulomb interaction of two electrons. $$\hat H = \hat H_1 + \hat H_2 + \hat H_{1,2}.$$ The wave ...
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134 views

Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
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617 views

The relation between Hamiltonian and Energy

I know Hamiltonian can be energy and be a constant of motion if and only if: Lagrangian be time-independent, potential be independent of velocity, coordinate be time independent. Otherwise ...
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52 views

Why is the energy operator special?

Only the energy operator controls the time dependence of a quantum system, but not the others, why is that?
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34 views

Is expectation value of the Hamiltonian always the energy? [duplicate]

There are time dependent & space dependent systems (magnetic fields) and time independent (particle in a box or harmonic oscillator). In the latter the expectation value is the 'average' energy ...
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1answer
38 views

How to scale variables in a classical Hamiltonian?

So I looked at some research articles where one has a classical Hamiltonian $H(p,q,t) = p^{2}/2 + V(q,t)$. If one introduces the scaling transformation $$t \mapsto t/\sqrt{s}, \quad H \mapsto Hs, ...
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74 views

Transfer from Heisenberg to Ising model

It is well know, that ferromagnets can be described using Hamiltonian $$ H = -\sum\limits_{i<j}J_{ij}\, (\mathbf{s}_i \cdot \mathbf{s}_j). $$ where (three dimensional) spins $\mathbf{s}_i$ ...
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114 views

Fermion 1D Hubbard Model ground state in the U = 0 limit

I am trying to determine the ground state of the 1D fermionic Hubbard model at half-filling of $2L$ sites with $L$ electrons with spin-$\uparrow$ and $L$ electrons with spin-$\downarrow$ in the $U=0$ ...
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114 views

About the derivation of the Hamilton-Jacobi equation

It is an old question for me. In Goldstein's book, the H-J equation is derived in this way. We want to find a generating function $F(q,P,t)$ such that the transformed Hamiltonian vanishes identically, ...
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687 views

Hamiltonian mechanics and conservation of energy?

Can anyone explain to me Hamiltonian mechanics relation to conservation of energy? I'm not very good at mathematics, and I know it's important into understanding Hamiltonian mechanics. However, can ...
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157 views

The proof that Dirac's hamiltonian commutes with inversion operator

I tried to check the statement that Dirac free Hamiltonian commutes with inversion operator. For $$ \hat {P}\Psi(\mathbf r , t) = i\hat {\gamma}_{0}\Psi (-\mathbf r , t), \quad \hat {H} = (\hat ...
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155 views

Adiabatic quantum evolution of single photon or biphoton system

The prerequisite for adiabatic quantum evolution of single photon or biphoton system is as follows. We have to prepare a single photon or biphoton quantum system which has a ground and a higher level ...
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61 views

Spin Transition Energies

I am reading a paper: http://arxiv.org/ftp/arxiv/papers/1305/1305.2445.pdf On p. 22, the following Hamiltonian is given: $$ H = \mu_B g \mathbf{B} \cdot \mathbf{S} + D(S_Z^2+\frac{1}{3}S(S+1)) + ...
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122 views

Number theoretical function applied in physics? [closed]

I have a series of number theoretic phenomena (mathematics) that I can describe exactly by the superpositions or linear combination of the below function (I know it is an inverse Fourier type). Does ...
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100 views

Boundary condition Hamiltonian with point tinteractions

I`m studying the Hamiltonian with point interaction centered in $y$ in three dimensions. I know that the elements in the domain of the Hamiltonian are of the form $$\psi=\phi+qG^z(\cdot-y)$$ where ...
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105 views

What does $\psi_j(r_i)$ mean?

I have a mean-field Hamiltonian for N electrons. The mean-field potential felt by electron $i$ at position ${\bf r}_i$ is given by $V^{(i)}_{int}({\bf r}_i)=\sum_{j\ne i}|\psi_j({\bf r}_i)|^2$ I ...
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Fourier transform of Hamiltonian for scalar field

In the Srednicki notes (http://web.physics.ucsb.edu/~mark/ms-qft-DRAFT.pdf) page 36 he goes from $$H = \int d^{3}x a^{\dagger}(x)\left( \frac{- \nabla^{2}}{2m}\right) a(x) $$ to $$H = \int ...
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1answer
2k views

Cyclic Coordinates in Hamiltonian Mechanics

I was reading up on Hamiltonian Mechanics and came across the following: If a generalized coordinate $q_j$ doesn't explicitly occur in the Hamiltonian, then $p_j$ is a constant of motion ...
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685 views

Propagators and Probabilities in the Heisenberg Picture

I'm trying to understand why $$\Bigl|\langle0|\phi(x)\phi(y)|0\rangle\Bigr|^2$$ is the probability for a particle created at $y$ to propagate to $x$ where $\phi$ is the Klein-Gordon field. What's ...
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59 views

Conservation of energy in quantum mechanics

In Griffiths' book Introduction to quantum mechanics (second edition, page 37) it states: The time-independent Schrödinger equation says $$\hat{H} \psi_{n} = E_{n}\psi_{n}$$ so $$\langle H ...
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91 views

What is the energy operator and from where do we get it?

I am trying to learn Quantum mechanics from MIT OCW Videos about quantum mechanics. I have reached the 5th lecture. Please help me in understanding this: In the middle (At 32:08), the professor wrote ...
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190 views

Showing that Hamiltonian expectation value is time independent

I want to check that I am getting the concept right here, and my question is: if the expectation value of a Hamiltonian is the same whether you use the time dependent version or not. I thought I had ...
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478 views

Lagrangian and hamiltonian of interaction

How to prove that lagrangian of interaction is equal to hamiltonian of interaction with minus sign? For example, I can't prove it for special case - quantum electrodynamics.
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183 views

Sign in the time-independent Schrödinger's equation

In the time-independent Schrödinger's equation: $$ -\frac{\hbar^2}{2m} \frac{d^2} {dx^2} u + Vu ~= Eu, $$ why there is a minus sign before the first term?
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The notion of bounded states in quantum mechanics and their characterization with operators

Is there any case of potential $V$, such that the continuity of the operator $H=c\ \Delta+V$ is not spoiled? And I don't know any non-differnetial operator examples for continous spectra. I ...
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1answer
57 views

Going to the interaction picture in the Jaynes–Cummings model [closed]

In the Jaynes–Cummings model for a two level atom, the Hamiltonian for the atom is defined as (I let $\bar{h}=1$) $$H_a=\omega_a\frac{\sigma_z}{2}$$ and the field Hamiltonian is ...
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2answers
109 views

Mathematical Proof the angular momentum and Hamiltonian commute?

I'm in a quantum mechanics class, and it is given in the book that the operators $\hat{L^{2}}$ and $\hat{H}$ commute for the 3D Harmonic Oscillator, but no definite mathematical proof is given, and ...
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1answer
132 views

Can all symplectic-form preserving canonical transformations generated by generating functions

This question is related to this fascinating post and this post and this post, but more limited in scope in discussing the practical definition canonical transformations. Canonical transformation ...
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168 views

Example where Hamiltonian $H \neq T+V=E$, but $E=T+V$ is conserved

I'm looking for an example of a Hamiltonian $H$, where $H\neq T+V$, but the total energy in the system, $E=T+V$, is still conserved. While I'm at it, I might as well add that I'd be most interested ...
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387 views

Representation of Hamiltonian in terms of “creation” and “destruction” operators

Let's have Schrodinger equation or Dirac equation in Schrodinger form: $$ i \partial_{0}\Psi = \hat {H}\Psi . $$ Sometimes we can introduce some operators $\hat {A}, \hat {B}$ (the second is not ...
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Energy Spectrum of pair of spin-1/2 particles with general Hamiltonian

I found this problem, and so far I am stumped. I was wondering if anyone wanted to solve it with me, or help me calculate eigenvectors, or just give insight on my questions. Consider a system of ...
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1answer
82 views

The Molecular Hamiltonian and the avoidance of Overcounting

Whenever I see the total non-relativistic molecular Hamiltonian, $\hat{H}_{molecular} = \hat{T}_{e} + \hat{T}_{n} + \hat{V}_{ee} + \hat{V}_{nn} + \hat{V}_{en}$ I always notice that the sums ...
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358 views

Factors of $c$ in the Hamiltonian for a charged particle in electromagnetic field

I've been looking for the Hamiltonian of a charged particle in an electromagnetic field, and I've found two slightly different expressions, which are as follows: $$H=\frac{1}{2m}(\vec{p}-q \vec{A})^2 ...