# Tagged Questions

The central term in the hamiltonian formalism. Can be interpreted as an energy input, or "true" energy.

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### What does it mean to expand a Hamiltonian using perturbation theory?

On UC Davis chemwiki website, the Hamiltonian for quadrupolar coupling in NMR is analyzed. (The details of this aren't important.) It is said in the analysis that: The expansion of the ...
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### How do we know that $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$?

I am kind of new to this eigenvalue, eigenfunction and operator things, but I have come across this quote many times: $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$. ...
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### Quantum Stat-Mech Proof of an Inequality for the Partition Function

I have the following problem that I was unable to solve for class, but I had a couple first steps that I started with that I am unable to finish. I know I can't get this since it's already been ...
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### Mathematical Proof the angular momentum and Hamiltonian commute?

I'm in a quantum mechanics class, and it is given in the book that the operators $\hat{L^{2}}$ and $\hat{H}$ commute for the 3D Harmonic Oscillator, but no definite mathematical proof is given, and I'...
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### What really generates time evolution?

A fundamental principle of quantum mechanics, as far as I can tell, states that the Hamiltonian generates time evolution. A common result about generators are the following: let $\mathrm T$ be the ...
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### Hamiltonian form of Noether's Theorem

I understand that Noether's Theorem has a Hamiltonian form, whereby {X, H} = 0 iff {H, X} = 0. The proof of this is trivial, as it follows from the antisymmetry of the Poisson Brackets. First ...
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### Confusion about Free Energy and the Hamiltonian

I'm probably making a relatively basic mistake here, but I'm a bit confused about the relation between the Hamiltonian and Helmholtz free energy. From what I can see, the free energy can be written ...
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### What does $\psi_j(r_i)$ mean?

I have a mean-field Hamiltonian for N electrons. The mean-field potential felt by electron $i$ at position ${\bf r}_i$ is given by $V^{(i)}_{int}({\bf r}_i)=\sum_{j\ne i}|\psi_j({\bf r}_i)|^2$ I ...
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### What is the energy operator and from where do we get it?

I am trying to learn Quantum mechanics from MIT OCW Videos about quantum mechanics. I have reached the 5th lecture. Please help me in understanding this: In the middle (At 32:08), the professor wrote ...
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### Showing that Hamiltonian expectation value is time independent

I want to check that I am getting the concept right here, and my question is: if the expectation value of a Hamiltonian is the same whether you use the time dependent version or not. I thought I had ...
In the time-independent Schrödinger's equation: $$-\frac{\hbar^2}{2m} \frac{d^2} {dx^2} u + Vu ~= Eu,$$ why there is a minus sign before the first term?