2
votes
1answer
33 views

Schroedinger equation. Why Potential energy instead of Force?

What is the reason Schroedinger equation is quoted in terms of potential energy instead of force?
4
votes
0answers
95 views

Degenerate perturbation theory applied to topological degeneracy?

Consider a quantum system described by a gapped Hamiltonian $H_0$ with degenerate ground states (GS), adding a perturbation term $V$ to $H_0$, then the low-energy physics can be described by an ...
5
votes
1answer
96 views

Why don't we use Hamilton-Jacobi method in QM?

In classical mechanics, we usually try to find a set of coordinates by Hamilton-Jacobi method to transform the Hamiltonian to zero such that the coordinates are conservations. However, we never try ...
3
votes
2answers
429 views

Gauge Invariance of the Hamiltonian of the electromagnetic field

The Hamiltonian for an electron of mass $m$ and charge $e$ in an exterior electromagnetic field is $$H=\frac{1}{2m}(p-(e/c)A)^2+e\varphi.$$ The corresponding (via canonical quantization) quantum ...
4
votes
1answer
99 views

Do we have a fundamental Hamiltonian for the system of H$_2$O molecules?

From the quantum mechanics(QM) viewpoint, does there exist a Hamiltonian $H$ for the system of H$_2$O molecules? Assume that the number of H$_2$O molecules is fixed. Imagine that by calculating the ...
7
votes
3answers
262 views

Why not formulate Quantum Mechanics using Lagrangians? [duplicate]

As the title implies, why is it that the most common formalisms we use in quantum mechanics prefer to describe systems in the terms of a Hamiltionian instead of a Lagrangian? Is there some ...
5
votes
3answers
189 views

Why are we living in the $q$ part of the phase space?

In Hamilton mechanics and quantum mechanics, $p$ and $q$ are almost symmetric. But in the real world, the $p$ space isn't as intuitive as the $q$ space. For example, We can uniquely identify a person ...
1
vote
1answer
100 views

Shouldn't the addition of angular momentum be commutative?

I have angular momenta $S=\frac{1}{2}$ for spin, and $I=\frac{1}{2}$ for nuclear angular momentum, which I want to add using the Clebsch-Gordon basis, so the conversion looks like: $$ \begin{align} ...
2
votes
1answer
258 views

Hamiltonian matrix off diagonal elements?

I'm trying to understand how Hamiltonian matrices are built for optical applications. In the excerpts below, from the book "Optically polarized atoms: understanding light-atom interaction", what I ...
13
votes
2answers
375 views

Can we quantize Aristotelian physics?

Aristotelian physics, shorn of whatever the historical Aristotle actually believed, is pretty similar to Newtonian physics. Instead of "An object in motion stays in motion unless acted on by an ...
0
votes
1answer
156 views

Find the possible energies and corresponding wavefunctions of the Hamiltonian [closed]

The Hamiltonian of an electron stuck within a tunnel in a dialectic cube is found to be $$H=\frac{p^2}{2m}+\frac{1}{2}Kx^2-\frac{e\Phi_0}{a}x$$ Find the possible energies and ...
5
votes
5answers
438 views

What is Quantization?

In classical mechanics you construct an action (involving a Lagrangian in arbitrary generalized coordinates, a Hamiltonian in canonical coordinates [to make your EOM more "convenient & ...
1
vote
1answer
113 views

Formulation of the uncertainty principle for a system?

There is a biological system that I can indeed describe by a simple quantum Hamiltonian $H$ having eigenstates $|q\rangle$ labelled by the numbers $q$, and having energies proportional to $f(q)$ - ...
1
vote
0answers
108 views

How to understand the matrix behind a Hamiltonian?

thanks to the answers I received to my previous questions, I could derive correctly an elegant partition function for my problem which resembles a second quantized model taking the particles to be ...
3
votes
0answers
178 views

The Hamiltonian for clocks?

I am rather a theoretician and looking for a formalism to represent biological clocks by Hermitian operators. The simplest thought model I am looking for is a formal representation of a clock (for ...
1
vote
1answer
197 views

Hamiltonian reduction having constant of the motion

I have this $2^n*2^n$ matrix that represent the evolution of a system of $n$ spin. I know that I can have only one excited spin in my configuration a time. (eg: 0110 nor 0101 ar not permitted, but ...
3
votes
1answer
494 views

Phase space in quantum mechanics and Heisenberg uncertainty principle

In my book about quantum mechanics they give a derivation that for one particle an area of $h$ in $2D$ phase space contains exactly one quantum mechanical state. In my book about statistical physics ...
2
votes
1answer
306 views

Quantum mechanical analogue of conjugate momentum

In classical mechanics, we define the concept of canonical momentum conjugate to a given generalised position coordinate. This quantity is the partial derivative of the Lagrangian of the system, with ...
6
votes
2answers
759 views

Weyl Ordering Rule

While studying Path Integrals in Quantum Mechanics I have found that [Srednicki: Eqn. no. 6.6] the quantum Hamiltonian $\hat{H}(\hat{P},\hat{Q})$ can be given in terms of the classical Hamiltonian ...
5
votes
2answers
647 views

Quantum Mechanics Notation for BRA KET

I've been given this homework problem, but I do not understand its notation. Please perform the following where the wavefunctions are the normalized eigenfunctions of the harmonic oscillator ...
1
vote
1answer
92 views

Noise spectrum of two systems and interacting Hamiltonian

I've been discovering recently the concept of noise spectrum, defined as: $$S_{xx}[\omega] = \int dt<x(t)x(0)>\text{e}^{-i\omega t}$$ Roughly the Fourrier transform of the two-point function. ...
7
votes
1answer
311 views

Operator Ordering Ambiguities

I have been told that $$[\hat x^2,\hat p^2]=2i\hbar (\hat x\hat p+\hat p\hat x)$$ illustrates operator ordering ambiguity. What does that mean? I tried googling but to no avail.
8
votes
5answers
529 views

Why don't we use the concept of force in quantum mechanics?

I'm a quarter of the way towards finishing a basic quantum mechanics course, and I see no mention of force, after having done the 1-D Schrodinger equation for a free particle, particle in an ...
4
votes
3answers
2k views

What exactly are Hamiltonian Mechanics (and Lagrangian mechanics)

What exactly are Hamiltonian Mechanics (and Lagrangian mechanics)? I want to self-study QM, and I've heard from most people that Hamiltonian mechanics is a prereq. So I wikipedia'd it and the entry ...
5
votes
1answer
168 views

Yang Mills Hamiltonian: why do we use the Weyl's temporal gauge?

Do you know why in the quantization of SU(2) Yang Mills Gauge Theory, it is always chosen the Weyl (temporal) gauge to derive the Hamiltonian? Is it possible to fix another gauge?
6
votes
3answers
761 views

How does one quantize the phase-space semiclassically?

Often, when people give talks about semiclassical theories they are very shady about how quantization actually works. Usually they start with talking about a partition of $\hbar$-cells then end up ...
1
vote
0answers
191 views

How important are constrained Hamiltonian dynamics and BRST transformation as a formalism?

I am to study BRST transformations, for which I'm currently trying to understand constrained Hamiltonian dynamics to treat systems with singular Lagrangians. The crude recipe followed is Lagrangian -> ...
15
votes
5answers
2k views

Why not using Lagrangian, instead of Hamiltonian, in non relativistic QM?

When we studied classical mechanics on the undergraduate level, on the level of Taylor, we covered Hamiltonian as well as Lagrangian mechanics. Now when we studied QM, on the level of Griffiths, we ...
1
vote
0answers
431 views

Square of Laplace–Runge–Lenz vector in Hydrogen atom [closed]

I have a problem. I've tried this question, but I don't get the correct expression. Can someone give me some ideas? Thanks! Consider the Hydrogen Atom Hamiltonian: $$ H = (\mathbf p^2/2 ...
8
votes
3answers
82 views

Constructing a Hamiltonian (as a polynomial of $q_i$ and $p_i$) from its spectrum

For a countable sequence of positive numbers $S=\{\lambda_i\}_{i\in N}$ is there a construction producing a Hamiltonian with spectrum $S$ (or at least having the same eigenvalues for $i\leq s$ for ...
1
vote
1answer
560 views

Conjugate Variables and Fourier Transforms in Classical Physics

Let q be a generalized coordinate with a conjugate momentum p and a potential resulting in a periodic motion of q. What is the meaning of the Fourier transform of q(t) over its period? Can this be ...
2
votes
1answer
182 views

Degeneracy and the Hamiltonian

How many linearly independent eigenfunctions can be associated with one degenerate eigenvalue of the Hamiltonian operator? (Is there a limit since it contains a 2nd order differential operator?) ...
4
votes
1answer
36 views

Connections of iterative solvers for large systems of equation in Physics?

I am trying to find the domains in physics where solving large systems of equations is computationally expensive. The sparse systems are of my particular interest, where the input matrix A is in GBs ...
5
votes
2answers
659 views

Energy operator

Does the Hamiltonian always translate to the energy of a system? What about in QM? So by the Schrodinger equation, is it true then that $i\hbar{\partial\over\partial t}|\psi\rangle=H|\psi\rangle$ ...
1
vote
1answer
331 views

Sudden change in the Hamiltonian

Could someone explain what this sentence mean? "If the Hamiltonian changes suddenly by a finite amount, the wavefunction must change continuously in order that the time-dependent Schrodinger equation ...
2
votes
1answer
370 views

Expectation of a commutation relation

Is there any significance to: $\langle[H,\hat{O}]\rangle =0$ (which can easily be shown) where $H$ is the Hamiltonian, $\hat{O}$ is an arbitrary operator? Thanks.
1
vote
1answer
215 views

interpretation of $\{H,L^2\}$

In Hamiltonian mechanics, we show $\{H,L_z\}=0$, which can be interpreted as the conservation of angular momentum around $Oz$. Following the same idea, how can we interprete $\{H,L^2\}$? Is the ...