0
votes
1answer
27 views

Expectation value of Hamiltonian on number state [closed]

Hamiltonian is defined by $H_I = \hbar \omega (\hat{a}^+ \hat{a} + 1/2)$ What is the expectation value of the energy on the number state $$\vert \psi \rangle = \frac{1}{\sqrt{2}} ( \vert 1 \rangle ...
11
votes
2answers
240 views

Correct way to write the eigenvector of a diagonalized hamiltonian in second quantization

I am studying diagonalization of a quadratic bosonic Hamiltonian of the type: $$ H = \displaystyle\sum_{<i,j>} A_{ij} a_i^\dagger a_j + \frac{1}{2}\displaystyle\sum_{<i,j>} [B_{ij} ...
6
votes
1answer
102 views

What are the restrictions on the Hamiltonian in QM?

In quantum mechanics, we usually write the Hamiltonian as: $$\hat{H}=\hat{T}+\hat{V}$$ But in classical mechanics, there are several reasons why it would not have this form: We've chosen some ...
0
votes
1answer
170 views

Proof of the time-independent Schrödinger equation

I have a question regarding the proof of the time-independent Schrödinger equation. So if we have a time-Independent Hamiltonian, we can solve the Schrödinger equation by adopting separation of ...
1
vote
1answer
104 views

Change of operator in the Hamiltonian [closed]

We are told that the particle has mass m and charge e and is moving in 2 dimensions. The position operator $\mathbf{X}=(X_{1},X_{2})$ and momentum operator $\mathbf{P}=(P_{1},P_{2})$ We are given ...
2
votes
1answer
145 views

How do I show that the eigenstates of a Hamiltonian can be made orthonormal?

I've been tearing my hair out over this all evening. It should be simple but I must be missing something somewhere. Can someone show me how to prove that the eigenstates of a Hamiltonian can be made ...
7
votes
1answer
110 views

Do systems with level crossings have unstable eigenbases?

It's folklore dating back to von Neumann and Wigner that time-dependent Hamiltonian systems tend not to have level crossings of their energy eigenvalues. However, we can of course consider smoothly ...
1
vote
2answers
450 views

Getting Energies and Probabilities from the Hamiltonian

So I need to find the possible energies and the probabilities of these using the eigenvalues of a Hamiltonian. Once I obtain the eigenvalues, are those the energies E_n in and of themselves? Or do ...
1
vote
2answers
140 views

Sign in the time-independent Schrödinger's equation

In the time-independent Schrödinger's equation: $$ -\frac{\hbar^2}{2m} \frac{d^2} {dx^2} u + Vu ~= Eu, $$ why there is a minus sign before the first term?
0
votes
1answer
146 views

Hamiltonian operator apply to a wavefunction

When a Hamiltonian operator apply to a wavefunction, how could we write the hamiltonian as, $$H \psi = (E_n-\hbar \omega_0) \psi \ \ ? $$ Is this because $E_n= H+ \hbar \omega_0$? where ...
2
votes
1answer
252 views

Hamiltonian matrix off diagonal elements?

I'm trying to understand how Hamiltonian matrices are built for optical applications. In the excerpts below, from the book "Optically polarized atoms: understanding light-atom interaction", what I ...
0
votes
0answers
90 views

Quantum Hamiltonian commuting with the Pauli-Runge vector

I have to prove that $[A_j, H] = 0$, with; $$\vec{A} = \frac{1}{2Ze^{2}m}(\vec{L} \times \vec{P} - \vec{p} \times \vec{L}) + \frac{\vec{r}}{r}$$ $$H = \frac{p^2}{2m} - \frac{Ze^2}{r}$$ And, $Z, e, ...
0
votes
3answers
438 views

Why can the Schroedinger equation be used with a time-dependent Hamiltonian?

I have a puzzle about Schroedinger equation with time-dependent hamiltonian, which is usually used in time-dependent quantum systems. However, one of the axioms in quantum mechanics postulates that ...
2
votes
0answers
139 views

Adiabatic quantum evolution of single photon or biphoton system

The prerequisite for adiabatic quantum evolution of single photon or biphoton system is as follows. We have to prepare a single photon or biphoton quantum system which has a ground and a higher level ...
3
votes
1answer
152 views

Intuition behind Hamiltonian

I am reading this paper by Das et al. which converts Deutsch's algorithm into an adiabatic quantum algorithm. I don't get the intuition behind the initial and final Hamiltonians. If defines the ...
4
votes
3answers
636 views

It appears that stationary states aren't so stationary

$$ \DeclareMathOperator{\dif}{d \!} \newcommand{\ramuno}{\mathrm{i}} \newcommand{\exponent}{\mathrm{e}} \newcommand{\ket}[1]{|{#1}\rangle} \newcommand{\bra}[1]{\langle{#1}|} ...
1
vote
0answers
98 views

What is the energy scale of a Hamiltonian?

On the second page of this paper a term 'fundamental energy scale' is used while talking about a Hamiltonian. The context is implementing Deutsch's algorithm using Adiabatic Quantum Computation. What ...
12
votes
1answer
510 views

Is the Ground State in QM Always Unique? Why?

I've seen a few references that say that in quantum mechanics of finite degrees of freedom, there is always a unique (i.e. nondegenerate) ground state, or in other words, that there is only one state ...
2
votes
0answers
47 views

Spin Transition Energies

I am reading a paper: http://arxiv.org/ftp/arxiv/papers/1305/1305.2445.pdf On p. 22, the following Hamiltonian is given: $$ H = \mu_B g \mathbf{B} \cdot \mathbf{S} + D(S_Z^2+\frac{1}{3}S(S+1)) + ...
1
vote
3answers
759 views

Energy Spectrum of pair of spin-1/2 particles with general Hamiltonian

I found this problem, and so far I am stumped. I was wondering if anyone wanted to solve it with me, or help me calculate eigenvectors, or just give insight on my questions. Consider a system of ...
1
vote
1answer
64 views

The Molecular Hamiltonian and the avoidance of Overcounting

Whenever I see the total non-relativistic molecular Hamiltonian, $\hat{H}_{molecular} = \hat{T}_{e} + \hat{T}_{n} + \hat{V}_{ee} + \hat{V}_{nn} + \hat{V}_{en}$ I always notice that the sums ...
2
votes
0answers
107 views

Number theoretical function applied in physics? [closed]

I have a series of number theoretic phenomena (mathematics) that I can describe exactly by the superpositions or linear combination of the below function (I know it is an inverse Fourier type). Does ...
1
vote
2answers
112 views

Molecular Hamiltonian

I was reading some material on the Molecular Hamiltonian on Wiki. It said that, Almost all calculations of molecular wavefunctions are based on the separation of the Coulomb Hamiltonian first ...
2
votes
2answers
305 views

How do we know that $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$?

I am kind of new to this eigenvalue, eigenfunction and operator things, but I have come across this quote many times: $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$. ...
2
votes
0answers
66 views

Boundary condition Hamiltonian with point tinteractions

I`m studying the Hamiltonian with point interaction centered in $y$ in three dimensions. I know that the elements in the domain of the Hamiltonian are of the form $$\psi=\phi+qG^z(\cdot-y)$$ where ...
3
votes
2answers
139 views

What is a symmetry of a physical system?

If I understand correctly, in many context in physics (quantum mechanics?), a physical system is specified by giving its Hamiltonian. I also hear that symmetries are rather essential. As far as the ...
7
votes
2answers
2k views

How to express a Hamiltonian operator as a matrix

Suppose we have Hamiltonian on $\mathbb{C}^2$ $$H=\hbar(W+\sqrt2(A^{\dagger}+A))$$ We also know $AA^{\dagger}=A^{\dagger}A-1$ and $A^2=0$, letting $W=A^{\dagger}A$ How can we express $H$ as $H=\hbar ...
3
votes
1answer
293 views

How does a state in quantum mechanics evolve?

I have a question about the time evolution of a state in quantum mechanics. The time-dependent Schrodinger equation is given as $$ i\hbar\frac{d}{dt}|\psi(t)\rangle = H|\psi(t)\rangle $$ I am ...
7
votes
2answers
2k views

How to construct the Hamiltonian matrix?

I'm trying to understand if there's a more systematic approach to build the matrix associated with the Hamiltonian in a quantum system of finite dimension. For example, I know that for the ammonia ...
3
votes
1answer
440 views

Alkali atom in oscilating electromagnetic field

I am trying to calculate atom - light (EM field) interaction Hamiltonian, and the results I get seem to me rather unphysical - I get some nonzero matrix elements which should not be there. Please, can ...
1
vote
0answers
108 views

Measurement in Quantum mechanics

I have got a quantum conservative system whose Hamiltonian is $H$. I consider an selfandjoint operator $O$ whose eigenvalues and eigenvectors are: $$O|\psi _{n}\rangle = \lambda _{n}|\psi ...
1
vote
1answer
120 views

Transform hamiltonian

I have got the following Quantum Hamiltonian: $$H=\frac{p^{2}}{2m}+k_{1}x^{2}+k_{2}x+k_{3}$$ Which transformation can I use to change this Hamiltonian into an harmonic oscillator hamiltonian? ...
1
vote
0answers
55 views

Length of the orbit (semiclassical orbits)

The Gutzwiller trace is about $$ d(E)=d_{0} (E)+ \sum_{p.o}A_{p}Cos(S(E)\ell_{p}) $$ and $ \ell_{p} $ are the length of the orbit. However my question is, how can one derive the length of the orbit ...
2
votes
2answers
2k views

Two expressions for expectation value of energy

I was looking up expectation value of energy for a free particle on the following webpage: http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/expect.html It says that $E=\frac{p^2}{2m}$ and ...
5
votes
2answers
603 views

Expectation value of time-dependent Hamiltonian

I'm trying to solve a problem in QM with a forced quantum oscillator. In this problem I have a quantum oscillator, which is in the ground state initially. At $t=0$, the force $F(t)=F_0 \sin(\Omega t)$ ...
5
votes
1answer
2k views

Evolution operator for time-dependent Hamiltonian

When i studyed QM I'm only working with non time-dependent Hamiltonians. In this case unitary evolution operator has the form $$\hat{U}=e^{-\frac{i}{\hbar}Ht}$$ that follows from this equation $$ ...
2
votes
0answers
144 views

Hubbard Model Hamitonian

$H = -\sum\limits_{i,j} A_{ij} c_i^{\dagger} c_j + \frac{U}{2} \sum\limits_i(c_i^\dagger c_i)(c_i^\dagger c_i -1)$ is defined to be a Hamiltonian for modeling quantum random walk of identical ...
4
votes
1answer
153 views

Finding the energy levels of an electron in a plane perpendicular to a uniform magnetic field

Suppose we have an electron, mass $m$, charge $-e$, moving in a plane perpendicular to a uniform magnetic field $\vec{B}=(0,0,B)$. Let $\vec{x}=(x_1,x_2,0)$ be its position and $P_i,X_i$ be the ...
2
votes
1answer
175 views

Perturbation method & eigenvalues

I have a problem but I don't understand the question. It says: "Show that, to first order in energy, the eigenvalues ​​are unchanged." What does it mean? It means that if the Hamiltonian has the ...
2
votes
1answer
538 views

Solving time dependent Schrodinger equation in matrix form

If we have a Hilbert space of $\mathbb{C}^3$ so that a wave function is a 3-component column vector $$\psi_t=(\psi_1(t),\psi_2(t),\psi_3(t))$$ With Hamiltonian $H$ given by $$H=\hbar\omega ...
1
vote
1answer
412 views

Commutation relation with Hamiltonian

How do we get $[\beta , L] = 0$ , where $L$= orbital angular momentum and $\beta$= matrix from Dirac equation?
1
vote
1answer
226 views

Symmetry and overlapping of ground states

In a quantum mechanics, there is the following formula to derive the zero energy $E_0$ of a perturbed Hamiltonian $$H = H_0 + V$$ knowing the zero energy $W_0$ of the free Hamiltonian $H_0$: $$E_0 = ...
1
vote
3answers
422 views

Propagators and Probabilities in the Heisenberg Picture

I'm trying to understand why $$\Bigl|\langle0|\phi(x)\phi(y)|0\rangle\Bigr|^2$$ is the probability for a particle created at $y$ to propagate to $x$ where $\phi$ is the Klein-Gordon field. What's ...
1
vote
2answers
465 views

Confusion about Free Energy and the Hamiltonian

I'm probably making a relatively basic mistake here, but I'm a bit confused about the relation between the Hamiltonian and Helmholtz free energy. From what I can see, the free energy can be written ...
2
votes
1answer
82 views

What does $\psi_j(r_i)$ mean?

I have a mean-field Hamiltonian for N electrons. The mean-field potential felt by electron $i$ at position ${\bf r}_i$ is given by $V^{(i)}_{int}({\bf r}_i)=\sum_{j\ne i}|\psi_j({\bf r}_i)|^2$ I ...
1
vote
1answer
100 views

Where can I find hamiltonians + lagrangians?

Where would you say I can start learning about Hamiltonians, Lagrangians ... Jacobians? and the like? I was trying to read Ibach and Luth - Solid State Physics, and suddenly (suddenly a Hamiltonian ...
1
vote
1answer
562 views

The Hermiticity of the Laplacian (and other operators)

Is the Laplacian operator, $\nabla^{2}$, a Hermitian operator? Alternatively: is the matrix representation of the Laplacian Hermitian? i.e. $$\langle \nabla^{2} x | y \rangle = \langle x | ...
0
votes
2answers
382 views

Base states with hamiltonian matrix

It is better for you to have studied "Feynman lectures on Physics Vol.3", because I cannot distinguish whether the words or expressions are what Feynman uses only or not and in order to summarize my ...
0
votes
1answer
207 views

Stationary states with a pair of hamiltonian equations

I read some derivation related with probability amplitudes and hamiltonian matrix in some book, and have a few questions. Here what the book says is. We want the general solution of the pair of ...
1
vote
3answers
145 views

The notion of bounded states in quantum mechanics and their characterization with operators

Is there any case of potential $V$, such that the continuity of the operator $H=c\ \Delta+V$ is not spoiled? And I don't know any non-differnetial operator examples for continous spectra. I ...