3
votes
0answers
80 views

What does it mean to expand a Hamiltonian using perturbation theory?

On UC Davis chemwiki website, the Hamiltonian for quadrupolar coupling in NMR is analyzed. (The details of this aren't important.) It is said in the analysis that: The expansion of the ...
5
votes
1answer
75 views

Is there a physical interpretation to invariant random matrix ensembles?

Disclaimer. I am a graduate student in pure mathematics, so my knowledge of physics more advanced than basic 1st/2nd year undergraduate physics is very limited. I welcome corrections on any ...
3
votes
1answer
41 views

Quantum mechanics with non-cartesian coordinates

Let say we have the classical hamiltonian of a harmonic oscillator: $$H=\frac{p_x^2+p_y^2+p_z^2}{2m}+\frac{k_1x^2+k_2y^2+k_3z^2}{2}$$ and we want to find the hamiltonian operator in quantum mechanics, ...
7
votes
0answers
105 views

Role of physics in the zeta function $\zeta$ and the Riemann hypothesis

Hilbert and Polya suggested a physical way to verify the Riemann hypotesis about $\zeta(x)$. If the Riemann hypotesis is true, we can state all eigenvalues of physical problems are real. What is the ...
1
vote
2answers
53 views

What is the energy operator and from where do we get it?

I am trying to learn Quantum mechanics from MIT OCW Videos about quantum mechanics. I have reached the 5th lecture. Please help me in understanding this: In the middle (At 32:08), the professor wrote ...
3
votes
2answers
155 views

What is an “Interaction Hamiltonian”

I'm an undergraduate reading up on some quantum physics so that I can help out more in the lab that I'm working in this summer. In the book I'm reading (Shankar's "Principles of Quantum Mechanics") I ...
0
votes
1answer
46 views

Vanishing diagonal matrix elements of pertubation

In time-dependent pertubation theory we can denote the Schrödinger equation by a set of two equations $$\dot{c_a} = -\frac{i}{\hbar}\Big[c_aH'_{aa}+c_bH'_{ab}e^{-i(E_b-E_a)t/\hbar}\Big] \\ \dot{c_b} ...
1
vote
1answer
99 views

Quick question on perturbation theory

Suppose we have a particle in an infinite potential well, with $V(x) = 0,\space 0< x < a $ and infinity everywhere else. Now suppose we have a perturbation on the LHS of the well: $V_1(x) = v, ...
0
votes
1answer
60 views

Hamiltonian Operator for Harmonic Oscillator

I have been solving the harmonic oscillator problem in quantum mechanics using Algebraic Method and since then I am consulting the books of Tannoudji and Griffiths for that matter. While studying both ...
2
votes
1answer
68 views

On use of Hamiltonians for Helium

The Hamiltonian of helium can be expressed as the sum of two hydrogen Hamiltonians and that of the Coulomb interaction of two electrons. $$\hat H = \hat H_1 + \hat H_2 + \hat H_{1,2}.$$ The wave ...
2
votes
1answer
96 views

Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
0
votes
1answer
126 views

Calculating the expectation value of a Hamiltonian

I want to calculate the expectation value of a Hamiltonian. I have a wave function that is $$\psi = \frac{1}{\sqrt{5}}(1\phi_1 + 2\phi_2).$$ I want to know if I set this up properly. The ...
0
votes
1answer
44 views

Expectation value of Hamiltonian on number state [closed]

Hamiltonian is defined by $H_I = \hbar \omega (\hat{a}^+ \hat{a} + 1/2)$ What is the expectation value of the energy on the number state $$\vert \psi \rangle = \frac{1}{\sqrt{2}} ( \vert 1 \rangle ...
11
votes
2answers
276 views

Correct way to write the eigenvector of a diagonalized hamiltonian in second quantization

I am studying diagonalization of a quadratic bosonic Hamiltonian of the type: $$ H = \displaystyle\sum_{<i,j>} A_{ij} a_i^\dagger a_j + \frac{1}{2}\displaystyle\sum_{<i,j>} [B_{ij} ...
6
votes
1answer
115 views

What are the restrictions on the Hamiltonian in QM?

In quantum mechanics, we usually write the Hamiltonian as: $$\hat{H}=\hat{T}+\hat{V}$$ But in classical mechanics, there are several reasons why it would not have this form: We've chosen some ...
3
votes
2answers
149 views

Eigenenergies and eigenkets given the Hamiltonian

For a two level system the Hamiltonian is: $$ H=a(|1\rangle \langle1|-|2\rangle\langle2|+|1\rangle\langle2|+|2\rangle\langle1|) $$ where $a$ is a number with the dimension of an energy. I need to ...
0
votes
1answer
195 views

Proof of the time-independent Schrödinger equation

I have a question regarding the proof of the time-independent Schrödinger equation. So if we have a time-Independent Hamiltonian, we can solve the Schrödinger equation by adopting separation of ...
1
vote
1answer
116 views

Change of operator in the Hamiltonian [closed]

We are told that the particle has mass m and charge e and is moving in 2 dimensions. The position operator $\mathbf{X}=(X_{1},X_{2})$ and momentum operator $\mathbf{P}=(P_{1},P_{2})$ We are given ...
2
votes
1answer
194 views

How do I show that the eigenstates of a Hamiltonian can be made orthonormal?

I've been tearing my hair out over this all evening. It should be simple but I must be missing something somewhere. Can someone show me how to prove that the eigenstates of a Hamiltonian can be made ...
7
votes
1answer
120 views

Do systems with level crossings have unstable eigenbases?

It's folklore dating back to von Neumann and Wigner that time-dependent Hamiltonian systems tend not to have level crossings of their energy eigenvalues. However, we can of course consider smoothly ...
1
vote
2answers
618 views

Getting Energies and Probabilities from the Hamiltonian

So I need to find the possible energies and the probabilities of these using the eigenvalues of a Hamiltonian. Once I obtain the eigenvalues, are those the energies E_n in and of themselves? Or do ...
1
vote
2answers
150 views

Sign in the time-independent Schrödinger's equation

In the time-independent Schrödinger's equation: $$ -\frac{\hbar^2}{2m} \frac{d^2} {dx^2} u + Vu ~= Eu, $$ why there is a minus sign before the first term?
0
votes
1answer
184 views

Hamiltonian operator apply to a wavefunction

When a Hamiltonian operator apply to a wavefunction, how could we write the hamiltonian as, $$H \psi = (E_n-\hbar \omega_0) \psi \ \ ? $$ Is this because $E_n= H+ \hbar \omega_0$? where ...
2
votes
1answer
393 views

Hamiltonian matrix off diagonal elements?

I'm trying to understand how Hamiltonian matrices are built for optical applications. In the excerpts below, from the book "Optically polarized atoms: understanding light-atom interaction", what I ...
0
votes
0answers
98 views

Quantum Hamiltonian commuting with the Pauli-Runge vector

I have to prove that $[A_j, H] = 0$, with; $$\vec{A} = \frac{1}{2Ze^{2}m}(\vec{L} \times \vec{P} - \vec{p} \times \vec{L}) + \frac{\vec{r}}{r}$$ $$H = \frac{p^2}{2m} - \frac{Ze^2}{r}$$ And, $Z, e, ...
0
votes
3answers
470 views

Why can the Schroedinger equation be used with a time-dependent Hamiltonian?

I have a puzzle about Schroedinger equation with time-dependent hamiltonian, which is usually used in time-dependent quantum systems. However, one of the axioms in quantum mechanics postulates that ...
2
votes
0answers
147 views

Adiabatic quantum evolution of single photon or biphoton system

The prerequisite for adiabatic quantum evolution of single photon or biphoton system is as follows. We have to prepare a single photon or biphoton quantum system which has a ground and a higher level ...
3
votes
1answer
166 views

Intuition behind Hamiltonian

I am reading this paper by Das et al. which converts Deutsch's algorithm into an adiabatic quantum algorithm. I don't get the intuition behind the initial and final Hamiltonians. If defines the ...
4
votes
3answers
839 views

It appears that stationary states aren't so stationary

$$ \DeclareMathOperator{\dif}{d \!} \newcommand{\ramuno}{\mathrm{i}} \newcommand{\exponent}{\mathrm{e}} \newcommand{\ket}[1]{|{#1}\rangle} \newcommand{\bra}[1]{\langle{#1}|} ...
1
vote
0answers
116 views

What is the energy scale of a Hamiltonian?

On the second page of this paper a term 'fundamental energy scale' is used while talking about a Hamiltonian. The context is implementing Deutsch's algorithm using Adiabatic Quantum Computation. What ...
15
votes
2answers
648 views

Is the Ground State in QM Always Unique? Why?

I've seen a few references that say that in quantum mechanics of finite degrees of freedom, there is always a unique (i.e. nondegenerate) ground state, or in other words, that there is only one state ...
2
votes
0answers
49 views

Spin Transition Energies

I am reading a paper: http://arxiv.org/ftp/arxiv/papers/1305/1305.2445.pdf On p. 22, the following Hamiltonian is given: $$ H = \mu_B g \mathbf{B} \cdot \mathbf{S} + D(S_Z^2+\frac{1}{3}S(S+1)) + ...
1
vote
3answers
944 views

Energy Spectrum of pair of spin-1/2 particles with general Hamiltonian

I found this problem, and so far I am stumped. I was wondering if anyone wanted to solve it with me, or help me calculate eigenvectors, or just give insight on my questions. Consider a system of ...
1
vote
1answer
67 views

The Molecular Hamiltonian and the avoidance of Overcounting

Whenever I see the total non-relativistic molecular Hamiltonian, $\hat{H}_{molecular} = \hat{T}_{e} + \hat{T}_{n} + \hat{V}_{ee} + \hat{V}_{nn} + \hat{V}_{en}$ I always notice that the sums ...
2
votes
0answers
110 views

Number theoretical function applied in physics? [closed]

I have a series of number theoretic phenomena (mathematics) that I can describe exactly by the superpositions or linear combination of the below function (I know it is an inverse Fourier type). Does ...
1
vote
2answers
118 views

Molecular Hamiltonian

I was reading some material on the Molecular Hamiltonian on Wiki. It said that, Almost all calculations of molecular wavefunctions are based on the separation of the Coulomb Hamiltonian first ...
2
votes
2answers
334 views

How do we know that $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$?

I am kind of new to this eigenvalue, eigenfunction and operator things, but I have come across this quote many times: $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$. ...
2
votes
0answers
72 views

Boundary condition Hamiltonian with point tinteractions

I`m studying the Hamiltonian with point interaction centered in $y$ in three dimensions. I know that the elements in the domain of the Hamiltonian are of the form $$\psi=\phi+qG^z(\cdot-y)$$ where ...
3
votes
2answers
155 views

What is a symmetry of a physical system?

If I understand correctly, in many context in physics (quantum mechanics?), a physical system is specified by giving its Hamiltonian. I also hear that symmetries are rather essential. As far as the ...
7
votes
2answers
2k views

How to express a Hamiltonian operator as a matrix

Suppose we have Hamiltonian on $\mathbb{C}^2$ $$H=\hbar(W+\sqrt2(A^{\dagger}+A))$$ We also know $AA^{\dagger}=A^{\dagger}A-1$ and $A^2=0$, letting $W=A^{\dagger}A$ How can we express $H$ as $H=\hbar ...
3
votes
1answer
372 views

How does a state in quantum mechanics evolve?

I have a question about the time evolution of a state in quantum mechanics. The time-dependent Schrodinger equation is given as $$ i\hbar\frac{d}{dt}|\psi(t)\rangle = H|\psi(t)\rangle $$ I am ...
7
votes
2answers
3k views

How to construct the Hamiltonian matrix?

I'm trying to understand if there's a more systematic approach to build the matrix associated with the Hamiltonian in a quantum system of finite dimension. For example, I know that for the ammonia ...
3
votes
1answer
545 views

Alkali atom in oscilating electromagnetic field

I am trying to calculate atom - light (EM field) interaction Hamiltonian, and the results I get seem to me rather unphysical - I get some nonzero matrix elements which should not be there. Please, can ...
1
vote
0answers
112 views

Measurement in Quantum mechanics

I have got a quantum conservative system whose Hamiltonian is $H$. I consider an selfandjoint operator $O$ whose eigenvalues and eigenvectors are: $$O|\psi _{n}\rangle = \lambda _{n}|\psi ...
1
vote
1answer
131 views

Transform hamiltonian

I have got the following Quantum Hamiltonian: $$H=\frac{p^{2}}{2m}+k_{1}x^{2}+k_{2}x+k_{3}$$ Which transformation can I use to change this Hamiltonian into an harmonic oscillator hamiltonian? ...
1
vote
0answers
56 views

Length of the orbit (semiclassical orbits)

The Gutzwiller trace is about $$ d(E)=d_{0} (E)+ \sum_{p.o}A_{p}Cos(S(E)\ell_{p}) $$ and $ \ell_{p} $ are the length of the orbit. However my question is, how can one derive the length of the orbit ...
2
votes
2answers
2k views

Two expressions for expectation value of energy

I was looking up expectation value of energy for a free particle on the following webpage: http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/expect.html It says that $E=\frac{p^2}{2m}$ and ...
5
votes
2answers
651 views

Expectation value of time-dependent Hamiltonian

I'm trying to solve a problem in QM with a forced quantum oscillator. In this problem I have a quantum oscillator, which is in the ground state initially. At $t=0$, the force $F(t)=F_0 \sin(\Omega t)$ ...
6
votes
1answer
3k views

Evolution operator for time-dependent Hamiltonian

When i studyed QM I'm only working with non time-dependent Hamiltonians. In this case unitary evolution operator has the form $$\hat{U}=e^{-\frac{i}{\hbar}Ht}$$ that follows from this equation $$ ...
2
votes
1answer
178 views

Hubbard Model Hamitonian

$H = -\sum\limits_{i,j} A_{ij} c_i^{\dagger} c_j + \frac{U}{2} \sum\limits_i(c_i^\dagger c_i)(c_i^\dagger c_i -1)$ is defined to be a Hamiltonian for modeling quantum random walk of identical ...