0
votes
0answers
24 views

Dynamics of modifing a Hamiltonian

I am working on quantum mechanics right now, and I am wondering if there is a qualitative way to think about off diagonal term of a Hamiltonian matrix? I know that we can diagonalize a matrix, then ...
10
votes
1answer
371 views

What exactly does the Hamiltonian operator tell us?

I'm confused about how energy and time are linked. On the one hand, the Hamiltonian seems to describe the time evolution of the system because in the time dependent Schrodinger equation, $$ \hat H ...
1
vote
2answers
57 views

What is the energy operator and from where do we get it?

I am trying to learn Quantum mechanics from MIT OCW Videos about quantum mechanics. I have reached the 5th lecture. Please help me in understanding this: In the middle (At 32:08), the professor wrote ...
2
votes
1answer
121 views

Quick question on perturbation theory

Suppose we have a particle in an infinite potential well, with $V(x) = 0,\space 0< x < a $ and infinity everywhere else. Now suppose we have a perturbation on the LHS of the well: $V_1(x) = v, ...
2
votes
1answer
104 views

On use of Hamiltonians for Helium

The Hamiltonian of helium can be expressed as the sum of two hydrogen Hamiltonians and that of the Coulomb interaction of two electrons. $$\hat H = \hat H_1 + \hat H_2 + \hat H_{1,2}.$$ The wave ...
2
votes
1answer
99 views

Expectation value of Hamiltonian in different pictures of quantum mechanics

We start with the familiar Schrodinger equation: $$ i\hbar \frac{\partial \left|\psi_S\right\rangle}{\partial t} = \hat{H}_S \left|\psi_S\right\rangle $$ As we switch to a different picture than ...
10
votes
2answers
266 views

The formal solution of the Schrodinger equation

Let's have Schrodinger equation (or some equation in Schrodinger form) $$ \tag 1 i \partial_{0} \Psi ~=~ \hat{H} \Psi . $$ One likes to write that it has formal solution $$ \tag 2 \Psi (t) ~=~ ...
0
votes
1answer
214 views

Proof of the time-independent Schrödinger equation

I have a question regarding the proof of the time-independent Schrödinger equation. So if we have a time-Independent Hamiltonian, we can solve the Schrödinger equation by adopting separation of ...
1
vote
1answer
119 views

Change of operator in the Hamiltonian [closed]

We are told that the particle has mass m and charge e and is moving in 2 dimensions. The position operator $\mathbf{X}=(X_{1},X_{2})$ and momentum operator $\mathbf{P}=(P_{1},P_{2})$ We are given ...
1
vote
2answers
210 views

Representation of Hamiltonian in terms of “creation” and “destruction” operators

Let's have Schrodinger equation or Dirac equation in Schrodinger form: $$ i \partial_{0}\Psi = \hat {H}\Psi . $$ Sometimes we can introduce some operators $\hat {A}, \hat {B}$ (the second is not ...
1
vote
2answers
158 views

Sign in the time-independent Schrödinger's equation

In the time-independent Schrödinger's equation: $$ -\frac{\hbar^2}{2m} \frac{d^2} {dx^2} u + Vu ~= Eu, $$ why there is a minus sign before the first term?
0
votes
3answers
474 views

Why can the Schroedinger equation be used with a time-dependent Hamiltonian?

I have a puzzle about Schroedinger equation with time-dependent hamiltonian, which is usually used in time-dependent quantum systems. However, one of the axioms in quantum mechanics postulates that ...
4
votes
3answers
993 views

It appears that stationary states aren't so stationary

$$ \DeclareMathOperator{\dif}{d \!} \newcommand{\ramuno}{\mathrm{i}} \newcommand{\exponent}{\mathrm{e}} \newcommand{\ket}[1]{|{#1}\rangle} \newcommand{\bra}[1]{\langle{#1}|} ...
3
votes
1answer
431 views

How does a state in quantum mechanics evolve?

I have a question about the time evolution of a state in quantum mechanics. The time-dependent Schrodinger equation is given as $$ i\hbar\frac{d}{dt}|\psi(t)\rangle = H|\psi(t)\rangle $$ I am ...
2
votes
2answers
3k views

Two expressions for expectation value of energy

I was looking up expectation value of energy for a free particle on the following webpage: http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/expect.html It says that $E=\frac{p^2}{2m}$ and ...
2
votes
1answer
641 views

Solving time dependent Schrodinger equation in matrix form

If we have a Hilbert space of $\mathbb{C}^3$ so that a wave function is a 3-component column vector $$\psi_t=(\psi_1(t),\psi_2(t),\psi_3(t))$$ With Hamiltonian $H$ given by $$H=\hbar\omega ...
1
vote
1answer
107 views

Where can I find hamiltonians + lagrangians?

Where would you say I can start learning about Hamiltonians, Lagrangians ... Jacobians? and the like? I was trying to read Ibach and Luth - Solid State Physics, and suddenly (suddenly a Hamiltonian ...
1
vote
1answer
649 views

The Hermiticity of the Laplacian (and other operators)

Is the Laplacian operator, $\nabla^{2}$, a Hermitian operator? Alternatively: is the matrix representation of the Laplacian Hermitian? i.e. $$\langle \nabla^{2} x | y \rangle = \langle x | ...
6
votes
3answers
826 views

What is the relationship between Schrödinger equation and Boltzmann equation?

The Schrödinger equation in its variants for many particle systems gives the full time evolution of the system. Likewise, the Boltzmann equation is often the starting point in classical gas dynamics. ...