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20
votes
3answers
2k views

Prove that negative absolute temperatures are actually hotter than positive absolute temperatures

Could someone provide me with a mathematical proof of why, a system with an absolute negative Kelvin temperature (such that of a spin system) is hotter than any system with a positive temperature (in ...
3
votes
2answers
348 views

When do thermal and chemical equilibrium not coincide?

What is an example for a system, which is in chemical equilibrium, but not in thermodynamical equilibrium? And what about the other way around? It seems to me, that as long as Parameters like ...
0
votes
1answer
454 views

Examples of immiscible or wall-climbing liquids

I am very interested in the physics of immiscible fluids. I would like to ask you if you know any source or list of experiments done by others, with two or three liquids. I am interested in the final ...
8
votes
6answers
7k views

Why does maximal entropy imply equilibrium?

From a purely thermodynamical point of view, why does that entropy have to be a maximum at equilibrium? Say there is equilibrium, i.e. no net heat flow, why can the entropy not be sitting at a ...
9
votes
4answers
300 views

Is “equilibrium state” equivalent to “well-defined state variables”?

Follow up to Intuitively, why is a reversible process one in which the system is always at equilibrium? and How slow is a reversible adiabatic expansion of an ideal gas? Suppose you have a ...
2
votes
2answers
376 views

why egg cooks slowly in mountains?

A quick Google tells me "Because water boils at a lower temperature at high altitudes". But I am not being able to understand this answer and fill-in the gap. Like, how does an egg cook in the first ...
7
votes
5answers
3k views

How do we perceive hotness or coldness of an object?

Some objects, especially metallic ones, feel cold on touching and others like wood, etc. feel warm on touching. Both are exposed to same environment and are in their stable state, so some kind of ...
7
votes
4answers
426 views

Applying the Maxwell–Boltzmann statistics to astrophysical objects

Quoting Wikipedia: In statistical mechanics, Maxwell–Boltzmann statistics describes the statistical distribution of material particles over various energy states in thermal equilibrium, when the ...
1
vote
1answer
540 views

Statistical physics of molecular dissociation of a diatomic gas

Say there are $N$ atoms of type $A$ in a box of volume $V$ and they are undergoing a reversible association-dissociation reaction $A + A = A_2$. Let an $A$ atom have mass $m$, and hence the molecule ...
1
vote
1answer
406 views

Upper equilibrium point of a pendulum with small perturbations

I remember the following fact about a rigid pendulum: The point when the pendulum weight is lowest is a stable equilibrium while the point where the pendulum weight is highest is an unstable one. ...
41
votes
7answers
4k views

Why is the Earth so fat?

I made a naive calculation of the height of Earth's equatorial bulge and found that it should be about 10km. The true height is about 20km. My question is: why is there this discrepancy? The ...
4
votes
2answers
965 views

Calculate stainless steel pole necking limit

Background Trying to determine how much weight a post can support without necking when a monitor is attached to an articulated arm: a cantilever problem. Problem There are three objects involved in ...
4
votes
1answer
170 views

Boltzman distribution for chemical potentials

I read that if we have a system with two co-existing phases with chemical potentials respectively $\mu_1$ and $\mu_2$ then, at the equilibrium, the concentrations $X_1$ and $X_2$ are related by the ...
5
votes
2answers
1k views

What determines the (minimum) angle at which a domino falls over?

Dominoes, when placed upright, remain that way. Sometimes, even if you tip them a little bit, they will go back to their upright position. However, if you tip them too far, they will fall over. ...