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problem about heat in thermodynamics

$$\nabla G=-T\nabla S-T\nabla S_{sur}=-Q+q $$ $$\nabla G=-T\nabla S-T\nabla S_{sur}=-(U-W_{rew})+q $$ $$\nabla G=-T\nabla S-T\nabla S_{sur}=-(q+W-W_{rew})+q $$ $$\nabla G=-T\nabla S-T\nabla ...
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1answer
77 views

Is state defined for non-equilibrium systems?

Equilibrium thermodynamic states follow the state principle and Gibb's phase rule when it comes to fixing a state when given a minimum of (typically) 2 state properties. For non-equilibrium states, I ...
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0answers
38 views

Why is it valid to assume that the liquid-vapour interface is always saturated during evaporation?

For steady state evaporation, I read from two textbooks which simply states that the partial pressure of vapour of interest (say water) at the liquid-vapour interface is equal to the saturation ...
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2answers
432 views

Understanding the Jacobian Matrix

Taking the example of a two dimensional system, desribred by the following ODE's: \begin{align} \frac{dx_1}{dt}&=f_1(x_1,x_2)\\ \frac{dx_2}{dt}&=f_2(x_1,x_2) \end{align} The Jacobian Matrix ...
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1answer
24 views

Electrical charge equilibrium and the piezoelectric effect

About the piezoelectric effect: if I press a crystal the electrical charges segregate and an electrical voltage appears on the other two faces of the crystal. See this link for example: ...
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0answers
67 views

Detailed Balance for Quantum Master Equations from System Hamiltonians with Degenerate Spectrum

Kossakowski, Andrzej, et al. ("Quantum detailed balance and KMS condition." Communications in Mathematical Physics 57.2 (1977): 97-110) gave a proof that the stationary state of a quantum dynamical ...
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1answer
115 views

'Mechanical equilibrium does not necessarily mean that the pressure is same at all points of the system' - why?

If there are variations in pressure or elastic stress within the system,parts of the system may move, or expand or contract. Eventually these motions,expansions or contractions will cease, and when ...
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3answers
184 views

Unstable equilibrium in a pendulum

Consider a pendulum with a bob and a massless, rigid, hinged rod attached to the bob. The bob is at rest at the bottom most position. Neglecting friction, is it possible to impart such a velocity ...
2
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1answer
95 views

Can't understand the meaning of a formula describing a stable equilibrium?

I've found this formula in a book and I can't understand its meaning: $$\frac{df}{dx}\biggr|_{x_0} < 0$$ It describes the condition of an object to being in a $\textit{stable}$ equilibrium. At ...
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1answer
46 views

Do Monte-Carlo updates have a physical significance in stat. mech?

One of the archetypical example to introduce Monte-Carlo methods in stat. mech. is to work out the properties of the 2D square lattice Ising model and compare the obtained results with Onsager's exact ...
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2answers
232 views

How does the temperature in a bucket of water with ice change over time?

I'm curious what happens to the temperature of the water in a bucket of water with ice in it. Let's start with a bucket with just ice in it, and we add water, in a room which is room temperature. It ...
2
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1answer
92 views

What's the point with equilibrium in Thermodynamics?

All the Thermodynamics books I saw until now state that in Thermodynamics we are mainly concearned with equilibrium states (I know there's "non-equilibrium Thermodynamics", but I'm interested on the ...
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1answer
160 views

H-theorem and Boltzmann equation applied to Boltzmann distribution

Using the Boltzmann equation: $$ \frac{dH}{dt} = \int_0^{\infty} dr \int_0^{\infty} ds W(r,s)[p_r - p_s][\ln{p_r} - \ln{p_s}],$$ and assuming $p_r = e^{-\beta r}$, the equation looks like $$ ...
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0answers
21 views

Perfectly vertical spinning top [duplicate]

Consider a non-spinning top. If a top is perfectly vertical, and the interface between its base and the ground is perfectly flat, it should stay in (unstable) equilibrium. I.e. it does fall. What ...
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3answers
141 views

Ice and liquid water interacting across a boundary

Imagine we have two thermodynamic systems, one a mass of ice and the other an equal mass of liquid water, with both at 273.16K. Each system is isolated, except that they can interact with each other ...
2
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1answer
55 views

Does the entropy of a system vary in the equilibrium?

I am not physicist and this question may seem trivial. But I understand that in the equilibrium the magnitudes such as temperature or volumen do not vary. Is the same for entropy? My logical says that ...
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1answer
124 views

Finding equilibrium of mechanical system

A system is described as follows: Consider a system consisting of two rotating bars of length $l$ and with uniform mass density and each with total mass $m$. The bars are attached to a common ...
3
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1answer
176 views

Why is $\omega = \sqrt{K/m}$ valid for a quantum oscillator?

I'm working in the 3rd edition of Modern Physics by Serway, Moses, and Moyer. In 6.6, it talks about a quantum oscillator. I don't fully understand how the definition of frequency works. Now, we ...
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0answers
175 views

Torque of person on bridge [closed]

Consider a 10 meter bridge that weighs 500 N supported at both ends. A person who weighs 750 N is standing 2 m from the end of the bridge. What are the forces $F_a$, $F_b$ holding the bridgeup at ...
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1answer
72 views

Transmission/Equilibrium Question

Suppose there are two wheels linked by some kind of apparatus with a transmission, in a vacuum. Wheel A is spinning, wheel B is not. Is it empirically possible for the transmission to transfer the ...
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0answers
41 views

How to calculate the partial entropy in a fully connected ising system

I'm trying to reproduce a calculation that should lead to the partial entropy in a fully connected ising model for the high-temperature range ($\beta < 2$) in the thermodynamic Limit ($N ...
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2answers
438 views

Do airlocks in space decompress violently as they do in movies?

The standard scene follows: The good guys have finally captured the enemies and have them in an airlock chamber on a spaceship. A button is pressed and out they go, violently propelled by the blast of ...
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2answers
144 views

How quickly should a fluid come to hydrostatic equilibrium?

Let's say I'm holding a one-liter water bottle, full of water, which I then drop. Before dropping the water bottle, the equilibrium is for there to be a pressure gradient in the water canceling the ...
3
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1answer
197 views

Lagrangian formulation of the problem: small oscillations around an equilibrium

I'm having trouble understanding how some conclusions are made in my book. I'm studying from a coursebook based on Goldstein's "Classical Mechanics", here's what's written in my book, with my problems ...
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2answers
531 views

Why mountain roads are winded up rather than keeping them straight? [closed]

In my opinion, to prevent the line passing from the center of gravity of a body (e.g bike or car) trying to climb the mountain or hill to fall outside the base of support so to maintain stable ...
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1answer
490 views

Mechanics question - ladder leaning against a wall

I am struggling with part a) of this question: Here is the solution: In part a) they prove that $F \leq \mu R$ is false for this system. So as $F$ is neither less than nor equal to $\mu R$ it ...
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0answers
43 views

Criteria for stable equilibrium [closed]

A homogeneous wooden bar of length 10 cm, thickness 4 cm and weight 1 Kg is balanced on the top of a semicircular cylinder of radius R as shown below. What is the minimum radius of the semicircular ...
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0answers
241 views

Truss Analysis with multiple moments creates linear combinations

So in my engineering statics course we have been doing a great deal of work with trusses and machines, and a part of the physics behind it has really been confusing me. Just as a note, I also have ...
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1answer
79 views

What is the relevance of potential energy as a concept?

As far as i understand, for an object to have a fixed quantity of potential energy, it must be in current equilibrium and have no net force applied to it (otherwise the potential would convert to ...
1
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1answer
62 views

How can the tension force be computed to test if a shape is moving or not?

Source Given the coordinates of $n$ 3D joints ($1kg$ each) connected by $m$ rods. Assume rods have zero mass and joints with $z=0$ are fixed to the ground while others are free to move, will the ...
2
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3answers
175 views

Equilibrium that is not stable

Consider a system which is in an equilibrium state. Now, a small perturbation causes it to start oscillating about the equilibrium state, but over time, the momentum with which it overshoots the ...
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0answers
36 views

How does a simple weighing balance actually work? [duplicate]

I have made a simple sketch of how I think the system looks like. My problem is: I always thought that the angle the balance makes is a function of the difference between the two masses (or the ...
3
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1answer
5k views

Difference between steady state and equilibrium?

In semiconductor physics, what is the difference between steady state and equilibrium. How analysis of devices varies in these processes?
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2answers
312 views

Physical significance of Taylor and Maclaurin series - What is the significance of defining a Maclaurin series in Mathematical Physics?

In physics, usually Taylor series is used to express a quantity which keep changes with coordinate. For example the potential energy of a molecule changes with coordinate, so we express the potential ...
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1answer
49 views

What is the equivalent of a eutectic point for a (two-liquid)+solids system?

I deal with complex phase equilibria involving solid and liquid phases at high temperature. Below is a simplified temperature-XH2O diagram for a multicomponent system at constant pressure. (Note: ...
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0answers
44 views

Vacancy Generation / Annihilation Time (Relaxation Time)

Vacancy Generation/Annihilation Time, Recombination Time and Relaxation Time ($\tau$) are all synonymously used in atomic physics literatures. They're defined as the time that it takes for vacancies ...
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2answers
346 views

Equilibrium of of water level in punctured bucket?

Would a bucket with a hole in the bottom being filled at different rates with water come to to different equilibrium levels with in the bucket? Or would at any fill rate above initial flow rate of ...
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4answers
530 views

Is vapour pressure based on partial pressures or just total pressure on the liquid?

The explanation for the boiling point of water is that at 100C, the vapour pressure becomes greater than atmospheric pressure. But say you had a a jar of water sealed in argon at 1atm, which is larger ...
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1answer
45 views

States of Matter and Equilibrium

Can I say that, matter generally when cooled decreases in volume because, when it is cooled,i.e., we lower the temperature of the surroundings, then the avg. energy of our sample will be higher than ...
0
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1answer
102 views

What happens to matter when in a thermodynamic equilibrium?

I am trying to gain a better understanding of thermodynamic equilibrium. Here's what (I think) I know: If a system is in Thermal, Radiative, Chemical, and Mechanical Equilibrium, then it is in ...
2
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1answer
174 views

Earnshaw's theorem and springs

Earnshaw's theorem states that the Laplacian of the potential energy of a small charge moving through a landscape full of static negative and/or positive charges (and gravity) is zero. Thus you can't ...
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1answer
516 views

Classify equilibrium points and find bifurcation points of a non-linear dynamic system

Context: The question refers to computational physics of non linear systems with Mathematica. Excercise: Given the system $\{f_1: \dot{x} = a x + y + x^3, f_2: \dot{y} = x - y \}$: Find the ...
1
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1answer
169 views

Can exergy and exergy destruction be understood through thermodynamical and/or statistical-mechanical principles?

My textbook Fundamentals of engineering thermodynamics, Moran and Shapiro states: The exergy is the maximum theoretical work obtainable for an overall system consisting of a system and the ...
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2answers
332 views

Equilibrium - uniform circular motion

Maybe this is a bit of a silly question, but let us pretend we have a pendulum in a ideal universe with no friction, drag, or anomalous forces there to affect it. Additionally, our pendulum is ...
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6answers
592 views

Why a system should be at its lowest energy state for its stability?

Every possible reaction in chemistry is to attain stability. In physics, the alignment of an electric dipole in an external electric field and in all other physical systems (at least those I study in ...
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3answers
318 views

Airplane with banner in a windy day

Will the banner of this airplane be always in the proper direction if the airplane flies in any direction on a windy day?
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1answer
69 views

Uniqueness of equilibria in electrostatics

I have the following problem. Suppose we place some continuous charge distribution (with total charge $Q$)on some conducting domain. The charge will redistribute itself on the domain until it's in ...
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2answers
666 views

Forces acting on a body in equilibrium

The resultant force acting on a body in equilibrium is 0: $$\iiint_R \rho {\bf b}\ dV + \iint_S {\bf t}^{(n)} ds = 0,$$ in which $R$ is a region inside the body, $\rho {\bf b}$ the body force per ...
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1answer
2k views

Estimate temperature and pressure of steam in a pot of boiling water

Suppose we have a pot of known dimensions filled to level L with boiling water on a stove, covered by a lid with a vent of known dimensions. Given the steady-state temperature of the stove (bottom of ...
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0answers
54 views

Reconciling Different Vapor Pressure Definitions

In describing vapor pressure, I have often heard the following intuition: Assume a closed container that is partially filled with water. Above the water lies a vacuum. The water will vaporize until ...