0
votes
1answer
46 views

'Mechanical equilibrium does not necessarily mean that the pressure is same at all points of the system' - why?

If there are variations in pressure or elastic stress within the system,parts of the system may move, or expand or contract. Eventually these motions,expansions or contractions will cease, and when ...
1
vote
2answers
52 views

How does the temperature in a bucket of water with ice change over time?

I'm curious what happens to the temperature of the water in a bucket of water with ice in it. Let's start with a bucket with just ice in it, and we add water, in a room which is room temperature. It ...
2
votes
1answer
53 views

What's the point with equilibrium in Thermodynamics?

All the Thermodynamics books I saw until now state that in Thermodynamics we are mainly concearned with equilibrium states (I know there's "non-equilibrium Thermodynamics", but I'm interested on the ...
1
vote
3answers
122 views

Ice and liquid water interacting across a boundary

Imagine we have two thermodynamic systems, one a mass of ice and the other an equal mass of liquid water, with both at 273.16K. Each system is isolated, except that they can interact with each other ...
3
votes
1answer
30 views

What is the equivalent of a eutectic point for a (two-liquid)+solids system?

I deal with complex phase equilibria involving solid and liquid phases at high temperature. Below is a simplified temperature-XH2O diagram for a multicomponent system at constant pressure. (Note: ...
1
vote
0answers
35 views

Vacancy Generation / Annihilation Time (Relaxation Time)

Vacancy Generation/Annihilation Time, Recombination Time and Relaxation Time ($\tau$) are all synonymously used in atomic physics literatures. They're defined as the time that it takes for vacancies ...
0
votes
4answers
208 views

Is vapour pressure based on partial pressures or just total pressure on the liquid?

The explanation for the boiling point of water is that at 100C, the vapour pressure becomes greater than atmospheric pressure. But say you had a a jar of water sealed in argon at 1atm, which is larger ...
0
votes
1answer
92 views

What happens to matter when in a thermodynamic equilibrium?

I am trying to gain a better understanding of thermodynamic equilibrium. Here's what (I think) I know: If a system is in Thermal, Radiative, Chemical, and Mechanical Equilibrium, then it is in ...
0
votes
0answers
74 views

Can I make a cold air trap (thermal equilibrium)

Thermodynamic buoyancy. I have an air intake for combustion air entering into a basement furnace room. During cold weather, the air enters unchecked (no damper on pipe is allowed). I have this 5 ...
0
votes
0answers
51 views

Equilibrium Condition

In classical thermodynamics, equilibrium conditions means maximum entropy for a closed state. However, people always talk about equilibrium for open systems as well. How can one say that an open ...
1
vote
1answer
140 views

Can exergy and exergy destruction be understood through thermodynamical and/or statistical-mechanical principles?

My textbook Fundamentals of engineering thermodynamics, Moran and Shapiro states: The exergy is the maximum theoretical work obtainable for an overall system consisting of a system and the ...
1
vote
0answers
968 views

Definitions in thermodynamics: temperature, thermal equilibrium, heat

I'm currently reading Fermi's "Thermodynamics" and I'm trying to grasp the (possibly different) right definitions for temperature, thermal equilibrium, heat. To clarify, I'm looking for definitions ...
1
vote
0answers
76 views

Biological Themodynamics - What does an endpoint saturated signal mean. How does it relate to equillibrium constant

I have had a question that has been bugging me for a couple of years in my graduate school career, and I was wondering if perhaps some physicist could help explain it to me. Given an endpoint assay ...
0
votes
1answer
332 views

Calculating the amount of dissolved gases in a liquid?

The most basic situation, water at room temperature, has dissolved oxygen, CO2, and more. Why is this? How would one calculate how much gas should be dissolved in any given liquid?
4
votes
4answers
273 views

Dissolving oxygen into water

I was wondering how one would actually calculate how much oxygen would dissolve into water given the necessary initial conditions, and what those initial conditions would need to be. I assume they ...
0
votes
2answers
561 views

Minimization of energy and maximization of entropy

Are maximization of entropy and minimization of energy equivalent? Or are they contrary? Why should the thermodynamic potentials such as $G$, $A$, etc, be minimum at equilibrium? I am confused. ...
7
votes
1answer
423 views

Why is (von Neumann) entropy maximized for an ensemble in thermal equilibrium?

Consider a quantum system in thermal equilibrium with a heat bath. In determining the density operator of the system, the usual procedure is to maximize the von Neumann entropy subject to the ...
1
vote
0answers
45 views

Any new texts directly on second law of thermodynamics? [duplicate]

Possible Duplicate: Recommendations for Statistical Mechanics book Is anyone aware of any recent text that summarises the research and arguments on second law of thermodynamics and also on ...
15
votes
4answers
3k views

Why does the nature always prefer low energy and maximum entropy?

Why does the nature always prefer low energy and maximum entropy? I've just learned electrostatics and I still have no idea why like charges repel each other. ...
0
votes
1answer
127 views

Evolution of Gibbs energy change of reaction with temperature

The Gibbs energy change of reaction is given by $$\Delta G^0_{rx}=\Delta H^0_{rx}-T\Delta S^0_{rx}$$ From the look of it seems the direction of variation of equlibrium with $T$ is given by the sign ...
3
votes
2answers
403 views

Time to establish saturated vapour pressure above liquid

Thought experiment - a liquid is in a closed container in equilibrium with its vapour, and then suddenly all the vapour is pumped away. Switch off the pump so that instantaneosuly there is no vapour ...
3
votes
3answers
238 views

What are some creative illustrations of the nature of dissipative forces?

I'm teaching a conceptual introduction to physics for American 13-15 year old students this summer. One of the main ideas I want to hit on is the relationship between energy conservation, ...
20
votes
3answers
2k views

Prove that negative absolute temperatures are actually hotter than positive absolute temperatures

Could someone provide me with a mathematical proof of why, a system with an absolute negative Kelvin temperature (such that of a spin system) is hotter than any system with a positive temperature (in ...
3
votes
2answers
334 views

When do thermal and chemical equilibrium not coincide?

What is an example for a system, which is in chemical equilibrium, but not in thermodynamical equilibrium? And what about the other way around? It seems to me, that as long as Parameters like ...
8
votes
6answers
7k views

Why does maximal entropy imply equilibrium?

From a purely thermodynamical point of view, why does that entropy have to be a maximum at equilibrium? Say there is equilibrium, i.e. no net heat flow, why can the entropy not be sitting at a ...
9
votes
4answers
286 views

Is “equilibrium state” equivalent to “well-defined state variables”?

Follow up to Intuitively, why is a reversible process one in which the system is always at equilibrium? and How slow is a reversible adiabatic expansion of an ideal gas? Suppose you have a ...
2
votes
2answers
342 views

why egg cooks slowly in mountains?

A quick Google tells me "Because water boils at a lower temperature at high altitudes". But I am not being able to understand this answer and fill-in the gap. Like, how does an egg cook in the first ...
7
votes
5answers
3k views

How do we perceive hotness or coldness of an object?

Some objects, especially metallic ones, feel cold on touching and others like wood, etc. feel warm on touching. Both are exposed to same environment and are in their stable state, so some kind of ...
4
votes
1answer
168 views

Boltzman distribution for chemical potentials

I read that if we have a system with two co-existing phases with chemical potentials respectively $\mu_1$ and $\mu_2$ then, at the equilibrium, the concentrations $X_1$ and $X_2$ are related by the ...