A important extensive property of all systems in thermodynamics, statistical mechanics, and information theory, quantifying their disorder (randomness), i.e., our lack of information about them. It characterizes the degree to which the energy of the system is *not* available to do useful work.

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Why is entropy defined as a discrete sum over all microstates in classical case?

I'm reading about statistical definition of entropy, which says $$S=-k_B\sum_ip_i\ln p_i,\tag1$$ where $k_B$ is Boltzmann's constant, and $p_i$ is probability of $i$th state to be occupied. But in ...
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3answers
2k views

What is the meaning of Boltzmann definition of Entropy?

I would like to ask if someone knows the physical meaning of Boltzmann's definition of entropy. of course the formula is pretty straightforward $$S=K_b\ln(Ω)$$ but what in the heck is the natural ...
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1answer
90 views

Number theoretic loophole allows alternative definition of entropy?

A bit about the post I apologize for the title. I know it sounds crazy but I could not think of an alternative one which was relevant. I know this is "wild idea" but please read the entire post. ...
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Second law of thermodynamics and the arrow of time: why isn't time considered fundamental?

I've come across this explanation that the "arrow of time" is a consequence of the second law of thermodynamics, which says that the entropy of an isolated system is always increasing. The argument is ...
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1answer
132 views

Why is the logarithm of the number of all possible states of a system differentiable?

Temperature of a system is defined as $$\left( \frac{\partial \ln(\Omega)}{ \partial E} \right)_{N, X_i} = \frac{1}{kT}$$ Where $\Omega$ is the number of all accessible states (ways) for the system. $ ...
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31 views

Have we found a resolution to the Loschmidt paradox? [duplicate]

Loschmidt's Paradox (also known as the Reversibility Paradox) claims that it is not possible to deduce an irreversible process from time-symmetric dynamics such as the classic dynamics. This puts the ...
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2answers
36 views

Can the law of entropy decide our fate? [on hold]

Second law of thermodynamics states that entropy always increases.Elixir of immortal life is a thing humans are longing for since ages.Does this law forbid us from becoming immortal?I mean if disorder ...
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1answer
216 views

Explicit form of the entropy production in hydrodynamics

I'm trying to understand how hydrodynamics arise from a precise, mathematical formulation of thermodynamics, learning mostly from Landau's "Hydrodynamics". So Landau starts from formulating the ...
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4answers
150 views

What is the cause for the inclusion of 'thermal equilibrium' in the statement of Ergodic hypothesis?

This is the fundamental assumption of statistical mechanics: In an isolated system in thermal equilibrium $^1$, all accessible microstates are equally probable. But why does it mention the ...
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6answers
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Why was the universe in a extraordinarily low-entropy state right after the big bang?

Let me start by saying that I have no scientific background whatsoever. I am very interested in science though and I'm currently enjoying Brian Greene's The Fabric of the Cosmos. I'm at chapter 7 and ...
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2answers
269 views

How can heat turn into light

I am confused about how hot surfaces can radiate light to their surroundings. When I shine a light on a surface the light turns to heat spontaneously, and when I leave that hot surface it radiates ...
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1k views

What is the conceptual difference between Gibbs and Boltzmann entropies?

In simple words what is the conceptual difference between Gibbs and Boltzmann entropies? Gibbs entropy: $S=-k_B\sum p_i\ln p_i$ Boltzmann entropy: $S=-k_B\ln \Omega$
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1answer
43 views

Why are $S = -k_B\sum_i P_i \ln P_i$ and $S = k_B \ln\Omega$ equivalent?

This might be a silly question, but I don't see the equivalence relation between these two equations. Could somebody explain to me how to derive one from the other? Thanks in advance!
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3answers
88 views

The second law of thermodynamics and life on Earth [closed]

The second law of thermodynamics says that order always decreases in a system. The appeareance of life seems to contradict that law, but if we invoke the Sun, everything faals into place again. But ...
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7answers
13k views

Why does maximal entropy imply equilibrium?

From a purely thermodynamical point of view, why does that entropy have to be a maximum at equilibrium? Say there is equilibrium, i.e. no net heat flow, why can the entropy not be sitting at a ...
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1answer
125 views

How does entropy change when heat is transfer into a system reversibly with constant T?

My guess will be deltaS system : increase [because heat is flowing into the system] deltaS surrounding: decrease [because heat is leaving the environment] deltaS universe (sys+surr) : 0 because it ...
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0answers
38 views

Does it take the same amount of time, it takes for a system to get to a low-entropy (fluctuation) state from equilibrium, to go in the other way?

Let a system be in a state of fluctuation - a state of low-entropy at $t_0\;.$ Then before and after a sufficiently large but finite time-interval, the system would again be at equilibrium. As the ...
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7answers
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How do you prove the second law of thermodynamics from statistical mechanics?

How do you prove the second law of thermodynamics from statistical mechanics? To prove entropy will only increase with time? How to prove? Please guide.
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2answers
60 views

Exact differentials and state functions

I was reading a Wiki article on the relationships between heat capacities And during the derivation I came across this formula (and others like it): This equation was used as a tool in a ...
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1answer
143 views

Why doesn't the separation of particles by mass via gravity decrease entropy?

Let's say we've got a fluid of heavy and light particles inside a cubical flask, which is initially shaken up so that the density of heavy particles is uniform everywhere. Let's also say that these ...
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8answers
4k views

Entropy is…disorder?

As I read somewhere, it said that the universe is heading toward disorder a.k.a entropy increasing. Now as far as I know from the second law of thermodynamics it states that entropy is indeed ...
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2answers
109 views

Is black hole formation reversible if physics law holds even in time reverse?

As we know many situations still fulfill physics law if time is reversed, such as particle collision. But how about black hole formation? Suppose a star is turning to a black hole and starts to have ...
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0answers
28 views

Extra 5/2 tau term in chemical potential of a monoatomic ideal gas? [closed]

The chemical potential of an ideal monoatomic gas should be: $\mu = \tau ln \frac {n}{n_Q}$ http://web.mit.edu/ndhillon/www/Teaching/Physics/bookse5.html I get this result if I derive it using the ...
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4answers
201 views

How can there be entropy change in this system?

How can there be an entropy change in this system? Suppose if I have a system consisting of liquid water, $1\, \mathrm{kg}$ at $290\,\mathrm{K}$, I stir it, and do say, $10\, \mathrm{J}$ of work on ...
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139 views

Entropy / Structure Relations

I want to check on the validity of the following objective definition of order. Is it correct? Is there a more rigorous statement of this concept? The further a system is from its maximum ...
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3answers
201 views

Entropy change in an irreversible process between 2 equilibrium state

Calculating entropy change in an irreversible process between 2 states requires computing the change in entropy for any reversible process between the 2 same states, but why? If someone could provide ...
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5answers
460 views

Definition of entropy in thermodynamics

In most textbooks, the definition of entropy in reversible processes on a system $S$ is given simply as $$d S=\delta Q/T.$$ It seems to me this definition is insufficient since it does not specify ...
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3answers
111 views

At an instant, does a system of gravitational charges exhibit equivalent behavior to a time-reversed system of like electric charges?

Question: In principle, does a system of gravitational charges exhibit equivalent behavior to a time-reversed system of like electric charges? (At a single instance in time?) Additional Notes: I am ...
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3answers
131 views

Is there really a direction of time?

Laws of physics are (almost) time symmetric, so a time-reversed description of a physical process is as qualified as the original one. What's the reason then, that in reality one version seems to ...
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2answers
57 views

Thermodynamics and Newton's second law

Is it correct to say, that the Newton's laws (or a Newtonian system) is reversible if the friction isn't considered (the fact that the time is of second order $\frac{d^2x}{dt^2}$) and an isolated ...
2
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1answer
42 views

Why must the total change in entropy be 0 for a heat cycle to be as efficient as possible?

If $\Delta S_{total}$ were not zero, then heat flow would take place at different temperatures. It is easy to see why this is true by examining the opposite: that when heat flow takes place at the ...
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0answers
18 views

How would one derive a theoretical anti-entropic force equation? [closed]

How would one imagine and formulate a theoretical force that counteracts the second law of thermodynamics? I'm not conceptualizing a force that merely pauses Entropy, but a force that creates order, ...
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2answers
91 views

Why can't the entropy of an isolated system decrease? [duplicate]

I read that heat cannot flow from cooler body to hotter because for that entropy of the system becomes negative. Why is that so? Why we cannot have negative entropy?
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91 views

Doesn't this LED created by MIT violate the second law of thermodynamics?

Here is the article I am referring to: http://www.wired.co.uk/news/archive/2012-03/09/230-percent-efficient-leds In their own words (or at least the article writer's), "it appears to draw in heat ...
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0answers
39 views

Could the Big Bang be the result of a decrease in entropy?

In my freshman engineering physics class I learned that a decrease in entropy, though hypothetically possible, is less statistically likely than either any or almost any other possible single ...
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2answers
228 views

Second law of thermodynamics (in terms of entropy)

Is the second law of thermodynamics (in terms of entropy) for closed systems or isolated systems? I thought it must be valid for isolated systems, such as the Universe. But the book Fundamentals of ...
3
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1answer
79 views

A mass falls to the ground from a height. What's the change of the entropy of the universe?

A mass $m$ falls to the ground from a height $h$. The temperature $T$ is constant. What's the change of the entropy of the universe? It's an example in Carter's Classical and Statistical ...
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1answer
103 views

If time is like space, why entropy always increases with time? [duplicate]

If time is like space, why entropy always increases with time I should not be able to distinguish whether I am going forwards or backwards in time. As entropy always increase with time. I can ...
3
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2answers
160 views

Is entropy absolute (as in absolute temperature)?

Following this question on the Entropy at the Big Bang where I asked: Since Entropy always increases (in general); its expected that the entropy at the beginning of the universe should be the ...
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2answers
854 views

Difficulties with understanding total entropy change and unavailabillty

Of course, I know the fact that the entropy of an isolated system never decreases. Neverthless what makes me confused about the entropy(or change of entropy) of an isolated system is the explanation ...
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1answer
120 views

Is entropy related to Poincare recurrence time?

One of the ideas involved in the concept of entropy is that nature tends from order to disorder in isolated systems. But we even know that Poincare recurrence time also is a particular time after ...
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0answers
44 views

Behavior of maximum entropy states in a closed system?

As I understand it, entropy is a measure of the number of permutations of microstates of a system possible, without changing the observed 'macrostate variables' / measurements or properties of a ...
2
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2answers
1k views

Physics-based derivation of the formula for entropy

I am looking for a derivation of the formula $$S~=~-\Sigma_ip_i \log (p_i).$$ for entropy, from first principles. I only wish to assume the laws of physics, and without involving concepts in ...
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1answer
1k views

Motivation for the use of Tsallis entropy

Every now and again I hear something about Tsallis entropy, $$ S_q(\{p_i\}) = \frac{1}{q-1}\left( 1- \sum_i p_i^q \right), \tag{1} $$ and I decided to finally get around to investigating it. I haven't ...
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0answers
35 views

Is uncertainty principle due to entropy? [duplicate]

Is uncertainty principle due to entropy or thermodynamics at all , I was wondering
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3answers
77 views

How can a reversible adiabatic expansion not increase entropy?

In the second stage of the Carnot cycle, a gas is thermally insulated and allowed to expand and do work on the piston. I understand the reason people give is that because entropy is $\,dS = \,dQ/T$ ...
3
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3answers
146 views

Entropy of loops in the PV plane

The change in entropy of the Carnot and reversible cycles is said to be 0. Several other loops are supposed to have a non-negative change in entropy. This presents 2 problems which I cannot ...
2
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2answers
182 views

The black hole paradox

I recently read in the news that Stephen Hawking claims to have solved the Black Hole Information paradox. I researched a bit about the paradox and the research that Stephen Hawking did to solve it. ...
3
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1answer
108 views

What exactly is entropy? Why is it measure of randomness? [duplicate]

What exactly is entropy? Why is it measure of randomness? I have been told Entropy is measure of randomness and it increases everytime randomness increases. What is Randomness? Randomness in what? ...
2
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1answer
68 views

Direction of time in an insulated room

I am puzzled with thought experiment that resembles/is version of Bolzmann's brain-hyphothesis. I could explain it in following way: Let’s assume that we have isolated system full of some stuff, ...