A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

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Exploding planets and entropy

Say we have a planet and we blow it up to tiny pieces that gets spread out in a cloud of debris around the planets original location. This cloud of debris is analogue to a cloud of water wapor in ...
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Physics-based derivation of the formula for entropy

I am looking for a derivation of the formula $$S~=~-\Sigma_ip_i \log (p_i).$$ for entropy, from first principles. I only wish to assume the laws of physics, and without involving concepts in ...
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Entropy Change During Reversible Processes

I'm confused about the Second Law of Thermodynamics. The Second Law of Thermodynamics prohibits a decrease in the entropy of a closed system and states that the entropy is unchanged during a ...
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What causes a eutectic point?

What causes the melting point depression known as a eutectic point? The temperature depression of a eutectic point can be calculated from the enthaplies and entropies of fusion of the two ...
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Expression of heat by the Brownian motion

folks. I was reading a paper from PRE and I'm not sure what's going on about the following equation. So for the system composed of two heat baths governed by Brownian motion, the entropy change of the ...
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Why do reversible processes not increase the entropy of the universe infinitesimally?

The book Commonly Asked Questions in Thermodynamics states: When we refer to the passage of the system through a sequence of internal equilibrium states without the establishment of equilibrium ...
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Is this derivation for black hole entropy being negative correct?

This "derivation" will use relativity-corrected Planck units to show black hole entropy should be negative. Do you see an error in this line of reasoning? From Einstein's "Relativity" appendix 2 ...
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Why is not the entropy of earth increasing? [closed]

The entropy of earth is not increasing significantly in the past billions of years. So what is the reason? It must be because of the sunshine. But I still do not have a concrete picture.
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Entropy / Structure Relations

I want to check on the validity of the following objective definition of order. Is it correct? Is there a more rigorous statement of this concept? The further a system is from its maximum ...
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Does the radius of the Universe correspond to its total entropy?

I heard a claim that due to holographic principle, the surface area of the cosmic horizon corresponds to the universe's total entropy. As such the initial state had zero surface area and later ...
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Can higher level animals have lower entropy than the food they consume?

If there is plant source of energy 100Cal and an animal source of energy 100Cal for a human being, where the animal derived that energy from a similar plant source, can we say for sure that the animal ...
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160 views

Mechanism of Hawking's radiation and entropy of the black hole

During Hawking's radiation, a virtual particle with negative energy and mass (from pair of particle and antiparticle) fall into black hole and its real partner having positive energy escape from ...
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Why does heat added to a system at a lower temperature cause higher entropy increase?

Entropy is defined in my book as $\Delta\ S = \frac{Q}{T}$. To derive the formula it says that entropy should be directly proportional to the heat energy as with more energy the particles would be ...
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Is Information a potential or kinetic kind of energy?

It is said that the law of least action is that nature tries to convert potential energy into kinetic one as fast as possible. Information can't be thought without a physical realisation, see here. ...
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What is the entropy of a mixed state in classical physics?

Consider a classical system which admits certain macroscopic level of description. It is known, that for two pure states $\omega_1$ and $\omega_2$ on this level of description the entropy of the ...
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Does anti-matter increase or decrease in entropy over time?

Antimatter is matter going backwards through time. From a matter-based observer does antimatter: Increase in entropy (and therefore decrease in entropy in its own time) OR Decrease in entropy ...
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Black hole entropy

Bekenstein and Hawking derived the expression for black hole entropy as, $$ S_{BH}={c^3 A\over 4 G \hbar}. $$ We know from the hindsight that entropy has statistical interpretation. It is a measure ...
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Where and how is the entropy of a black hole stored?

Where and how is the entropy of a black hole stored? Is it around the horizon? Most of the entanglement entropy across the event horizon lies within Planck distances of it and are short lived. Is ...
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Definition of entropy in thermodynamics

In most textbooks, the definition of entropy in reversible processes on a system $S$ is given simply as $$d S=\delta Q/T.$$ It seems to me this definition is insufficient since it does not specify ...
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How is information related to energy in physics?

I recently attended a talk by Dr. Ravi Gomatam on 'quantum reality', where the speaker suggested, that conservation of energy is not a fundamental law, and is conditional, but the conservation of ...
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Does entropy increase or decrease as our Universe is expanding?

Scientists say that entropy of our universe is increasing as it is expanding and our universe is cooling down gradually from the time of its birth. If something is getting cooler and cooler, then how ...
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Why it is said that Universe is an isolated system?

I have read in many places "Entropy of an isolated systems never decreases" And as a corollary: "As Universe is an isolated system(I) then its entropy is constantly increasing(II)" I) ...
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Why must heat supplied in the definition of entropy be reversible? Can't it be irreversible after all it is a state function?

The definition of entropy contains the term $Q_\text{rev}$ which means the heat supplied or taken out reversibly. I thought yes it can be after all only the initial & final states are important as ...
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H-theorem and Boltzmann equation applied to Boltzmann distribution

Using the Boltzmann equation: $$ \frac{dH}{dt} = \int_0^{\infty} dr \int_0^{\infty} ds W(r,s)[p_r - p_s][\ln{p_r} - \ln{p_s}],$$ and assuming $p_r = e^{-\beta r}$, the equation looks like $$ ...
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Entropy increase vs Conservation of information (QM)

Unitarity of quantum mechanics prohibits information destruction. On the other hand, the second law of thermodynamics claims entropy to be increasing. If entropy is to be thought of as a measure of ...
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Entropy of loops in the PV plane

The change in entropy of the Carnot and reversible cycles is said to be 0. Several other loops are supposed to have a non-negative change in entropy. This presents 2 problems which I cannot ...
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Can the energy/power required to mix two fluids together be calculated?

Given two fluids; say for example oxygen and nitrogen gases. By simply introducing, again for example 1 liter of each gas into a closed container, the process of diffusion alone will eventually cause ...
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Is amount of entropy subjective?

From all sources I have seen it follows that the proof you can't decrease the amount of entropy in the Universe is given only statistically - the order is just one of the many ways how things can be ...
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Difficulties with understanding total entropy change and unavailabillty

Of course, I know the fact that the entropy of an isolated system never decreases. Neverthless what makes me confused about the entropy(or change of entropy) of an isolated system is the explanation ...
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Entropy change in Heisenberg picture

If we stick with Heisenberg picture where density matrix $\rho$ is constant, how do we account for entropy increase? I've read the answer to State collapse in the Heisenberg picture but I don't see ...
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Probability of spontaneous Boltzmann brain formation

I was reading through Scott Aaronson's notes (pdf), but I can't make sense of his discussion about Boltzmann brains on p61. Specifically the fact that it says: But the problem is worse. Since in ...
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Is entropy absolute (as in absolute temperature)?

Following this question on the Entropy at the Big Bang where I asked: Since Entropy always increases (in general); its expected that the entropy at the beginning of the universe should be the ...
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do relativistic velocities change the apparent entropy content of the moving object?

Imagine a box of hot gas. It has a certain (large) amount of entropy, which we can relate to the amount of information needed to completely specify the position and velocity of every gas particle in ...
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Intuitively, why does removing solutes cost $k_B T$ of free energy per molecule?

I can calculate that if you want to, for example, desalinate water, you will have to pay a free energy cost of $k_B T$ for each ion you remove. In other words, removing an ion from a volume of water ...
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Really how does the entropy of the universe increase?

Universe means the system along with its surroundings. I have always got this statement while studying the second law; be it a thermodynamics book(Sears, Salinger) , physical cihemistry book(Atkins, ...
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Motivation for the use of Tsallis entropy

Every now and again I hear something about Tsallis entropy, $$ S_q(\{p_i\}) = \frac{1}{q-1}\left( 1- \sum_i p_i^q \right), \tag{1} $$ and I decided to finally get around to investigating it. I haven't ...
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Does a venturi injector contradict the 2nd law of thermodynamics?

The picture below shows a venturi injector. When the water flow enters the narrower cross section its velocity increases and its pressure decreases. Subsequently, fluid is sucked (or injected) into ...
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Does Noether's theorem apply to entropy?

Entropy appears to have a translation symmetry - adding some constant value to it doesn't appear to my fairly rudimentary understanding of physics alter the actual physics. Is this correct? Now ...
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How does the heat death looks like from inside the system?

As this answer points out, any human would first freeze rather than experience the heat death. However, assuming hypothetically that we could make some robot live at such low temperature (or even ...
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Find an expression for S(T,x) from tension and specific heat

I'm working on a problem from a Statistical Mechanics lecture series online, and on the homework, I hit a bump in this problem. Here is the problem set, and I'm asking about #1.c. Short version, we ...
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Is there a definition of relative Renyi entropy?

Is there a Renyi entropy analogue of ``$H(X \vert Y)$" ? If yes then is there any known meaning to that? Googling around I found a few different notions, equation 18 here, ...
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Can I measure the volume of a locked room by pumping gas through keyhole and measuring its entropy?

Suppose that I have a locked room and a keyhole in the door and I want to measure the room's volume. Suppose also that I have some "magical" "artificial" inert gas A that doesn't interact with ...
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Does the entropy of the universe change as expansion exceeds the speed of light?

The potential encoded information in a photon that is at the edge of the observable universe would seem to be lost as the universe expands. Does that loss of information contribute to the overall ...
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Entropy and the principle of least action

Is there any link between the law of maximum entropy and the principle of least action. Is it possible to derive one from the other ?
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Can the entropy of a part of a closed system become less than the initial entropy of the entire system?

I am reading Sir Roger Penrose's book "What came before the Big Bang?". Here, I came across a chapter where he talks about how sunlight provides us energy in low entropy and how through various ...
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Relation between Von Neumann entropy (and other entanglement measures) and thermodynamical entropy

Suppose I have a bipartite system (with Hilbert space $H = H_a \times H_b$) and the following state: $$\sigma = \sum_{n} \frac{e^{-\beta E_n}}{Z} \rho_n$$ where $Z = \sum_n e^{- \beta E_n}$ and ...
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Gough-Joule effect in rubber band

When a stretched rubber band is heated, surprisingly, its tension will increase. What is the physics behind this?! Another thing. The Entropic spring model says, for a good specimen, that the ...
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Entropy change in an irreversible process between 2 equilibrium state

Calculating entropy change in an irreversible process between 2 states requires computing the change in entropy for any reversible process between the 2 same states, but why? If someone could provide ...
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Calculation of entropy change in irreversible cycles, meaning of $\delta Q/T$ in irreversible processes

Lets take the two cycles in the pictures working with an ideal gas. We perform one, and than perform the other. The cycle is made reversible by making the gas exchange heat with a heat bath having ...