A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

learn more… | top users | synonyms

0
votes
3answers
3k views

Why can the entropy of an isolated system increase?

From the second law of thermodynamics: The second law of thermodynamics states that the entropy of an isolated system never decreases, because isolated systems always evolve toward ...
2
votes
3answers
93 views

At an instant, does a system of gravitational charges exhibit equivalent behavior to a time-reversed system of like electric charges?

Question: In principle, does a system of gravitational charges exhibit equivalent behavior to a time-reversed system of like electric charges? (At a single instance in time?) Additional Notes: I am ...
3
votes
0answers
147 views

Proving that Measurement increases von Neumann entropy

Let $V$ be a finite dimensional complex inner product space. Let $\mathcal{M}$ be the classical sample space of measurement outcomes that may occur in a given experiment, and $M_\mu$, $\mu \in ...
1
vote
0answers
27 views

Thermodynamics of binary symmetric channels

I am reading this very interesting paper: http://m.iopscience.iop.org/1751-8121/41/40/402002/pdf/1751-8121_41_40_402002.pdf about thermodynamics of channels in information theory. More generally, ...
1
vote
0answers
42 views

About parametrizing quadratic fluctuations in the metric about $AdS_2 \times S^2$

I am referring to the contents of page 20-23 of the paper, http://arxiv.org/abs/1108.3842.pdf Equation 4.5 seems to suggest that one wants to restrict the metric fluctuations $h$ to a subset such ...
2
votes
1answer
127 views

What is intrinsic gravitational entropy?

What is intrinsic gravitational entropy? Does it have to do with dark matter or coarse graining in the universe? Is it unique to general relativity, or there are predictions from quantum mechanics as ...
6
votes
4answers
351 views

How does the formation of a solar system not break the second law of thermodynamics?

Please forgive: I am a layman when it comes to physics and cosmology, and have tried finding an answer to this that I can understand, with no luck. As I understand it, the solar system evolved from a ...
2
votes
1answer
105 views

How to calculate the Wald functional?

I want to calculate the Wald functional for arbitrary higher curvature Lagrangians - like getting equation 6.31 from 6.30 in this paper. A priori the above looks like an extremely complicated ...
22
votes
3answers
979 views

Will the black hole size increase?

I was thinking about the following thought experiment, but wasn't sure about its outcome. Suppose there is a black-hole and I enter it with a partitioned box containing two different gases on either ...
2
votes
1answer
163 views

Entropy is constant. How to express this equation in terms of pressure and density?

In hydrodynamics of an ideal, non-compressive flow we use 5 variables: pressure $p$, density $\rho$ and velocity field $\mathbf{v}$. So we need 5 equations. Landau's "Hydrodynamics" states that the ...
3
votes
2answers
117 views

Entropy / Structure Relations

I want to check on the validity of the following objective definition of order. Is it correct? Is there a more rigorous statement of this concept? The further a system is from its maximum ...
3
votes
0answers
163 views

Explicit form of the entropy production in hydrodynamics

I'm trying to understand how hydrodynamics arise from a precise, mathematical formulation of thermodynamics, learning mostly from Landau's "Hydrodynamics". So Landau starts from formulating the ...
2
votes
2answers
175 views

Is there a relation between (non-) existence of magnetic monopoles and thermodynamics?

This question follows on previous work on connections between (other) areas of physics and thermodynamics as in here, here and even here. P. Dirac (an electrical engineer initially) was one of the ...
1
vote
2answers
395 views

Is quantum uncertainty principle related to thermodynamics?

Would like to ask a question, but first i would like to say Hello Everybody in a way that plays the system, since some geniouses decided that one should not be able to say hello in a question. The ...
0
votes
0answers
95 views

Does causality alone resolve the mathematical ambiguity of expressing physical systems?

Newton's 2nd law of motion is most often written in the differential form $\sum F = {dp \over dt} $ but can also be expressed in an integral form $ p = \int\sum F dt $ Each form of expressing ...
0
votes
1answer
86 views

Meaning of the Reduced Density Operator

I am confused about what it is exactly that a reduced density operator describes. To illustrate, I came across the following seemingly paradoxical argument. Consider a biparte system $AB$, described ...
2
votes
0answers
69 views

Has any possible non-extensive entropy been classified?

How many non-extensive entropies do exist? Tsallis, Havrda-Chavrat, Renyi, Kaniadakis, Sharma-Mittal,... To be more precise, I am wondering if some classification like those of "finite" or Lie groups ...
0
votes
0answers
73 views

entropy in Information theory vs thermodynamic?

We Now From Information Theory That Entropy Of Functions Of A Random Variable $X$ Is Less Than Or Equal To The Entropy Of $X$. Does It Break The Second Law Of Thermodynamic?
10
votes
1answer
510 views

Principle of Caratheodory and The Second Law of Thermodynamics

Background Constantin Carathéodory formulated thermodynamics on a purely mathematical axiomatic foundation. His statement of the second law is known as the Principle of Carathéodory, which may be ...
3
votes
2answers
316 views

Quantum entropy in term of density matrix

Why in von Neumann expression of quantum entropy we have trace of density matrix expression? Why don't off diagonal term play a role?
0
votes
2answers
135 views

The entropy of the universe in an irreversible cycle [closed]

Suppose we have an ideal gas performing an irreversible cycle composed by: an isothermal transformation at $T_{1}$; an isobaric transformation at $P_{A}$; an isothermal transformation at $T_{2}$; an ...
6
votes
2answers
145 views

How can the microstates be measured with zero energy expenditure?

James P. Sethna. Statistical Mechanics. Exercise 5.2: What prevents a Maxwellian demon from using an atom in an unknown state to extract work? The demon must first measure which side of the ...
0
votes
2answers
942 views

Entropy and chemical potential of an ideal gas

I am reading Schroeder's book "Thermal Physics". One calculation in the text was not quite clear to me. The entropy of an ideal gas is given by the Sackur-Tetrode equation: $$ ...
6
votes
2answers
254 views

Classical and Semi-classical treatments of the ideal gas

In the semi-classical treatment of the ideal gas, we write the partition function for the system as $$Z = \frac{Z(1)^N}{N!}$$ where $Z(1)$ is the single particle partition function and $N$ is the ...
5
votes
1answer
101 views

Intuitively, why does removing solutes cost $k_B T$ of free energy per molecule?

I can calculate that if you want to, for example, desalinate water, you will have to pay a free energy cost of $k_B T$ for each ion you remove. In other words, removing an ion from a volume of water ...
1
vote
0answers
67 views

Is entropy a dynamical quantity [closed]

I am confused whether Entropy is a dynamical quantity or not. Gibbs entropy, and quantum mechanical Von Neumann entropy.
32
votes
7answers
3k views

Homemade salad dressing separates into layers after it sits for a while. Why doesn't this violate the 2nd law of thermodynamics?

The oil, vinegar and other liquids in homemade salad dressing separate into layers after sitting for a while, making the mixture become more organized as time evolves. Why doesn't this violate the ...
3
votes
1answer
141 views

Definition of Information in Information Theory

I am not sure in which SE site I have to put this question. But since I have learnt Shannon Entropy in the context of Statistical Physics, I am putting this question here. In the case of Shannon ...
2
votes
2answers
574 views

Entropy $dQ=TdS$ and Work $dW = -pdV$ conditions?

What are the conditions in order for the equations: Entropy $dQ = TdS$ and Work $dW = -p dV$ to work? I think for $dQ = T dS$, it must be a reversible process? But for $dW = -p dV$, shouldn't it ...
4
votes
2answers
236 views

Probability of spontaneous Boltzmann brain formation

I was reading through Scott Aaronson's notes (pdf), but I can't make sense of his discussion about Boltzmann brains on p61. Specifically the fact that it says: But the problem is worse. Since in ...
0
votes
1answer
68 views

Can Entropy decrease through genralized measurement

Can entropy of a quantum state decrease through the generalized measurement?
22
votes
5answers
2k views

Where does deleted information go?

I've heard that, in classical and quantum mechanics, the law of conservation of information holds. I always wonder where my deleted files and folders have gone on my computer. It must be somewhere I ...
0
votes
2answers
252 views

Information or Matter or Energy

Which one is the most fundamental of the universe? What it is made of? Physicists are searching for unique and fundamental form. The question is , information is more fundamental than energy ? ...
6
votes
3answers
250 views

Entropy and the uncertainty principle

According to the second law of thermodynamics, the total entropy of the Universe must always increase after any interaction (as I understand). So in the hydrogen atom, the electron has a high ...
0
votes
0answers
80 views

On the relationship between entropy and chaotic noise

I have few conceptual questions related to application of chaos in communications. Kolmogorov-Sinai Entropy1 , Kolmogorov-Sinai Entropy2 and Kolmogorov-Sinai Entropy3 KS is an entropy metric for ...
0
votes
2answers
70 views

Would it be possible to measure the change of entropy of a system? why?

To be more specific, what I mean is to measure it in a experiment. And if the answer is no, I want to know if it is principally impossible, or just impossible due to the technic limitation of our ...
5
votes
3answers
1k views

Is entropy of all systems zero at absolute zero?

Is the entropy of every system zero at the absolute zero? Or is it taken to be zero at the absolute zero? Are there systems that doesn't reach zero entropy even till absolute zero?
0
votes
1answer
252 views

Entropy and Stability [closed]

What happens when you increase entropy in a system? Does it increase the instability? Is disorder the same as entropy?
1
vote
1answer
146 views

consequences of universe in which second law of thermodynamics does not hold [closed]

What would happen if the second law of thermodynamics was not there for governing in every day processes. Can a universe exist and evolve if the second law of thermodynamics does not exist in first ...
0
votes
1answer
73 views

Thermodynamic entropy vs. quantum mechanical entropy

Is there a fundamental difference in the definition of entropy when considering the classical thermodynamic picture vs. the quantum mechanical picture, or are they both fundamentally equivalent?
8
votes
1answer
170 views

What precisely does the 2nd law of thermo state, considering that entropy depends on how we define macrostate?

Boltzmann's definition of entropy is $\sigma = \log \Omega$, where $\Omega$ is the number of microstates consistent with a given macrostate. If I understand correctly, this means that it only makes ...
0
votes
2answers
108 views

Does all information in the universe come from the observer?

In absence of the observer any system undergoes unitary evolution, that is reversible evolution without entropy change. It is believed that the initial state of the universe had very low entropy, ...
1
vote
1answer
77 views

Free Energy, Avialable Work in a reversible process

I was reading the Wikipedia page on Helmoltz Free Energy, http://en.wikipedia.org/wiki/Helmholtz_free_energy, and run across a point I cannot unravel. The discussion goes as follows, I reproduce it ...
6
votes
3answers
254 views

Why is adiabatic process isentropic?

I have read that adiabatic process is isentropic because there is no heat exchange in an adiabatic process and thus no change in entropy. But my question is - Even in adiabatic process, work can be ...
8
votes
2answers
221 views

Why aren't we surrounded by Black holes?

The Bekenstein bound is a limit to the amount of entropy a thermodynamical system can have. The bound is given by the following expression: \begin{equation} S \leq \frac{2 \pi k R E}{\hbar c} ...
10
votes
5answers
1k views

Can entropy of Universe be constant?

If I understand entropy correctly, then for example two objects orbiting a centre of mass have lower entropy than when said objects eventually crash into each other and form a new one. So let's say ...
2
votes
0answers
80 views

Could CP violation be exploited to violate the second law?

I don't understand well CP-violation, but since it introduces a microscopic irreversible process, couldn't it be somehow exploited to decrease entropy? For instance, if we could somehow use it to bias ...
1
vote
1answer
123 views

Entropy in biological systems

I understand why entropy tends to a maximum; it is the tendency of a system to spend most of its time in the macroscopic state that corresponds to the largest number of phase cell configurations. How ...
2
votes
1answer
161 views

Immediately after the Big Bang, was the universe in a state of extremely low or extremely high entropy?

Phase space theory suggests that the largest course-graining region, $p$, in a phase space, $P$, is the point in the phase space with the highest entropy. As such, it is in thermal equilibrium with ...
2
votes
2answers
102 views

Entropy before and after collapse of the wavefunction/ and interpretation?

Seems like it might be pretty rudimentary but I want to see if my thinking is on the right track as well as what the result means. The question is, is the entropy of the collapse of a wavefunction or ...