A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

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“Violation” of the Second Law

I can't reconcile some facts about entropy and irreversibility. This depresses me, because I feel I can't quite grasp the importance of entropy. I will illustrate my problems with an example given by ...
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48 views

Can you choose the variables of a state function?

I'm confused. I was first introduced to entropy as a state function of internal energy and volume $$S(U,V) \Rightarrow dS = C_v\frac{\mathrm{d}T}{T} - p\frac{\mathrm{d}V}{T} $$ wich is the ...
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232 views

Helmholtz free energy from a relation for entropy

The Legendre transformation defines the helmholtz free energy (at least according to my lectures) as: $F(T,V,N)=E-TS$ It also says to start with $E(S,V,N)$ and $T=\frac{\partial{E}}{\partial{S}}$ ...
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66 views

Has any possible non-extensive entropy been classified?

How many non-extensive entropies do exist? Tsallis, Havrda-Chavrat, Renyi, Kaniadakis, Sharma-Mittal,... To be more precise, I am wondering if some classification like those of "finite" or Lie groups ...
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1answer
104 views

How to calculate the Wald functional?

I want to calculate the Wald functional for arbitrary higher curvature Lagrangians - like getting equation 6.31 from 6.30 in this paper. A priori the above looks like an extremely complicated ...
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What is information?

We're all familiar with basic tenets such as "information cannot be transmitted faster than light" and ideas such as information conservation in scenarios like Hawking radiation (and in general, ...
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63 views

Entropy change at varying temperatures?

Entropy change is defined as the amount of energy dispersed reversibly to or from the system at a specific temperature. Reversivility means that the temperature of the system must remain constant ...
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Difference between heat capacity and entropy?

Heat capacity $C$ of an object is the proportionality constant between the heat $Q$ that the object absorbs or loses & the resulting temperature change $\delta T$ of the object. Entropy change is ...
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1answer
141 views

Definition of entropy in nonequilibrium states

Thermodynamical definition of entropy $$S(p)=-\int p\ln p~dx$$ is defined only on equilibrium system. But why can't we use it for non-equilibrium system? Is there a well-accepted definition for it?
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Regarding the 'Arrow of Time'

I read according to 'Newtonian' Mechanics any set of physical activity of particles can be reversed ( I think) so a set of complicated dynamic systems of particles and matter can reverse their ...
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74 views

Thermodynamics of scattering theory

I have a couple of conceptual questions regarding the thermodynamics of scattering. Any partial answer or argument will be appreciated. For the sake of discussion, consider the scattering of ...
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118 views

Is there a minimum energy content of information, other than 0 Joules?

Lets say I want to send the bit string 010110 to someone. Is there a theoretical lower bound on the energy needed to do this?
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401 views

Axioms behind entropy!

The concept of entropy is very ubiquitous, we learn about its uses starting from Information Theory (Shannon entropy) up to its basic definition in statistical mechanics in terms of number of ...
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1answer
60 views

Does the entropy of a system vary in the equilibrium?

I am not physicist and this question may seem trivial. But I understand that in the equilibrium the magnitudes such as temperature or volumen do not vary. Is the same for entropy? My logical says that ...
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0answers
54 views

Entropy of an oscillator in Einstein's solid

This is a homework problem and I need help with it. A solid's (Einstein's model) oscillators are in the first excited state on average. How much entropy does one oscillator have? What I've tried so ...
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1answer
448 views

Gravity and the Second Law of Thermodynamics [duplicate]

I was wondering about the hypothetical - and apparently improbable - heat death of the Universe when I stumbled upon this seeming contradiction. A certain volume of space with a uniform distribution ...
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2answers
224 views

Who invented the perfume bottle thought experiment?

A common thought experiment used to explain the second law of thermodynamics, the "arrow of time", etc. is perfume escaping from an opened perfume bottle; the perfume is likely to diffuse into the ...
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1answer
824 views

Thermodynamics for Dummies: Entropy and temperature

I do not study physics and I have never had a course in thermodynamics. I have no idea what it is about, but I am currently taking a course where we had something about entropy. Would be great if ...
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3answers
480 views

Is Fourier's law of conduction a consequence of the second principle?

In classical thermodynamics courses, entropy is often motivated by the need to justify that heat flows from high temperatures zones to lower temperatures zones: this is seen as a consequence of ...
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107 views

Does all information in the universe come from the observer?

In absence of the observer any system undergoes unitary evolution, that is reversible evolution without entropy change. It is believed that the initial state of the universe had very low entropy, ...
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186 views

Dimensionless entropy interpretation

Measuring temperature in joules instead in the artificial units of Kelvin would render entropy as a dimensionless quantity. This is quite appealing since entropy has always been quite a misterious ...
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86 views

What is entropy of the universe? [duplicate]

What is entropy of the universe? What is the change in entropy of our universe? Is this change increases or decreases? If the entropy of universe keeps on increasing then what are the consequences? Is ...
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3answers
478 views

Are galaxies, stars, planets, and ultimately life in violation of the second law of thermodynamics? [duplicate]

How can we think about entropy in these situations? To my knowledge all of these structures are born out of gravitational interaction. However, it would seem that the formation of these more organized ...
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BTZ Black Hole Central Charge and Conformal Weight

I have been trying to reproduce a calculation (equation 4.12) in this paper http://arxiv.org/pdf/1107.2678v1.pdf by Carlip reviewing the derivation of the effective central charge of the BTZ Black ...
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136 views

Potential energy & entropy of three particles

Let me first say that I am not a physicist, but I am trying to make a simulation on my computer and I have the following question. Let's consider that we have three free charges that somehow can ...
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2answers
143 views

How can heat turn into light

I am confused about how hot surfaces can radiate light to their surroundings. When I shine a light on a surface the light turns to heat spontaneously, and when I leave that hot surface it radiates ...
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60 views

Is the subadditivity of quantum entropy valid in the infinite-dimensional case?

Does the subadditivity (and strong subadditivity) of quantum entropy hold for infinite dimensional quantum systems as well? Unfortunately the books in my hand give proof for finite dimensional cases ...
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Is the second law of thermodynamics a real law? [duplicate]

Everytime I ask people why the second law of thermodynamics is true, they say because the probability of entropy increasing is very large. This for some reason doesn't seem right for me. Just because ...
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Mathematical proof of the Second Law of Thermodynamics [duplicate]

Is there some book or paper that formalizes statistical mechanics, like some people have done with relativity, and proves the second law of thermodynamics from more foundational axioms?
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262 views

What is the difference between a low vs. high entropy plasma just after and before a singularity occurs?

Although it appears that the universe is not closed (since it is accelerating) I have been reading different websites on how the universe would look like if it was closed and the big crunch did occur. ...
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124 views

What is intrinsic gravitational entropy?

What is intrinsic gravitational entropy? Does it have to do with dark matter or coarse graining in the universe? Is it unique to general relativity, or there are predictions from quantum mechanics as ...
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985 views

Does the entropy of an adiabatically isolated system stays the same after we decrease/increase the pressure?

Even if the system is isolated and there is no heat exchange with surroundings, shouldn't the decrease/increase of pressure result in increase/decrease of entropy? Does this property of an ...
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How do you prove the second law of thermodynamics from statistical mechanics?

How do you prove the second law of thermodynamics from statistical mechanics? To prove entropy will only increase with time? How to prove? Please guide.
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48 views

How to calculate the partial entropy in a fully connected ising system

I'm trying to reproduce a calculation that should lead to the partial entropy in a fully connected ising model for the high-temperature range ($\beta < 2$) in the thermodynamic Limit ($N ...
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1answer
73 views

What is the relation between entropy and mass of black hole?

What is the relation between entropy and mass of black hole? And what is the relation between symmetry of physics operation and entropy?For instance,measuring or doing measure on state of quantum ...
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230 views

Why is Entropy's Definition Useful?

I have somewhat of an understanding for other physical quantities, but as far as entropy goes I only know it to be "disorder". Why is the change in entropy formula an appropriate/useful definition, ...
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67 views

Confusion on entropy in the universe [closed]

I was researching about the heat-death of the universe, and I was wondering if my understanding of it so far is factual to the theory? However, the 3rd Law of Thermodynamics prevents the universe’s ...
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1answer
570 views

Does the heat death of the universe really imply a maximum entropy state *all* of the time? Or most of the time?

Statistically speaking, you're going to still encounter deviations from equilibrium, even though the expected value is equilibrium. But these rare deviations from equilibrium - which are inevitable - ...
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Problem about entropy

Combining the first and second law of thermodynamics we can get the following equation $$TdS=dU-P_{ext}dV$$ First question: Is this equation applicable for irreversible processes such that that ...
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Second law of Thermodynamics: Why is it only “almost” always true that entropy is non-decreasing? [duplicate]

Wikipedia - Second law of thermodynamics: ...the entropy of any closed system not in thermal equilibrium almost always increases. I understand that the second law of thermodynamics is based on ...
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1answer
226 views

Relativity of simultaneity and the second law of thermodynamics? [closed]

Has the connection been noted between these two? I have been studying special relativity and in learning Minkowski diagrams I have noticed that as v approaches c, the relativity of simultaneity is so ...
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277 views

Is entropy in quantum mechanics emergent or fundamental?

Since a quantum mechanical system, even an isolated system containing one particle, can be described by a density matrix, with entropy for the system given by $\langle S\rangle=-k \rho\ln(\rho)$, is ...
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Why do we remember the past but not the future?

The question is sometimes referred to as the "psychological arrow of time" (Hawking, 1985). Here the past is understood as a moment or time when the entropy of the universe was lower, and contrarily ...
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64 views

Can Entropy decrease through genralized measurement

Can entropy of a quantum state decrease through the generalized measurement?
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What is happening as our Universe is expanding? Is entropy increasing or decreasing?

Scientists say that entropy of our universe is increasing as it is expanding and our universe is cooling down gradually from the time of it's birth.If something is getting cooler and cooler then how ...
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Is there a general H-theorem?

In statistical mechanics, Boltzmann showed that for dilute gases the H-function increases. I remember from a lecture that there is no general H-theorem, e.g. for non-dilute gases or in the quantum ...
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Why is Entropy expressed in terms of Enthalpy?

Why does ${\Delta}S_{m(fusion)} = \frac{{\Delta}H_{m(fusion)}}{T}$ ? I always thought ${\Delta}S = \frac{dQ}{T}$ In this case does it mean $dQ = {\Delta}H$ ?? Why is it so?
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Entropy as a state property

The usual "proof" entropy is a state property is like that: "Consider a system which undergoes a reversible process from state 1 to state 2 along path A, and let cycle be completed along path B, ...
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162 views

What does the Higgs boson have to do with the uncertainty principle and quantum oscillations?

I was looking in New Scientist the other day when I saw something to do with the Higgs boson, energy levels, entropy, space/time, quantum oscillations and many other things. It was in a feature to do ...
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Entropy of photons

Do low energy photons have greater entropy than high energy photons, or is the entropy of all photons the same (and the relationship between high and low entropy radiation is just a function of the ...