A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

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Calculating the change in entropy in a melting process

I have a homework question that I'm completely stumped on and need help solving it. I have a $50\, \mathrm{g}$ ice cube at $-15\, \mathrm{C}$ that is in a container of $200\, \mathrm{g}$ of water at ...
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84 views

Second Law from Statistics

Hi all I hope you can help me with the statistical origins of the Second Law. I cannot find anything that mathematically proves that order from disorder is impossible only improbable Leading me to ...
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2answers
73 views

Modeling a list with a tunable degree of disorder/shuffling

Imagine we have a list of ordered numbers $L = (1, 2,\dots, N)$. I want to add an arbitrary amount of "disorder" to that list. For instance: Adding a little bit of disorder would permute a few ...
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69 views

Statistics of many body systems in pure states

My understanding of describing a system in thermal equilibrium is that we introduce an ideal thermal reservoir for convenience and then imagine that the system+reservoir samples all states of constant ...
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48 views

Entropy-A question. [closed]

If I have 100 coins then a macrostate is how many heads/tails I have, a micro state is the facing of each individual coin of the 100, but what then is a "configuration" in this example? It is a basic ...
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254 views

Why does $S = k_B \ln W$ not always apply?

I thought for a long time that the Boltzmann formula for entropy, $S = k_B \ln W$, was a universally true statement, or rather the definition of entropy from the perspective of statistical mechanics. ...
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1answer
788 views

Equation of state of a rubber band

I have the following question that I attached in png format. I have done part (a), but I am having difficulties in part (b) when I proceed according to the book. I have non zero tension at ...
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34 views

Entropy of this system

We have a system with two energy states $E_0$< $E_1=0$. We also know that state $E_0$ can only take at most $m$ particles. Curently, there are $n<m$ particles in $E_0$. Now, I am supposed to ...
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How does dark matter collapse?: Entropy considerations

Inspired by this question. I believe that the usual explanation that preserves the second law of thermodynamics as an astrophysical gas cloud collapses under gravity is that the gas must heat and ...
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1answer
88 views

Why doesn't a Brownian ratchet provide free energy?

A Brownian ratchet is described here at Wikipedia. The "why it fails" section reads: Feynman demonstrated that if the entire device is at the same temperature, the ratchet will not rotate ...
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1answer
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Imaginary time is to inverse temperature what imaginary entropy is to …?

The Wick-Rotation rotates imaginary time into inverse temperature (as can be seen from its "rotating" the Schrödinger equation into the heat equation). Now since entropy is temperature's conjugate, I ...
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Homemade salad dressing separates into layers after it sits for a while. Why doesn't this violate the 2nd law of thermodynamics?

The oil, vinegar and other liquids in homemade salad dressing separate into layers after sitting for a while, making the mixture become more organized as time evolves. Why doesn't this violate the ...
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273 views

Why can we say that $\bar{d}Q=TdS$?

When we introduce entropy we do this by saying that: $$\bar{d}Q=TdS.$$ Now I was wondering why this should be true? I know that by looking at a Carnot cycle, we do get this relation for reversible ...
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Does entropy increases due to gravity? [closed]

Imagine travelling to the surface of a neutron star where the very intense gravity would make you weigh 140 trillion times more than we do on earth. It's enough to significantly raise the entropy of ...
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1answer
84 views

entropy of a long molecule chain with respect to its length

Consider a (very long) one-dimensional chain of $N$ moleculs, which can be in either of the energy states $\alpha$ or $\beta$. The configurations have length $a$ or $b$ respectively. Show ...
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Contradiction on Entropy of the “universe” decreasing

I have hit what seems to be a contradiction concerning entropy. In my class, we measured the entropy change of photosynthesis which is obviously a non-spontaneous process. We used the formula, ...
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170 views

What is the conceptual difference between Gibbs and Boltzmann entropies?

In simple words what is the conceptual difference between Gibbs and Boltzmann entropies? Gibbs entropy: $S=-k_B\sum p_i\ln p_i$ Boltzmann entropy: $S=-k_B\ln \Omega$
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Calculating entropy [duplicate]

Suppose 30 gram of metal Gallium melts at 36 °C. The specific heat of fusion is 80.3 kJ/kg and the melting temperature is 29.9 °C. Explain if the melting of the Gallium in this process is ...
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51 views

How much of elastic energy is stored as entropy?

There are two cases of elastic stretching: springs and rubber. When you streach a spring or a piece of rubber both absorb some energy as Entropy (S) and some as plain energy (U) $$\displaystyle{ ...
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137 views

Explicit form of the entropy production in hydrodynamics

I'm trying to understand how hydrodynamics arise from a precise, mathematical formulation of thermodynamics, learning mostly from Landau's "Hydrodynamics". So Landau starts from formulating the ...
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56 views

Consequences of Entropy/Information Reversal in a System?

Can pairs of different physical systems be symmetrical under a process which would turn one of these physical system's entropic and informational contents into another system's respective ...
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What is the relationship between Energy, Entropy, and Information?

What is the relationship between Energy, Entropy, and Information? I read this - What Is Energy? Where did it come from? - and the top answer says that 'energy' is an abstract number that is a ...
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1answer
186 views

Is this derivation of Black Hole entropy viable?

This question is motivated by this one. Suppose $l$ is the minimum measurable unit of length. What is entropy of a spinless particle contained in this interval? We know that entropy of a two-level ...
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425 views

Difference between irreversible and entropy?

Cedric Villani recently wrote an article on Landau damping, where at least one topic discussed confused me. Besides discussing the issue of how a process can be microscopically reversible and ...
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1answer
354 views

How is the logarithmic correction to the entropy of a non extremal black hole derived?

I`ve just read, that for non extremal black holes, there exists a logarithmic (and other) correction(s) to the well known term proportional to the area of the horizon such that $S = \frac{A}{4G} + K ...
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216 views

Violation of the second law of thermodynamics? [closed]

Here is a machine which seems to violate the second law of thermodynamics: $A$ and $B$ are point black bodies of the same temperature (initially). everything is rotationally symmetric around the ...
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Why is information indestructible?

I really can't understand what Leonard Susskind means when he says that information is indestructible. Is that information that is lost, through the increase of entropy really recoverable? He ...
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222 views

Isentropic and Isothermal Compressibility

Why isentropic compressibility is greater than isothermal compressibility ? While deriving $C_p$ and $C_v$ relation, I got $\frac{Cp}{Cv}$ as $\frac{ke}{Kt}$. Which tells us that $Ke > Kt$. But ...
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64 views

Isentropic process and reversibility [duplicate]

I know that every adiabatic reversible process is an isentropic process. Can a process be isentropic but still not reversible adiabatic? Please provide me some examples.
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1answer
32 views

How does entropy change when heat is transfer into a system reversibly with constant T?

My guess will be deltaS system : increase [because heat is flowing into the system] deltaS surrounding: decrease [because heat is leaving the environment] deltaS universe (sys+surr) : 0 because it ...
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2answers
74 views

For change in entropy dS = dq/T, is T the temperature of system or surrounding or both?

For change in entropy dS = dqrev/T, is T the temperature of system or surrounding or both? I am confused about Thot, Tcold, Tsys and Tsurr. If qrev, are we talking about the reversible cycle such as ...
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2answers
229 views

Is this theory about Universe and information true?

I recently saw this video about information and randomness. At some point, it states that a completely predictable universe would infringe the second law of thermodynamics, because it would imply that ...
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61 views

Does the relation between entropy and temperature depend on the ensemble?

If we change the temperature of a given system, there will be a relation between its entropy and temperature S(T). Is S(T) the same in a canonical ensemble and a grand canonical ensemble? If not, is ...
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217 views

Entropy and the uncertainty principle

According to the second law of thermodynamics, the total entropy of the Universe must always increase after any interaction (as I understand). So in the hydrogen atom, the electron has a high ...
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128 views

“Violation” of the Second Law

I can't reconcile some facts about entropy and irreversibility. This depresses me, because I feel I can't quite grasp the importance of entropy. I will illustrate my problems with an example given by ...
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1answer
42 views

Can you choose the variables of a state function?

I'm confused. I was first introduced to entropy as a state function of internal energy and volume $$S(U,V) \Rightarrow dS = C_v\frac{\mathrm{d}T}{T} - p\frac{\mathrm{d}V}{T} $$ wich is the ...
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1answer
150 views

Helmholtz free energy from a relation for entropy

The Legendre transformation defines the helmholtz free energy (at least according to my lectures) as: $F(T,V,N)=E-TS$ It also says to start with $E(S,V,N)$ and $T=\frac{\partial{E}}{\partial{S}}$ ...
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56 views

Has any possible non-extensive entropy been classified?

How many non-extensive entropies do exist? Tsallis, Havrda-Chavrat, Renyi, Kaniadakis, Sharma-Mittal,... To be more precise, I am wondering if some classification like those of "finite" or Lie groups ...
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1answer
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How to calculate the Wald functional?

I want to calculate the Wald functional for arbitrary higher curvature Lagrangians - like getting equation 6.31 from 6.30 in this paper. A priori the above looks like an extremely complicated ...
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What is information?

We're all familiar with basic tenets such as "information cannot be transmitted faster than light" and ideas such as information conservation in scenarios like Hawking radiation (and in general, ...
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53 views

Entropy change at varying temperatures?

Entropy change is defined as the amount of energy dispersed reversibly to or from the system at a specific temperature. Reversivility means that the temperature of the system must remain constant ...
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4answers
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Difference between heat capacity and entropy?

Heat capacity $C$ of an object is the proportionality constant between the heat $Q$ that the object absorbs or loses & the resulting temperature change $\delta T$ of the object. Entropy change is ...
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1answer
97 views

Definition of entropy in nonequilibrium states

Thermodynamical definition of entropy $$S(p)=-\int p\ln p~dx$$ is defined only on equilibrium system. But why can't we use it for non-equilibrium system? Is there a well-accepted definition for it?
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Regarding the 'Arrow of Time'

I read according to 'Newtonian' Mechanics any set of physical activity of particles can be reversed ( I think) so a set of complicated dynamic systems of particles and matter can reverse their ...
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Thermodynamics of scattering theory

I have a couple of conceptual questions regarding the thermodynamics of scattering. Any partial answer or argument will be appreciated. For the sake of discussion, consider the scattering of ...
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105 views

Is there a minimum energy content of information, other than 0 Joules?

Lets say I want to send the bit string 010110 to someone. Is there a theoretical lower bound on the energy needed to do this?
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356 views

Axioms behind entropy!

The concept of entropy is very ubiquitous, we learn about its uses starting from Information Theory (Shannon entropy) up to its basic definition in statistical mechanics in terms of number of ...
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190 views

Is the second law of Thermodynamics an immense tautology?

Let's imagine for a second a system that is changing constantly from one microstate to another one. It could be a given volume of a gas with its atoms moving and bouncing around, or a deck of cards ...
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1answer
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Does the entropy of a system vary in the equilibrium?

I am not physicist and this question may seem trivial. But I understand that in the equilibrium the magnitudes such as temperature or volumen do not vary. Is the same for entropy? My logical says that ...
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Entropy of an oscillator in Einstein's solid

This is a homework problem and I need help with it. A solid's (Einstein's model) oscillators are in the first excited state on average. How much entropy does one oscillator have? What I've tried so ...