A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

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What is reversible and irreversible process? Can process below even be irreversible?

I heard the definitions, but I have much trouble understanding them. My teacher told me that in an example with two chambers and gas particles (look below) entropy increases, but I cannot understand ...
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Unmixing of gases: What is the relevant temperature for my Entropy?

This answer to a question about unmixing gases states: However, let us now assume we have to hand a source of mechanical work, and a large heat reservoir at temperature $T$. I'll assume that ...
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How can there be entropy change in this system?

How can there be an entropy change in this system? Suppose if I have a system consisting of liquid water, $1\, \mathrm{kg}$ at $290\,\mathrm{K}$, I stir it, and do say, $10\, \mathrm{J}$ of work on ...
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What is the entropy of a pure state?

Well, zero of course. Because $S = -\text{tr}(\rho \ln \rho)$ and $\rho$ for a pure state gives zero entropy. But... all quantum states are really pure states right? A mixed state just describes ...
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Entropy change in a reversible carnot cycle with 2 beakers

Consider 2 beakers each containing 1kg of water. One beaker has initial temperature of 25 degrees celsius and the other at 100 degrees celsius. The beaker are now mixed. Assuming no heat exchanged is ...
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Deriving the partition function in MaxEnt

I'm trying to understand this paper on Maximum Entropy by Jaynes, and am stuck on something which should be rather simple. We're attempting to maximize the entropy $-\sum_i p_i \ln(p_i)$ subject to ...
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Is there a relationship between force and entropy?

Is there any relation between force and entropy? If any, I would like to know what the equation of this relation will be. What is the entropy of strong and weak nuclear force? Can we determine it? If ...
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What is the entropy of strong and weak nuclear forces? [duplicate]

Can we determine the entropy of strong and weak nuclear forces? If so, what will be the formula to determine the strong and weak force entropy? Thank you :)
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Are reversible adiabatic processes always isentropic?

If my understanding is correct, neither reversible nor adiabatic processes are necessarily isentropic. But are reversible adiabatic processes always isentropic?
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Resonance in Benzene violating Second Law of Thermodynamics

In chemistry a few months ago we were taught the resonant structure of benzene, that states the double bonds upon the six carbon atoms flicker back and forth between the two possible states it can be ...
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49 views

What perpetuates change? [duplicate]

People say that our notion of "time" comes from entropy which in turn is just a large scale effect of the laws of physics, but what is it that perpetuates the laws of physics from one state into the ...
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Link between Hawking-Bekenstein Black hole entropy and entanglement entropy

I'm currently doing a project on two sided Ads-Schwarzschild black holes in the context of Ads/CFT. I want to show that the entanglement entropy between the two CFTs corresponds approximately to the ...
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Entropy of radiation emitted into space

In several papers I see something equivalent to the following expression for the entropy of radiation given by an astronomical object such as the Sun (assuming the object can be approximated as a ...
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Entropy Change in an irreversible process

I have just started learning thermodynamics and the concept of entropy confuses me. Suppose I have a gas in a cylindrical container fitted with a piston. I take it through an adiabatic irreversible ...
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26 views

How can a reversible adiabatic expansion not increase entropy?

In the second stage of the Carnot cycle, a gas is thermally insulated and allowed to expand and do work on the piston. I understand the reason people give is that because entropy is $\,dS = \,dQ/T$ ...
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clausious inquality

Take a reservoir which gains a heat Q irreversibly at temp T from a surrounding at temp T0 then the entropy change of reservoir is given by Q/t and that of the surrounding is -Q/T0...How is this ...
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entropy change during irreversible heat loss [duplicate]

When a thermodynamic system gains heat if the heat gain is irreversible then there is a entropy generation along with the entropy transfer..so is there a similar entropy generation associated with ...
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915 views

How does the introduction of living things into a closed system affect the rate of change of entropy?

Does the introduction of living things into a closed system increase or decrease the overall rate of change of entropy of a system?
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578 views

How to measure Entropy?

While $$\delta Q=T\ dS$$ allows for obtaining the entropy change of an isolated system in equilibrium by measuring the heat exchange with the environment, I was wondering whether there are ways to ...
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329 views

What is the resolution to Gibb's paradox?

This question is essentially a duplicate of Gibbs Paradox - why should the change in entropy be zero?. The question concerns the following situation: I have some gas of identical particles and they ...
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Gibbs Paradox - why should the change in entropy be zero?

The Gibbs paradox deals with the fact that for an ideal gas with $N$ molecules in a volume $V$ seperated by a diaphragm into two subvolumes $V_1,V_2$ with $N_1,N_2$ particles in each subvolume, ...
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Why does maximal entropy imply equilibrium?

From a purely thermodynamical point of view, why does that entropy have to be a maximum at equilibrium? Say there is equilibrium, i.e. no net heat flow, why can the entropy not be sitting at a ...
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1answer
63 views

Transfer of heat through a finite temprature difference

Consider the following derivation There are two reservoirs at temp A & B at temp T1 & T2 .They are connected by a metal rod such that T1 > T2. Q amonut of heat is transfered ...
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How does dark matter collapse?: Entropy considerations

Inspired by this question. I believe that the usual explanation that preserves the second law of thermodynamics as an astrophysical gas cloud collapses under gravity is that the gas must heat and ...
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Entropy Change for a Thermally Isolated System

Clausius' Theorem states that $\int\frac{dQ}{T}\leq0$ for a closed cycle, with equality for a reversible cycle. Suppose we wish to take our system around a closed cycle such that the path from A to B ...
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How does gravity increase (or, at least, not-decrease) entropy?

I'm a total physics n00b (i.e. I only know the physics as taught in IT grades, and don't remember much of it), and was talking about entropy (initially, not with the physical implications). My friend ...
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Entropy Change During Reversible Processes

I'm confused about the Second Law of Thermodynamics. The Second Law of Thermodynamics prohibits a decrease in the entropy of a closed system and states that the entropy is unchanged during a ...
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238 views

Do some of the laws of thermodynamics break down in quantum mechanics?

I do not know if this is a stupid question as I am not an expert in thermodynamics and certainly no expert in QM. So, we know that the laws of thermodynamics are laws based on statistics. They ...
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Second Law of Thermodynamics and the Arrow of Time: Why isn't time considered fundamental?

I've come across this explanation that the "arrow of time" is a consequence of the second law of thermodynamics, which says that the entropy of an isolated system is always increasing. The argument is ...
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393 views

Has anyone ever tried to formulate physics based on computer science or information processing?

Some physicists and university researchers say it's possible to test the theory that our entire universe exists inside a computer simulation, like in the 1999 film "The Matrix." In 2003, University ...
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85 views

2nd law of thermodynamics - thought experiment

I have designed this simple thought experiment that seems to contradict 2nd law of thermodynamics. Could you please find a mistake in my reasoning? ...
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123 views

Ideal chain / entropic spring - what is the *microscopic* force?

The ideal chain is the classic example of an entropic force. Usually one derives this force from the fundamental relation describing forces in the canonical ensemble: $$ \tag 1 F = (\partial \langle E ...
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64 views

Does a closed system with fixed entropy imply an isolated system?

Just first to clarify, my university notation is $$\text{change in entropy} = \text{entropy flow} + \text{internal production of entropy}$$ I am confused with the term fixed entropy. Does that mean ...
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Why the non-analyticity of free energy function implies phase transition? And what's its connection with other 'higher level' free energies?

I have seen 'free energy' arising from several contexts in very different forms, and each contains different amount of information. For example free energy is defined as the logarithm of the ...
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Is the second law of Thermodynamics an immense tautology?

Let's imagine for a second a system that is changing constantly from one microstate to another one. It could be a given volume of a gas with its atoms moving and bouncing around, or a deck of cards ...
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Second law of thermodynamics (in terms of entropy)

Is the second law of thermodynamics (in terms of entropy) for closed systems or isolated systems? I thought it must be valid for isolated systems, such as the Universe. But the book Fundamentals of ...
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70 views

Derive the Sackur-Tetrode equation

How do you derive the Sackur-Tetrode equation? I know that you must start off with the multiplicity of a mono-atomic ideal gas: ...
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How does my car's remote keep running?

Two years ago, I got a new car. It comes with a wireless remote that provides keyless ignition and can unlock and lock doors at the press of a button. Just recently, I read somewhere (unfortunately ...
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Does the second law of thermodynamics take into consideration of attractive interactions between particles?

If one searches Google or textbooks on 2nd Law of Thermodnamics, one usually finds a statement that is either equivalent or implies the following. The entropy of the universe always increases. But ...
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Entropy - Gas Inside A Closed System Reaches Maximum Entropy

Filling a box with a certain amount of gas with a specific total energy and allowing the gas to reach a maximum entropy state, what happens next? Would the gas remain in a maximum entropy state ...
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51 views

Entropy: Disorder or energy dispersal?

The first definition of entropy given by Clausius is I believe this $$S=Q/T$$ It is as I understand a common fact to understand entropy and maybe often teach it as a measure of disorder through the ...
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81 views

Arrow of time and entropy?

The arrow of time is usually defined by the direction in which entropy increases. In a closed system, if there's a max entropy that the system can reach, does that mean time stops or at least become ...
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For an isolated system, can the entropy decrease or increase?

In any sizable system, the number of equilibrium states are much, much greater then the number of non-equilibrium states. Since each accessible micro state is equally probably, it is overwhelmingly ...
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Mass, energy, and entropy.

I have a seemingly simple question about the relation between these three that for some reason doesn't make sense to me. If entropy is the disorder of a system, then a low entropy state is one of ...
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285 views

Is this derivation of Black Hole entropy viable?

This question is motivated by this one. Suppose $l$ is the minimum measurable unit of length. What is entropy of a spinless particle contained in this interval? We know that entropy of a two-level ...
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Change in entropy of the Universe for charging/discharging a capacitor

I just need to know what exactly happens when charging/discharging a capacitor. Is there any heat transfer between the capacitor and the surroundings? Is there a heat transfer between other parts of ...
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How does Landauer's Principle apply in quantum (and generally reversible) computing

I understand that a reversible computer does not dissipate heat through the Landauer's principle whilst running - the memory state at all times is a bijective function of the state at any other time. ...
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38 views

Specific heat ratio range [closed]

I know that the specific heat ratio, $\gamma$, exists in the range $1 <\gamma< 2$, and I am required to demonstrate a proof of this. I have come across the following proof (but I don't really ...
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Can Black Holes Maintain Data Entropy When Formed By a Data Storage System?

It's been shown that black holes don't destroy information. There's a little-known scenario in computer science (Specifically AI) where an advanced civilization creates an artificial intelligence that ...
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Entropy $S$ for canonical (NVT) and isobaric (NPT) ensemble

In case of non-isolates system (NVT or NPT ensemble), I learned I can calculate the entropy, $$S=-k_B\sum_jp_j\ln(p_j)$$ where $p_j$=probability at $j$ state. but I saw that the entropy is also ...