A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

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getting frm micro to macro entropy problem

For an ideal gas entropy forvolume change from micro to macro can be rewritten as: $S=k\ln W$ $\Delta S= S_2-S_1=k\ln W_2-k\ln W_1=k \ln\frac{W_2}{W_1} $ since we are constrained from derivation ...
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What is the gas entropy as a functional of a one-particle distribution function?

There are some discrepancies on how to introduce entropy in classical kinetic theory. In what follows $f(r,p,t)$ is the usual one-particle distribution function of a monatomic gas, normalised to the ...
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What is time, with respect to universe? [closed]

I want to know what is actually time, not like the measurable quantity. But with some scientific terms Someone said that "time is entropy". Is that true? also what makes time unique?
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Black Hole Entropy Calculation

I was watching "Leonard Susskind on The World As Hologram" ( youtube ). At one point he describes the way Bekenstein calculates the entropy of a black hole. Paraphrasing: Take a minimally sized black ...
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Why is the change in entropy for a given energy input dependent on the temperature?

In my thermodinamics class, we saw that $$dS=\frac{dQ}{T}$$ and $$\Delta S=\int_{a}^{b}\frac{dQ}{T}$$ My question is: why for the same energy input $dQ$ the entropy increases more in lower ...
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Setting constants equal to 1 conditions

I have the following expression for the entropy of an ideal gas in a microcanonical ensemble, $$S=Nk_B\ln \left[ \frac{Ve}{N}\left(\frac{4\pi m e E}{3Nh_0^2}\right)\right] $$ Ideally I would like to ...
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Why is adiabatic process isentropic?

I have read that adiabatic process is isentropic because there is no heat exchange in an adiabatic process and thus no change in entropy. But my question is - Even in adiabatic process, work can be ...
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58 views

(No need of 2nd law) Adiabatic and isothermal compressibility relation with specific heat

One classical example of thermodynamics is the relation between the Adiabatic and Isothermal Compressibility Relation with the Specific Heats: Compressibilities: ...
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Does a magnetic field decrease or increase entropy?

My question is just the title: Does a magnetic field decrease or increase the entropy of a system? For example if we apply a magnetic filed to a substance, is the entropy decreased or increased?
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Laplace's demon and spontaneous symmetry breaking

One interpretation of Quantum mechanics is the hidden variable theory. This suggests that if we were to have a complete knowledge of the system at one time then the future states of the system are ...
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Entropy - does Heat Death occur in a closed system

Does heat death occur in a closed system? (Assuming you can theoretically have some sort of "closed system".
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How does the second law of thermodynamics follow from low entropy of early universe?

One of the explanations of the second law of thermodynamics is that it goes back to the low entropy in the early universe (How do you prove the second law of thermodynamics from statistical ...
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Entropy increase vs Conservation of information (QM)

Unitarity of quantum mechanics prohibits information destruction. On the other hand, the second law of thermodynamics claims entropy to be increasing. If entropy is to be thought of as a measure of ...
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Where does information go if thermodynamic death?

Often read that until Hawking the black holes were introducing a problem with information. Allegedly information should be unable disappear, while this was happening in classic black holes. What ...
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The Big Crunch and perceived entropy

I'm aware of the Big Crunch theory, that once at capacity, the universe may collapse in on itself. Hawking once theorized that time may go backwards during this crunch. So, that got me thinking: how ...
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Temperature in statistical mechanics and differentiating entropy

In statistical mechanics, the entropy of an isolated system with energy $E$ (with fixed volume $V$ and chemical composition $N$) is defined as $S(E) = k \log \Omega$, where $\Omega$ is the number of ...
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Is it possible to disprove water memory with an entropy argument?

Water memory was a controversial experiment claiming to provide an explanation supporting homeopathy. The results were largely dismissed as being tainted by experimental error. One possible mechanism ...
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64 views

Entropy and the $2^{nd}$ law of thermodynamics

I have just been introduced to the word "entropy" and as it is my understanding that it is a measure of the randomness and chaos of particles in as system. My textbook list the 2nd law of ...
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Problems with units of entropy in statistical thermodynamics

The statistical thermodynamics definition of entropy: $S = kN \ln (W)$ troubles me a lot with the problem of dimenstions. where $S$ is entropy; $k$, the Boltzmann constant; $N$ the number of particles ...
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Is information a form of energy? [closed]

To better describe my question, do the following experiment: Calculate x=12+26+67+71 Now you might have spent some time in getting the answer. You burnt sugar, you used up energy to get the ...
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How does this new theory of a possible infinitely old universe not violate the second law of thermodynamics

I read the following article: http://phys.org/news/2015-02-big-quantum-equation-universe.html And followed it back to this journal reference : http://arxiv.org/abs/1404.3093 It appears to be ...
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What is the interpretatation of individual contributions to the Shannon entropy?

If $X=\{ x_1,x_2,\dots,x_n\}$ are assigned probabilities $p(x_i)$, then the entropy is defined as $\sum_{i=1}^n\ p(x_i)\,\cdot\left(-\log p(x_i)\right).$ One may call $I(x_i)=-\log p(x_i)$ the ...
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Entropy of the whole universe

In "Thermal Physics", Charles Kittel proves that entropy always increases in systems when the degree of freedom are increased (adding particles, adding energy, expanding volume, etc ). I started to ...
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Why does heat added to a system at a lower temperature cause higher entropy increase?

Entropy is defined in my book as $\Delta\ S = \frac{Q}{T}$. To derive the formula it says that entropy should be directly proportional to the heat energy as with more energy the particles would be ...
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Space-Time and Entropic gravity [closed]

Gravity warps space-time, and Gravity can be thought of as Entropy. (Entropic gravity) So, as spacetime expands, how is space-time Entropy (or the inverse of gravity) effected? (If this is a noob ...
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Ternary dimensioned density matrix

I am currently reading this paper: Entropy Inequalities by Araki and Lieb (project Euclid link). And I am not able to understand one step: $${\rm Tr}^{123}\left(\rho^{12}\rho^{23}\right)={\rm ...
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Entropy Inequalities

Hey I am reading this paper Entropy Inequalities by Araki and Lieb. I am trying to prove the following lemma: $$S^1+S^2\leq S^{12}+S^{23}$$ using the following lemmas: ...
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Entropy and chemical potential of an ideal gas

I am reading Schroeder's book "Thermal Physics". One calculation in the text was not quite clear to me. The entropy of an ideal gas is given by the Sackur-Tetrode equation: $$ ...
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Existence of negative temperatures and the definition of entropy

How negative temperatures can be possible has been treated on StackExchange before (several times in fact), but in light of some recent academic discussion, most of these answers seem to be possibly ...
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220 views

No hair theorem and black hole entropy

The no hair theorem says that black holes rapidly converge to a state that is completely described just by their mass, spin and charge. Black hole thermodynamics says that the black hole entropy is ...
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33 views

What can I do with specific entropy and quality on a state (Rankine Cycle)

I've been working some Thermodynamics problems on Power Cycles and I have noticed that if I'm given a specific quality at the exit of the turbine and considering the adiabatic process I will have two ...
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197 views

Doesn't entropy increase backwards in time, too?

In statistical explanations of entropy, we can often read about a (thought) experiment of the following sort. We have a bunch of particles in box, packed densely in one of the corners. We assume some ...
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How does the entropy change during the cooling of a hot coffee in a cold cup?

The second Law of Thermodynamics states that entropy always increases in the universe: things become more disorganised. This means, that if I have a hot coffee in a cold cup, then the heat will ...
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Entanglement entropy vs entropy

I just read that if you have a pure density matrix state on a product space, then a way to define entropy in a subspace is to take the reduced density matrix state and define $S = 1- ...
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Why does this entropy change formula for heating water blow up at $T_{1}=0$?

My textbook says: Next we consider a more complicated problem: heating m grams of water, from $T_{1}$ to $T_{2}$. The entropy change is $$S_{2}-S_{1}=\int mc_{w} ...
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Is there a thermodynamic limit on how efficiently you can solve a Rubik's cube?

Suppose I build a machine which will be given Rubik's cubes that have been scrambled to one of the $\sim 2^{65}$ possible positions of the cube, chosen uniformly at random. Is it possible for the ...
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How does the entropy of an isolated system increase?

The change of entropy is defined $$\Delta S = \int \frac{dQ_\mathrm{rev}}{T}.$$ If a system is isolated the heat transfer between the system and the surroundings is zero ($dQ = 0$), thus $\Delta S = ...
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Is there a relation between (non-) existence of magnetic monopoles and thermodynamics?

This question follows on previous work on connections between (other) areas of physics and thermodynamics as in here, here and even here. P. Dirac (an electrical engineer initially) was one of the ...
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Why the amount of entropy increase to a system is less when heat is added to a higher temperature system than to a lower one?

As I understand it, statistically this means that a fall from a high temperature (say $300\text{ K}$) to a middle temperature ($200\text{ K}$), and an increase from say ($100\text{ K}$) to ($200\text{ ...
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Prove that $-\log{d} \leq H(A|B) \leq \log{d}$ for von Neumann entropy

I'm trying to prove that $-\log{d} \leq H(A|B) \leq \log{d}$ for von Neumann entropy. Now, for this to make sense I should give some definitions. System $A$ lives in Hilbert space ...
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Is the equilibrium state in thermodynamics a consequence of the second law of thermodynamics?

Is the thermal equilibrium state the state of maximum entropy? Is it a consequence of the second law of thermodynamics?
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Behavior of maximum entropy states in a closed system?

As I understand it, entropy is a measure of the number of permutations of microstates of a system possible, without changing the observed 'macrostate variables' / measurements or properties of a ...
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What is entropy really?

On this site, change in entropy is defined as the amount of energy dispersed divided by the absolute temperature. But I want to know: What is the definition of entropy? Here, entropy is defined as ...
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How does the universe store information

I have read that entropy is responsible for the storage of information in the universe; that information increases with entropy increase. and that information is never lost. Is this correct? But ...
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Entropy change at varying volumes

I have two questions both related to each other: 1.What is the effect of change in volume (whether increasing or decreasing), of a system, under isothermal conditions? How does this change in ...
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365 views

Is the flatness of space a measure of entropy?

This is a bit quirky: For a very long time I've found Stephen Hawking's evaporating small black holes a lot more reasonable and intuitive than large black holes. The main reason is that gravity is ...
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Does Noether's theorem apply to entropy?

Entropy appears to have a translation symmetry - adding some constant value to it doesn't appear to my fairly rudimentary understanding of physics alter the actual physics. Is this correct? Now ...
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Definition of Entropy for reversible and irreversible process

$\int \dfrac{\delta Q}{T}$ can't be used to calculate entropy of an irreversible process. If you happen to know heat supplied and temperature at which it is supplied for just an instant. Can you then ...
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Is Boltzmann distribution contradicting with the fundamental assumption of statistical thermodynamics?

In equilibrium statistical physics the fundamental assumption of statistical thermodynamics states that the occupation of any microstate is equally probable (i.e. $p_i=1/\Omega, S=-k_B\sum p_i\,{\rm ...
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Can entropy of Universe be constant?

If I understand entropy correctly, then for example two objects orbiting a centre of mass have lower entropy than when said objects eventually crash into each other and form a new one. So let's say ...