A important extensive property of all systems in thermodynamics, statistical mechanics, and information theory, quantifying their disorder (randomness), i.e., our lack of information about them. It characterizes the degree to which the energy of the system is *not* available to do useful work.

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221 views

Von Neumann Entropy: varying definitions

I have seen different authors define von Neumann entropy in different ways. In particular, some use the natural logarithm and others log to base 2. What is the reasoning for this? Does it make any ...
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2answers
924 views

Difficulties with understanding total entropy change and unavailabillty

Of course, I know the fact that the entropy of an isolated system never decreases. Neverthless what makes me confused about the entropy(or change of entropy) of an isolated system is the explanation ...
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1answer
1k views

Why is the equation for Entropy of an ideal gas that undergoes reversible change in T at constant Pressure like this?

Why is the equation for change in Entropy for a reversible change in $T$ at constant $P$ described as $$\Delta S = n C_p \ln\frac{T_f}{T_i}$$
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1answer
151 views

Is there a relation between supersymmetry and entropy?

Considering that entropy denotes the level of order/disorder in a system, would it be possible for entropy and supersymmetry to exist at the same time? Or, are they entirely unrelated?
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3answers
878 views

Why isn't the Bekenstein-Hawking Entropy considered the quantum gravitational unification?

Based on the Bekenstein-Hawking Equation for Entropy, hasn't the relationship between quantum mechanics and gravity already been established.
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0answers
159 views

How to solve state parameters using these givens for an ideal gas?

In a thermodynamic turbine using air as an ideal gas, given that you have a known inlet temperature value $T_i$, a known exit pressure value $P_e$, a known inlet and exit velocity $V_i$ and $V_e$, a ...
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1answer
131 views

Do gasses always mix because of their Gibbs free energy?

As far as I know there are no two gasses that don't mix (excluding demixing by gravitational effects). For me, as someone working with fluids and surface tensions a lot, this means that the surface ...
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0answers
123 views

Entropy change relation to the number of lost bits

Can we use entropy change value to define the (perhaps fractional) number of bits of information that are lost by and, or, xor gates?
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1answer
230 views

How can dQ/T be interpreted as a system's level of disorder?

Long before statistical mechanics, entropy was introduced as: $dS = \frac{dQ}{T}$ At the time when entropy was introduced in this manner, was it known that entropy represents how "disordered" a ...
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7answers
3k views

Entropy and Crystal Growth

I was reading about growing single crystals and I'm a little confused about this - In most crystal growing processes, a "seed crystal" is used, and the rest of the material crystallizes on the seed ...
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1answer
71 views

What are the units of the Bekenstein bound?

Working with the Wikipedia definition of the Bekenstein bound: $S \leq \frac{2 \pi R k_bE}{\hbar c}$ $2\pi R \ $ is $m^2$ $k_b$ is $\frac{J}{K}$ $E$ is $J$ $\hbar$ is $J*s$ $c$ is $\frac{m}{s}$ ...
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4answers
429 views

Comments on entropy and the direction of time in Landau and Lifshitz's Statistical Mechanics

In Landau and Lifshitz's Stat Mech Volume I is the comment: However, despite this symmetry, quantum mechanics does in fact involve an important non-equivalence of the two directions of time. ...
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574 views

How to compute configurations (entropy) of a system?

If we have a system $X$ consisting of subsystems $X_1$ and $X_2$. We also know that $X_1$ and $X_2$ have eigenstates $H_1 = 1 \times 10^{20}$ and $H_2 = 1 \times 10 ^{22}$. Can we calculate the ...
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1answer
445 views

relation between first law of thermodynamics and statistical mechanics definition of entropy

From the definition of entropy as $S= - Tr (\rho\, ln \rho)$ one obtains that $S = \frac{\langle E \rangle}{T} + \log Z.$ The first law of thermodynamics has $dS = {dE \over T}$. Why is there no ...
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1answer
883 views

Why is (von Neumann) entropy maximized for an ensemble in thermal equilibrium?

Consider a quantum system in thermal equilibrium with a heat bath. In determining the density operator of the system, the usual procedure is to maximize the von Neumann entropy subject to the ...
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2answers
623 views

Entropy exchange of a free fall

I have a problem in which the tell me that you drop a bag of 50 kg of sand from 10 meters high, and you have to caltulate the entropy difference of the sand, asuming that the speific heat of the sand ...
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4answers
12k views

For an isolated system, can the entropy decrease or increase?

In any sizable system, the number of equilibrium states are much, much greater then the number of non-equilibrium states. Since each accessible micro state is equally probably, it is overwhelmingly ...
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2answers
206 views

Order = Energy = Mass?

Here is a following problem I encountered when chatting about physics with my friend: Let us imagine a classical example of ordered state of matter in thermodynamic sense: let's take a cylinder ...
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2answers
9k views

Can ice have a higher entropy than water?

I've leant that entropy is a state of randomness, and that solids have a more structured form, therefore having less entropy. However, I saw a YouTube comment stating the following: a liquid NOT ...
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1answer
385 views

The definition of entropy

As history of thermodynamics say, it was a mystery that what is the required condition for a given energy conversion to take place? Like there are two possible events each conserving energy but only ...
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1answer
227 views

Amount of energy to separate Gases - relationship to concentration

I want to understand the efficiencies of separating mixed gases, and for that I want to understand the thermodynamic limit case. Looking at the wikipedia page for entropy of mixing, I find the ...
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1answer
2k views

Isentropic processes

I'm having trouble understanding why reversible adiabatic processes are isentropic. I understand that in a reversible adiabatic process there is no heat exchange and so $dQ = TdS = 0.$ However, if ...
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1answer
200 views

Relation between Casimir and hydrophobic effects

Background Some years ago I was studying "Fundamentos de biología" (Biology fundamentals) and learned how the lipids create a bilayer due to the water repulsion. Some time later I learned that this ...
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4answers
16k views

Entropy Change During Reversible Processes

I'm confused about the Second Law of Thermodynamics. The Second Law of Thermodynamics prohibits a decrease in the entropy of a closed system and states that the entropy is unchanged during a ...
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0answers
949 views

Entalpy and entropy role in freezing-point depression phenomena

There's this "atomic" explanation of the freezing-point phenomena on Wikipedia that leaves me really intrigued. Consider the problem in which the solvent freezes to a very nearly pure crystal, ...
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2answers
144 views

Where and how is the entropy of a black hole stored?

Where and how is the entropy of a black hole stored? Is it around the horizon? Most of the entanglement entropy across the event horizon lies within Planck distances of it and are short lived. Is ...
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1answer
366 views

free energy and entropy of 2D soap froth

This is a (exploratory) computational project. The soap froth was created by injecting bubbles into a chamber formed by two rectangular plates which are 0.16cm. From the moment the soap froth was ...
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6answers
2k views

Entropy and the principle of least action

Is there any link between the law of maximum entropy and the principle of least action. Is it possible to derive one from the other ?
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1answer
78 views

How does quantum entropy scales with the size of the sample?

Suppose i have a 3D bulk of physical matter with no black holes enclosed in a sphere of radius $R$. What is the scaling law of all quantum entropy in function of $R$? If the scaling is not $R^2$, in ...
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2answers
14k views

Can entropy be equal to zero?

I've searched for it but I only found contradicting answers from "scientists": Dr. David Balson, Ph.D. states: "entropy in a system can never be equal to zero". Sam Bowen does not refutes the ...
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4answers
7k views

Why does the nature always prefer low energy and maximum entropy?

Why does the nature always prefer low energy and maximum entropy? I've just learned electrostatics and I still have no idea why like charges repel each other. ...
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1answer
341 views

Name of experiment

I'm seeking the name of or reference for an experiment I once saw in a college physics class. At the beginning of one class the instructor repeatedly wound a wiper that spread a blot of some type of ...
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1answer
390 views

How much energy Maxwell's demon will earn?

Suppose we have one mole of one-atom ideal gas at temperature $T$. Suppose Maxwell's daemon has separated molecules into two sections, one with speed below mean and another with speed above mean. ...
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4answers
1k views

How does the introduction of living things into a closed system affect the rate of change of entropy?

Does the introduction of living things into a closed system increase or decrease the overall rate of change of entropy of a system?
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3answers
4k views

How would we perceive time going backwards? [closed]

I haven't taken Physics in University. Lately, I've been reading about some of the branches of physics through Wikipedia. I read several times that many of the theoretical models do not explain why ...
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2answers
2k views

Physics-based derivation of the formula for entropy

I am looking for a derivation of the formula $$S~=~-\Sigma_ip_i \log (p_i).$$ for entropy, from first principles. I only wish to assume the laws of physics, and without involving concepts in ...
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2answers
2k views

Can entropy be explained in terms of a cleaning/keeping your room clean?

I'm trying to relate the concept of entropy to keeping my room clean as suggested by my high school teacher ~1993... Comparing the two scenarios: Every day I come home and throw an empty can on the ...
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2answers
327 views

Activation energy and entropy

First assertion If a system is already in a high temperature, adding energy, will increment the entropy in a low amount (compared with a system in a lower temperature). Question (if assertion is ...
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1answer
621 views

Does the Higgs Mechanism contradict Entropic Gravity?

Does the Higgs Mechanism contradict Entropic Gravity? It seems like it probably does. But then again, one is a microscopic theory and the other is macroscopic. Can they live together in harmony? or ...
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2answers
1k views

The definition of entropy in quantum mechanics

I have seen entropy with several different definitions. Like Von Neumann entropy and Rényi entropy, etc. So I am curious why there are so many different definitions in quantum mechanics while only ...
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1answer
339 views

An explanation for the Landauer's principle

Has anyone understood the Landauer's principle? What is the current status? In specific, is there a theoretical derivation of the Landauer's Principle?(not the heuristic one based on Salizard's ...
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1answer
316 views

Do laws of thermodynamics have a place in Theory of Everything? [closed]

I am having a difficulty understanding why second law of thermodynamics is still a valid universally accepted concept. I understand it works on paper for describing isolated heat systems. However, I ...
2
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1answer
187 views

Minimal Maxwell's Demon

I would like to understand where the waste heat is generated in the Maxwell's demon problem. To this end I've come up with the simplest scenario I can think of. If my scenario is workable I am hoping ...
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5answers
2k views

Does high entropy means low symmetry?

According to Bogolubov postulate (various texts name it differently) in Non-equilibrium thermodynamics, the number of needed parameters to describe our system is decreasing with time, and finally at ...
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3answers
1k views

Formal demonstration that minimizing the free energy equals maximizing the entropy

I never had great intuition when it came to thermodynamic concepts and potentials even though reading a textbook and completing the exercises has never been a huge problem. In one of them, I was ...
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3answers
3k views

Why does the law of increasing entropy, a law arising from statistics of many particles, underpin modern physics?

As far as I interpret it, the law of ever increasing entropy states that "a system will always move towards the most disordered state, never in the other direction". Now, I understand why it would ...
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2answers
347 views

Speed of Entropy change

If time in systems moving with different speed goes differently, does speed of entropy change differ in these systems? (is "speed of entropy change" a valid term? can we compare them?)
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4answers
636 views

Does entropy decrease through measurement?

For an electron in its rest frame, we have an entropy $$ S = \log 2, $$ which comes from the 2 possible spin directions along z-axis. If the measurement $S_z$ changes its state to $\left| + ...
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2answers
177 views

Qualitative discussion about entropy and disorder

Many discussions about entropy and disorder use examples of decks of cards, pages of books thrown in the air, two gases being mixed in a container, even the state of a nursery at the end of the day ...
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499 views

Entanglement Entropy

I needed some references which involves, the basic definition and motivation for Entanglement Entropy, and its one or two applications to many-body physics/black holes.