A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

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Entropy: two explanations for the same quantity?

I studied thermodynamics and I saw the following definition for entropy: $$ \Delta S = \int_1^2 \frac{\text{d}Q}{T} $$ that we use to calculate $\Delta S$ for different types of transformations. In ...
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Where is the critical moment where the microcanonical ensemble enters the justification for the equilibium state?

As explained in many books, for the microscopic justification of the second law of thermodynamics (lets formulate it as the total entropy takes maximum among all possible exchanges of two systems), ...
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Kolgomorov entropy issues

I am long been confused by these entropy terms. Would be obliged if an explanation is provided in less technical jargon What are the differences between Shannon's entropy, topological entropy and ...
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Question about entropy and “smart materials” (that remember shape)

We all know that entropy is the measure of chaos in the system, and it's always increasing in the system. Now comes my question - how does entropy work in smart materials? Here is a youtube video ...
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Reference request for low entropy big bang

There is a somewhat widely accepted argument that the second law of thermodynamics exists because the universe began in a low-entropy state. I'm writing a paper that mentions this (and must be ...
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153 views

Can entanglement be used to decrease entropy of two systems?

I know that entanglement can create correlation between systems. Would it be true to say that entanglement create constraints between systems? Can constraints be used to lower the total entropy of ...
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Does radiation change entropy?

Are there entropy changes associated with the transmission of energy from the sun to the earth? Does radiation differ from other modes of heat transfer with respect to the entropy changes? Are the ...
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317 views

Wasn't the Hawking Paradox solved by Einstein?

I just watched a BBC Horizon episode where they talked about the Hawking Paradox. They mentioned a controversy about information being lost but I couldn't get my head around this. Black hole ...
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Do magnets lose their magnetism?

I recently bought some buckyballs, considered to be the world's best selling desk toy. Essentially, they are little, spherical magnets that can form interesting shapes when a bunch of them are used ...
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How did the energy/entropy/volume/pressure/temperature relationship exist at the Big Bang and how did it evolve thereafter?

According to the current Big Bang with inflation cosmological model? I was under the mistaken impression that there was very low volume, very high temperature/pressure, very low entropy and the Big ...
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Confusion regarding entropy, reference papers request

1.a In paragraph at Wikipedia/Entropy it is stated: This is because energy supplied at a high temperature (i.e. with low entropy) tends to be more useful than the same amount of energy ...
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The entropy of a static granular mixture

Regarding static granular mixtures (pile of sand - particles with different sizes), is there an expression that will give me the entropy of such a mixture? I am interested in finding the entropy of ...
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Connection between entropy and energy

An isolated system $A$ has entropy $S_a>0$. Next, the isolation of $A$ is temporarily violated, and it has entropy reduced $$S_b ~=~ S_a - S,\space\space\space S\leq S_a.$$ Is it true to say: the ...
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System moves away from equilibrium $\rightarrow$ it has energy added?

Suppose there is an isolated system $A$ at time $(-\infty, t_1)$, whose entropy is $S=S_{max}$, i.e. it is at thermodynamical equilibrium. Between moments $[t_1, t_2)$ the isolation is violated and ...
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Reference paper to support information — energy relation ($kT \ln2 \rm\frac{J}{bit}$)

In answer to Maxwell's Demon Constant (Information-Energy equivalence) there is stated that one bit of information allows to perform $kT \cdot \ln2$ Joules of work. Which paper supports the ...
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177 views

Is a closed system receiving heat guaranteed to have entropy below maximum?

Isolated system will preserve its entropy unchanged (for fully reversible system) or it will increase its entropy (for system with irreversible processes). For a closed system, it can receive energy ...
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Does measurement, quantum in particular, always increase the total entropy?

Measurement of a quantum observable (in an appropriate, old-fashioned sense) necessarily involves coupling to a system with a macroscopically large number of degrees of freedom. Entanglement with this ...
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Does the second law of thermodynamics tell me how the entropy changes?

In thermodynamics I can e.g. compute the properties of ideal gases with certain energies $U_1,U_2$ in boxes with certain volumes $V_1$ and $V_2$. Say I have two such boxes and they have some specific ...
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Did really everything begin with a state with very low entropy?

As emphasized by Penrose many years ago, cosmology can only make sense if the world started in a state of exceptionally low entropy. The low entropy starting point is the ultimate reason that the ...
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What's the validity of the thermodynamic definition of entropy?

Thermodynamic Entropy Variation is defined as $$\Delta S = \int_i^f \frac{dQ}{T},$$ where $i$ and $f$ are the initial and final states of the process. My question is: does this equation apply to ...
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What is a qualitative explanation for order of values of standard entropies of formation for isomers of hexane?

I have literature values for the standard enthalpy and Gibbs energy changes of formation at 298 K, $\Delta H_\text{f}^o$ and $\Delta G_\text{f}^o$, for product in the ideal gas state. Since $G=H-TS$ ...
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83 views

Is there an abstract notion of heat within a microscopical system?

The microstates of a system are said to be unobservable. I can introduce the entropy as a measure of the number of microstates, which lead to the same macroscopic variables. So in this detailed ...
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Statistical interpretation of Entropy

I'm preparing my statistical physics course, and while writing the lecture notes it says that a system with non distinguishable particles has much less microstates asociated with a particular ...
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Maxwell's Demon Constant (Information-Energy equivalence)

New Scientist article: Summon a 'demon' to turn information into energy The speed of light c converts between space and time and also appears in e=mc^2. Maxwell's Demon can turn information supplied ...
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Are information conservation and energy conservation related?

as evident from the title, are both, conservation of energy and conservation of information two sides of the same coin?? Is there something more to the hypothesis of hawking's radiation other than ...
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Entropy change in a cycle with two isochoric and two adiabatic processes [closed]

Prove that the change of Entropy in a cycle with two isochoric and two adiabatic processes is 0. How can I prove that? Thanks!
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What meaning do changes in the absolute value of Gibbs free energy have in a simple expansion process?

Below is a simple representation of the thermodynamics of a steam turbine. Stream kinetic and potential energy changes are neglected and no other type of non-PV work is done besides shaft work. ...
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How long will my fridge magnet stay attached to my fridge?

I have a 500 gram neodymium magnet. It is stuck to my fridge. With the constant pull of gravity trying to pull it off how long would it stay attached to fridge? For arguments sake lets say my fridge ...
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Joining the definitions of entropy

$\int \frac{Q_{rev}}{T} = \Delta(k_B\ln\Omega)=\Delta S$ Could anyone give some definite proof for this? I was able to prove that the two definitions of change in entropy are equivalent for an ...
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Deriving an Expression for Entropy

How to derive an expression for entropy in form of $S = \ln \Omega$ from the form $\displaystyle{S = - \sum_i \; p_i \ln p_i}$ ? That is the last formula taken as a definition of entropy. Just a ...
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244 views

Maxwell's Demon bug, trapdoor space and time

What about the size of the door (space) and how long has it to be opened (time)? I think Maxwell's demon would have a problem with space, if the door is too wide (more than one particle size), then ...
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How to choose the right units to compute the phase space volume in classical statistical mechanics?

Without the natural unit $\hbar$, why doesn't it seem to be a problem for Statistical Physics to define $$S=k_B\ log(\Omega)\ ?$$ If $\Omega$ is given in one unit system and I switch to other units ...
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Nonextensive statistical mechanics

I know that the Tsallis($S_q$) entropy is called nonextensive information measure in the sense that if $P$ and $Q$ are two probability distributions then $S_q(P\times ...
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How is thermodynamic entropy defined? What is its relationship to information entropy?

I read that thermodynamic entropy is a measure of the number of microenergy states. What is the derivation for $S=k\log N$, where $k$ is Boltzmann constant, $N$ number of microenergy states. How is ...
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Simple question about a gas in a box with a moving wall

David Albert is a philosopher of Science at Columbia. His book "Time and Chance" includes this example (p 36). A gas is confined on one side of a box with a removable wall. "Draw the wall out, ...
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Restrictions on defining microstates (Entropy)

If we have an isolated system $Sb$ with thermodynamic entropy $Eb=X$ (and growing by the 2nd law of thermodynamics), we could define an abstract system $Sa$ (containing the system $Sb$) but define ...
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Explaining Arrow of Time with Entropy

WARNING: Possibly a naive post. Hi guys. I just watched on BBC, [some show] yesterday (sunday) where the host talked about Arrow of Time, where by 2nd law of thermodynamics states that "nature" is ...
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Best example of energy-entropy competition? [closed]

What are the best examples in practical life of an energy-entropy competition which favors entropy over energy? My initial thought is a clogged drain -- too unlikely for the hair/spaghetti to align ...
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How does lifting an object effect its entropy

I have figured out that: When photons leak out from a container, the entropy of the photon collection increases, because each photon has a different escape time. Photons that have leaked out from a ...
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Do all closed systems, only considering kinematic/mechanical principles, exhibit time reversal symmetry?

It makes a lot of sense to me to imagine a cannonball flying through space as not so much experiencing a macroscopic non-conservative drag force, but as pushing a bunch of air molecules and giving ...
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Energy of unmixing

Mixing of two different fluids is associated with an increase of entropy. Conversely, separation of two gases must be associated with a decrease of the entropy of the two fluids. Is there a minimum ...
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Why was the universe in a extraordinarily low-entropy state right after the big bang?

Let me start by saying that I have no scientific background whatsoever. I am very interested in science though and I'm currently enjoying Brian Greene's The Fabric of the Cosmos. I'm at chapter 7 and ...
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How to understand temperatures of different degrees of freedom?

So I'm reading this book, where after the preface and before the models there is a section called General Notions and Essential Quantities, which introduce some things I don't understand. They regard ...
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340 views

Defining Orderly/Chaotic states in terms of entropy?

I'm trying to properly understand the meaning of entropy, and how the universe is moving from an orderly state to a chaotic one. If a glass of wine (for example) only has meaning to a human, what ...
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What is the current science on entropic gravity?

In the past couple of years there has been some buzz about 'entropic gravity', including here on stackexchange in Jan 2011. Many say that there is no way that gravity can be entropic, while others ...
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Second law of thermodynamics and a bunch of magnets

Say I put a bunch of powerful square magnets on a nearly frictionless table in a disordered fashion. The second law of thermodynamics states that the system shall spontaneously get more disordered, ...
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Is this a known entropy formula?

While playing around with a variant of the one-dimensional Ising model with periodic boundary conditions I came up with a formula, let's call it $F$, whose form looks suspiciously like an entropy ...
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Use of escort distribution in nonextensive stat. mech

In some of the articles which I read recently, I happen to see the following statement. In Nonextensive statistical physics, it is inappropriate to use the original distribution $P=(p_i)$ ...
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Can a single classical particle have any entropy?

recently I have had some exchanges with @Marek regarding entropy of a single classical particle. I always believed that to define entropy one must have some distribution. In Quantum theory, a single ...
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