Tagged Questions
3
votes
1answer
160 views
Why is (von Neumann) entropy maximized for an ensemble in thermal equilibrium?
Consider a quantum system in thermal equilibrium with a heat bath. In determining the density operator of the system, the usual procedure is to maximize the von Neumann entropy subject to the ...
11
votes
5answers
680 views
Why does the nature always prefer low energy and maximum entropy?
Why does the nature always prefer low energy and maximum entropy?
I've just learned electrostatics and I still have no idea why like charges repel each other.
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5
votes
3answers
2k views
Why does maximal entropy imply equilibrium?
From a purely thermodynamical point of view, why does that entropy have to be a maximum at equilibrium? Say there is equilibrium, i.e. no net heat flow, why can the entropy not be sitting at a ...