A important property of all systems in thermodynamics and statistical mechanics. Entropy characterizes the degree to which the energy of the system is *not* available to do useful work

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Relation between Von Neumann entropy (and other entanglement measures) and thermodynamical entropy

Suppose I have a bipartite system (with Hilbert space $H = H_a \times H_b$) and the following state: $$\sigma = \sum_{n} \frac{e^{-\beta E_n}}{Z} \rho_n$$ where $Z = \sum_n e^{- \beta E_n}$ and ...
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39 views

Proving $-\frac{\partial P}{\partial V}|_{T,N}\geq0$ [on hold]

I have obtained the following condition from the entropy maximum principle: $$\left.\frac{\partial^2U}{\partial V^2}\right|_{S,N}\left.\frac{\partial^2U}{\partial ...
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25 views

Gough-Joule effect in rubber band

When a stretched rubber band is heated, surprisingly, its tension will increase. What is the physics behind this?! Another thing. The Entropic spring model says, for a good specimen, that the ...
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30 views

Is there a definition of relative Renyi entropy?

Is there a Renyi entropy analogue of ``$H(X \vert Y)$" ? If yes then is there any known meaning to that? Googling around I found a few different notions, equation 18 here, ...
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36 views

What is known about Renyi entropy of a probability density function?

I see most discussions about Renyi entropy to be using either of these two kinds of definitions, for $\alpha > 0, \alpha \neq 1$ $H_{\alpha}(p_i)=\frac{1}{1-\alpha}\log \sum p_i^{\alpha}$ for a ...
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58 views

Calculation of entropy change in irreversible cycles, meaning of $\delta Q/T$ in irreversible processes

Lets take the two cycles in the pictures working with an ideal gas. We perform one, and than perform the other. The cycle is made reversible by making the gas exchange heat with a heat bath having ...
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40 views

What is reversible and irreversible process? Can process below even be irreversible?

I heard the definitions, but I have much trouble understanding them. My teacher told me that in an example with two chambers and gas particles (look below) entropy increases, but I cannot understand ...
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102 views

How can there be entropy change in this system?

How can there be an entropy change in this system? Suppose if I have a system consisting of liquid water, $1\, \mathrm{kg}$ at $290\,\mathrm{K}$, I stir it, and do say, $10\, \mathrm{J}$ of work on ...
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32 views

Entropy change in a reversible carnot cycle with 2 beakers

Consider 2 beakers each containing 1kg of water. One beaker has initial temperature of 25 degrees celsius and the other at 100 degrees celsius. The beaker are now mixed. Assuming no heat exchanged is ...
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23 views

Deriving the partition function in MaxEnt

I'm trying to understand this paper on Maximum Entropy by Jaynes, and am stuck on something which should be rather simple. We're attempting to maximize the entropy $-\sum_i p_i \ln(p_i)$ subject to ...
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19 views

What is the entropy of strong and weak nuclear forces? [duplicate]

Can we determine the entropy of strong and weak nuclear forces? If so, what will be the formula to determine the strong and weak force entropy? Thank you :)
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65 views

Is there a relationship between force and entropy?

Is there any relation between force and entropy? If any, I would like to know what the equation of this relation will be. What is the entropy of strong and weak nuclear force? Can we determine it? If ...
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74 views

Resonance in Benzene violating Second Law of Thermodynamics

In chemistry a few months ago we were taught the resonant structure of benzene, that states the double bonds upon the six carbon atoms flicker back and forth between the two possible states it can be ...
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48 views

What perpetuates change? [duplicate]

People say that our notion of "time" comes from entropy which in turn is just a large scale effect of the laws of physics, but what is it that perpetuates the laws of physics from one state into the ...
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45 views

Unknown formula

Can someone tell me if this formula really exists and is relevant in some area of physics? $$\frac{\underbrace{lim}_{n \rightarrow \infty} |(S\sqrt{M^{2}-3.14})^{6.672}|}{{\int\sin \alpha \times ...
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126 views

Link between Hawking-Bekenstein Black hole entropy and entanglement entropy

I'm currently doing a project on two sided Ads-Schwarzschild black holes in the context of Ads/CFT. I want to show that the entanglement entropy between the two CFTs corresponds approximately to the ...
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1answer
26 views

How can a reversible adiabatic expansion not increase entropy?

In the second stage of the Carnot cycle, a gas is thermally insulated and allowed to expand and do work on the piston. I understand the reason people give is that because entropy is $\,dS = \,dQ/T$ ...
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33 views

entropy change during irreversible heat loss [duplicate]

When a thermodynamic system gains heat if the heat gain is irreversible then there is a entropy generation along with the entropy transfer..so is there a similar entropy generation associated with ...
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60 views

clausious inquality

Take a reservoir which gains a heat Q irreversibly at temp T from a surrounding at temp T0 then the entropy change of reservoir is given by Q/t and that of the surrounding is -Q/T0...How is this ...
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62 views

Transfer of heat through a finite temprature difference

Consider the following derivation There are two reservoirs at temp A & B at temp T1 & T2 .They are connected by a metal rod such that T1 > T2. Q amonut of heat is transfered ...
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31 views

Entropy Change for a Thermally Isolated System

Clausius' Theorem states that $\int\frac{dQ}{T}\leq0$ for a closed cycle, with equality for a reversible cycle. Suppose we wish to take our system around a closed cycle such that the path from A to B ...
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311 views

How does gravity increase (or, at least, not-decrease) entropy?

I'm a total physics n00b (i.e. I only know the physics as taught in IT grades, and don't remember much of it), and was talking about entropy (initially, not with the physical implications). My friend ...
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84 views

2nd law of thermodynamics - thought experiment

I have designed this simple thought experiment that seems to contradict 2nd law of thermodynamics. Could you please find a mistake in my reasoning? ...
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52 views

Does a closed system with fixed entropy imply an isolated system?

Just first to clarify, my university notation is $$\text{change in entropy} = \text{entropy flow} + \text{internal production of entropy}$$ I am confused with the term fixed entropy. Does that mean ...
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66 views

Second law of thermodynamics (in terms of entropy)

Is the second law of thermodynamics (in terms of entropy) for closed systems or isolated systems? I thought it must be valid for isolated systems, such as the Universe. But the book Fundamentals of ...
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59 views

Derive the Sackur-Tetrode equation

How do you derive the Sackur-Tetrode equation? I know that you must start off with the multiplicity of a mono-atomic ideal gas: ...
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39 views

How does my car's remote keep running?

Two years ago, I got a new car. It comes with a wireless remote that provides keyless ignition and can unlock and lock doors at the press of a button. Just recently, I read somewhere (unfortunately ...
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Why the non-analyticity of free energy function implies phase transition? And what's its connection with other 'higher level' free energies?

I have seen 'free energy' arising from several contexts in very different forms, and each contains different amount of information. For example free energy is defined as the logarithm of the ...
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4answers
87 views

Entropy - Gas Inside A Closed System Reaches Maximum Entropy

Filling a box with a certain amount of gas with a specific total energy and allowing the gas to reach a maximum entropy state, what happens next? Would the gas remain in a maximum entropy state ...
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49 views

Entropy: Disorder or energy dispersal?

The first definition of entropy given by Clausius is I believe this $$S=Q/T$$ It is as I understand a common fact to understand entropy and maybe often teach it as a measure of disorder through the ...
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77 views

Arrow of time and entropy?

The arrow of time is usually defined by the direction in which entropy increases. In a closed system, if there's a max entropy that the system can reach, does that mean time stops or at least become ...
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3answers
103 views

Does the second law of thermodynamics take into consideration of attractive interactions between particles?

If one searches Google or textbooks on 2nd Law of Thermodnamics, one usually finds a statement that is either equivalent or implies the following. The entropy of the universe always increases. But ...
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100 views

Change in entropy of the Universe for charging/discharging a capacitor

I just need to know what exactly happens when charging/discharging a capacitor. Is there any heat transfer between the capacitor and the surroundings? Is there a heat transfer between other parts of ...
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Specific heat ratio range [closed]

I know that the specific heat ratio, $\gamma$, exists in the range $1 <\gamma< 2$, and I am required to demonstrate a proof of this. I have come across the following proof (but I don't really ...
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Can Black Holes Maintain Data Entropy When Formed By a Data Storage System?

It's been shown that black holes don't destroy information. There's a little-known scenario in computer science (Specifically AI) where an advanced civilization creates an artificial intelligence that ...
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52 views

Entropy $S$ for canonical (NVT) and isobaric (NPT) ensemble

In case of non-isolates system (NVT or NPT ensemble), I learned I can calculate the entropy, $$S=-k_B\sum_jp_j\ln(p_j)$$ where $p_j$=probability at $j$ state. but I saw that the entropy is also ...
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Entropy change in an irreversible process between 2 equilibrium state

Calculating entropy change in an irreversible process between 2 states requires computing the change in entropy for any reversible process between the 2 same states, but why? If someone could provide ...
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217 views

Do some of the laws of thermodynamics break down in quantum mechanics?

I do not know if this is a stupid question as I am not an expert in thermodynamics and certainly no expert in QM. So, we know that the laws of thermodynamics are laws based on statistics. They ...
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Why did the universe have a low entropy at the big bang?

Sean Carroll, in his book "From Eternity to Here", asks the following question. Why did the universe have a low entropy at the big bang? in John Cramer version of the Wheeler - Feynman absorber ...
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Is it possible to calculate the information content of matter? How?

I know the Bekestein bound is the upper bound for the information content of a region of space, but is it possible to actually calculate that information content (number of bits, not the bits ...
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getting frm micro to macro entropy problem

For an ideal gas entropy forvolume change from micro to macro can be rewritten as: $S=k\ln W$ $\Delta S= S_2-S_1=k\ln W_2-k\ln W_1=k \ln\frac{W_2}{W_1} $ since we are constrained from derivation ...
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What is the gas entropy as a functional of a one-particle distribution function?

There are some discrepancies on how to introduce entropy in classical kinetic theory. In what follows $f(r,p,t)$ is the usual one-particle distribution function of a monatomic gas, normalised to the ...
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112 views

What is time, with respect to universe? [closed]

I want to know what is actually time, not like the measurable quantity. But with some scientific terms Someone said that "time is entropy". Is that true? also what makes time unique?
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Black Hole Entropy Calculation

I was watching "Leonard Susskind on The World As Hologram" ( youtube ). At one point he describes the way Bekenstein calculates the entropy of a black hole. Paraphrasing: Take a minimally sized black ...
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111 views

Why is the change in entropy for a given energy input dependent on the temperature?

In my thermodinamics class, we saw that $$dS=\frac{dQ}{T}$$ and $$\Delta S=\int_{a}^{b}\frac{dQ}{T}$$ My question is: why for the same energy input $dQ$ the entropy increases more in lower ...
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36 views

Setting constants equal to 1 conditions

I have the following expression for the entropy of an ideal gas in a microcanonical ensemble, $$S=Nk_B\ln \left[ \frac{Ve}{N}\left(\frac{4\pi m e E}{3Nh_0^2}\right)\right] $$ Ideally I would like to ...
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258 views

Mass, energy, and entropy.

I have a seemingly simple question about the relation between these three that for some reason doesn't make sense to me. If entropy is the disorder of a system, then a low entropy state is one of ...
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66 views

(No need of 2nd law) Adiabatic and isothermal compressibility relation with specific heat

One classical example of thermodynamics is the relation between the Adiabatic and Isothermal Compressibility Relation with the Specific Heats: Compressibilities: ...
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Does a magnetic field decrease or increase entropy?

My question is just the title: Does a magnetic field decrease or increase the entropy of a system? For example if we apply a magnetic filed to a substance, is the entropy decreased or increased?
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Laplace's demon and spontaneous symmetry breaking

One interpretation of Quantum mechanics is the hidden variable theory. This suggests that if we were to have a complete knowledge of the system at one time then the future states of the system are ...