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AC Stark effect first order change in energy

I am looking at this paper http://ieeexplore.ieee.org/stamp/stamp.jsp?arnumber=89946 where Eq (12) $\triangle E_{ii}(\tau)=-\frac{e\hbar}{m_{i}c}\bf{k}.\bf{A}(\tau)$ (where i=c,v) is mentioned as the ...
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1answer
66 views

Why according to Hund's first rule all electron with same spin should occupy orbitals when partially filling?

I get that because of coulomb repulsion initially all the electrons will not occupy the same site but will single occupy the orbitals.But while doing so how do they know to keep their spins aligned ...
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1answer
27 views

Can a strained diamond actually become conductive?

According to about.com, "The electrical resistivity of most diamonds is on the order of 1011 to 1018 Ω·m" (source) However, according to the diamond band diagram, it seems that under a certain ...
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19 views

What's the elementary reason for the formation of a band gap?

Bohr's solution for an isolated hydrogen atom showed that there are only discrete allowed energy levels, $E_n = -{E_0\over n^2}$ and the solution of the Schreodinger equation provided a certain ...
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0answers
20 views

How are band gap energy, dielectric constant (permittivity) and resistance related to each other?

The following three properties are related to current flow: Band gap energy Dielectric constant Resistance I would expect them all to have the same trend (i.e. higher band gap energy would cause ...
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1answer
41 views

Semiconductors and energy bands

The valence and conduction band of a semi-conductor are often drawn as here click. This plot has essentially two features and I would like to understand them. The peak and the valley of the two ...
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3answers
54 views

What does $m^*>m_e$ imply? (the effective mass of electron is larger than its rest mass)

From what I understand, the concept of effective mass is just something people come up with to make electrons and holes obey the equation of motion $$ \vec{F}=m^* \vec{a} $$ without dealing with the ...
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1answer
54 views

How to calculate the speed of electrons in a metal

According to the Sommerfeld model, the electrons on the Fermi level has the relation $$ \epsilon_F=\frac{\hbar^2k_F^2}{2m_e}=\frac{1}{2}m_ev_F^2 $$ i.e. $\hbar k_F=m_ev_F$ with $k_F=(3\pi^2n)^{1/3}$ ...
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1answer
24 views

Periodic momentum space in band structure

I often see pictures like this in physics, this one for Silicon band structure. (source, NB: it's the German page for Silicon). There you see the plot of the energy in terms of the momentum $k$. ...
3
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1answer
66 views

Hartree-Fock correction to $e$-$e$ interaction

The corrections to the energy per electron in a jellium model (uniform distribution of positive ion charge approximation to the regulated long range order ionic array) is given by (in units of Ry) ...
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1answer
17 views

Why an undoped heterojunction causes potential barrier?

In this image (source) a potential double-barrier was created using GaAs and AlAs lattices (undoped). Why would any potential barrier be formed, if all the bonds are electrostatically balanced (i.e. ...
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34 views

Why the current through a resonant tunnel diode drops when the bound state goes below the conduction band?

The IV curve of a resonant tunneling diode is N-shaped. The rise in current flow happens because the bound state (the energy state in the well) enters the thermal area of the conductor ($\mu_1 + ...
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1answer
16 views

What's the difference between tunnel diode (TD) and resonant tunneling diode (RTD)?

According to wikipedia, a tunnel diode is a PN junction whose energies are shifted with bias, while a resonant tunneling diode is a quantum well between a double barrier, whose energies change with ...
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0answers
23 views

Symmetry breaking and band gaps?

Can the discontinuity in the E-K dispersion relation of a periodic lattice (at the boundary of a Brillouin zone) be understood as a consequence of breaking continuous translation symmetry into ...
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0answers
34 views

How come graphene is considered to have two valleys?

The typical graphene band-structure is a double-cone (in opposite directions to each other) with Dirac point in the middle. I assume the bottom cone is like the valence band, while the top cone is ...
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1answer
46 views

Metals/Insulators and Electron Counting

I'm a little confused by the description I commonly hear about the electron counting rule in band theory. The general statement I find is that a "solid with an odd number of electrons per unit cell ...
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0answers
20 views

Couting the occupied states in band structure

I work with several dft codes and I have produced the band structures of some doped semiconductors with their plots. The problem I have is that I do not know how I can analyze the band structure and ...
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22 views

Quantum Forbidden Regions-Band Theory

In systems where certain regions are classically forbidden for a particle, quantum mechanics permits a finite probability of finding the particle in those regions. However, in band theory of metals, ...
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1answer
142 views

Effect of doping on the width of depletion layer of PN-junction diode

I've read that if there is very low doping in a pn-junction diode, the depletion region will be large because a large volume of depleted semiconductor is needed to generate enough electric field to ...
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1answer
67 views

Electron density in metals at non zero temperature

When computing the electron density in metals, the usual crude result is computed for zero temperature. That is, we integrate \begin{equation} n=\frac{8\sqrt{2}\pi m^{3/2}}{h^{3}} ...
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1answer
24 views

Indirect band gap and additional momentum?

For indirect band gaps, an electron needs both energy and momentum in order to be excited from the conduction band. I am not sure I understand the momentum requirement. What does it mean physically? ...
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1answer
53 views

Effective masses for different direction

Assume we have an indirect semiconductor where the effective mass becomes anisotropic in different directions. Usually, one talks about a mass in parallel and perpendicular direction referring to ...
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0answers
29 views

How to check the ohmic contact to the film?

I have a thin semiconductor film deposited on an isolating substrate. I would like to check different metals to find out do they form the ohmic contact or Schottky barrier. What is the best way to do ...
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20 views

How can we determine the inbuilt barrierpotential and electric feld for a given band diagram?

Suppose I have got two p type silicon materials of different concentrations (the difference in thier concentrations is small but considerable enough that their fermi levels differ by noticeable ...
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4answers
104 views

The conduction electrons in metals is a thermal phenomenon?

When applying an external electric field in a metal at absolute zero, there is electrical current? There must be thermal fluctuations in the electron's band to be occurs current?
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1answer
133 views

Sold-State Band Structure - connection between Fermi Energy, Fermi Level and Work Fuction

I've been struggling with the concepts of these three terms - Fermi Energy, Fermi Level and work fuction. Now, I was given these definitions (in the context of semi-conductors): Fermi Level is the ...
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0answers
26 views

Computing Parity by numerical tables of characters

I have a table of the characters of a set of wavefunctions for different points in reciprocal space and for different band indices (this is for a solid). For the case of a single irreducible ...
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1answer
49 views

Calculating band gap from band structure

If while calculating a band gap, the band just below the Fermi level touches the Fermi level, can we say the material is semiconducting?
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1answer
208 views

Plotting a bandstructure along High-symmetry points when kx,ky,kz is known

Suppose you know kx,ky,kz points along with the corresponding energies. Basically, you know about the 4-D E(k) dispersion. How you do then convert that data into the bandstructure plots you commonly ...
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3answers
479 views

Reverse bias P-N junction [duplicate]

I am not able to understand why the PN junction does not conduct when reverse biased. Can't electrons travel from the N side through the power supply to the P side where they can jump from one hole to ...
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3answers
98 views

How does temperature affect photovoltaics (PV) efficiency?

I know that photovoltaic panels are more efficient at lower temperatures: As the temperature increases, the output voltage decreases. I am looking for an explanation of the mechanism behind this ...
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1answer
421 views

What is an electron/hole pocket and what is the significance?

What is an electron/hole pocket and what is the significance? I'm trying to get my head around this. I've read what Ashcroft and Mermin have to say on the subject, but it's a little convoluted. They ...
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0answers
22 views

What is Fermi energy and Fermi level? [duplicate]

What is meant by Fermi level and Fermi energy? And what is the difference between the two?
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1answer
95 views

Electron degeneracy pressure

Why is it that in stars undergoing gravitational collapse electron degeneracy kicks in? Why couldn't the electrons form energy bands like in semiconductors?
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23 views

How to model a nonperiodic supercell as a periodic one?

Some researchers use Hydrogen atom termination, to model a non periodic finite sized 2D and 1D structures as periodic one. How far this approach is useful in predicting the properties of periodic ...
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1answer
134 views

How to obtain band dispersion from a band structure diagram?

Reading about bands dispersion, I came across the following (Computational Chemsitry of Solid State Materials): ...
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2answers
85 views

List of experimental band gap

does anyone know where one can find a list, database, book of experimental bandgap values of semiconductors? Is there such a collection? Or do I need to scour papers one at a time to get the values?
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1answer
295 views

Band gaps: are they at the centre or at the edge of the Brillouin zone?

Reading about electronic band structures, I came across the following: Band gaps open at the edges of the Brillouin zone (BZ), since that is where the Bragg scattering occurs. I am slightly ...
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Is there a way to quantify how similar a polycrystal should behave to a single crystal?

So in solid state classes we learned about phenomena like band structure and others arising from a periodic potential. Then we get to doing actual experiment and find out that materials being single ...
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1answer
385 views

Fermi level and conductivity

Can someone in a simple way explain me what the Fermi level is and what does it have to do with conductivity. My teacher said that Cu conducts electric current better than Al because of something in ...
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0answers
170 views

Derivation of existence of energy band gap in semiconductor (solid State)

I am looking for both a mathematical and a physical reason for energy band gap in metals. For Physical reason, I was told that at each reciprocal lattice, you could have Bragg scattering, that would ...
2
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1answer
141 views

Effective mass of a particle

I was reading about concept of effective mass on Wikipedia and came across the line that effective mass of a particle can be negative and even zero. How is this possible?
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10 views

Hydrostatically compressed crystal

When a crystal is hydro-statically compressed, the band gap becomes larger, however I am unsure why. Can anyone explain why to me in detail though?
3
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1answer
158 views

In a positively biased PN junction, where do the injection carriers come from?

I am not quite understand i-v character of PN-junction diode. Here is the model in textbook. The PN junction diode can be divided into three regions. They are One depletion region near the PN ...
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0answers
658 views

What is the reason behind band gap narrowing in semiconductors

I want to know why some semiconductors band gap decreases after doping with elements. Burstein-Moss band-filling effect can be useful to explain band gap widing in a semiconductor materials but i was ...
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1answer
80 views

Can excitons be understood in terms of classical quantum physics?

From what I understand, an exciton is an electron-hole pair in a semiconductor that exists in a bound state (through the electrostatic potential). I have seen it stated that this pair behaves in a way ...
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66 views

Nature of electron states in a semiconductor

Usually one is led to think of an electron moving from the valence band to the conduction band as an electron leaving the atom it is bound to in the lattice, and becoming free to move, while leaving ...
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3answers
478 views

How do charge carriers move thermal energy? (Peltier effect)

I am having hard time understanding how the charge carriers (electrons and holes) are able to move thermal energy. I am on a high school physics level, so I will probably have a hard time ...
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1answer
172 views

Semiconductors: why the mass action law is not valid for very low temperatures?

I thought that it was valid for very low temperatures since for it to be valid I think that it is necessary to be in the non-degeneracy condition, which requires $E_G >> k_B T$ (with $E_G$ being ...
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2answers
684 views

How to interpret band structures

I'm currently taking a Solid State Physics class, and is currently reading about the quantum mechanical description of solids. I then came across the following figure: It's supposed to be the band ...