1
vote
0answers
28 views

How does a battery work?

How does the positive terminal of the battery attract electrons? Does the electric field emitted by the positive terminal attract the electrons?
0
votes
0answers
21 views

Why is the Poisson - Boltzmann equation not suitable for high potential?

The Poisson - Boltzmann equation is to find the potential whose charge density obey the Boltzmann distribution. If the potential is not large compare to $k_BT$, the PBE can lead to the Debye–Hückel ...
7
votes
1answer
115 views

Does an electric field create a pH gradient?

Since pH is a measure of the effective concentration of $\mathrm{H}^+$ ions a solution, I expect that an electric field applied to a solution will create a pH gradient. The higher concentration of ...
2
votes
1answer
683 views

Solving Poisson-Boltzmann equation for flat surface without excess salt

I'm trying to understand the solution of Poisson-Boltzmann (PB) equation as I read it in a review. The surface is uniformly charged and flat. I am only considering the $x$ direction. The PB equation ...