1
vote
1answer
57 views

Normalizing continuous eigenstates

As far as I understand, to normalize the eigenfunctions, corresponding to the continuous spectrum, we use Dirac delta function: $\langle \psi_\lambda \mid \psi_{\lambda'} \rangle = \delta(\lambda - ...
0
votes
0answers
39 views

Showing that the maximum possible uncertainty for any observable is half the difference between its maximum and minimum eigenvalues

Show that the maximum possible uncertainty for any observable is $\frac{1}{2}|x_2 - x_1|$ where $x_1$ and $x_2$ are the extreme eigenvalues of X (Maximize $\Sigma_i p_ix_i^2 - (\Sigma_i p_ix_i)^2$) ...
1
vote
3answers
55 views

Help understanding proof in simultaneous diagonalization

The proof is from Principles of Quantum Mechanics by Shankar. The theorem is: If $\Omega$ and $\Lambda$ are two commuting Hermitian operators, there exists (at least) a basis of common eigenvectors ...
0
votes
2answers
71 views

Momentum Operator in Quantum Mechanics

1) What is the difference between these two momentum operators: $\frac{\hbar}{i}\frac{\partial}{\partial x}$ and $-i\hbar\frac{\partial}{\partial x}$? How are these two operators the same? My ...
5
votes
2answers
124 views

Eigenvalue problem for differential equations in QM

I have a very simple question with regard to numerical methods in physics. I want to solve the eigenvalue problem for a particle moving in an arbitrary potential. Let's take 1D to be concrete. I.e. I ...
3
votes
1answer
48 views

Eigenvalues of Infinite Dimensional Matrix [duplicate]

If I take a infinite-dimensional square matrix, what can I say about its eigenvalue spectrum? Will they have a discrete infinity of eigenvalues or continuous infinity of them?
4
votes
1answer
220 views

Imaginary Eigenvalue Of A Hermitian Operator

The eigenfunctions of a Hermitian operator are real. But consider a function $\psi(x)=e^{-\kappa x}$, $x\in\mathbb{R}$, where $\kappa$ is a real constant. Then, $$\hat p \psi(x)=-i\hbar ...
0
votes
1answer
170 views

Proof of the time-independent Schrödinger equation

I have a question regarding the proof of the time-independent Schrödinger equation. So if we have a time-Independent Hamiltonian, we can solve the Schrödinger equation by adopting separation of ...
1
vote
1answer
126 views

Spin eigenvalues and eigenvectors problem. Is this the correct way to solve it?

An electron is described by the Hamiltonian $ H=\frac{e}{mc}\bar{S}\cdot\bar{B} $ where $\bar{S} =(S_x,S_y,S_z)$ is the spin operator and $\bar{B}$ the magnetic field. For $t>0$ ...
1
vote
1answer
77 views

Clarify formula in quantum perturbation theory

I'm studying perturbation theory in the context of quantum mechanics. My lecture notes say that in order to calculate the first-order correction of eigenfunction $\psi_n$, that is $\psi_n^{(1)}$, I ...
11
votes
2answers
222 views

Eigenfunctions of the Runge-Lenz vector

The hamiltonian for the hydrogen atom, $$ H = \frac{\mathbf{p}^2}{2m} - \frac{k}{r} $$ is spherically symmetric and it therefore commutes with the angular momentum $\mathbf{L}$; this causes all its ...
1
vote
2answers
133 views

The eigenspinors for the spin operator in the $x$-direction?

$$S_x= \frac{\hbar}{2}\quad\begin{pmatrix}0&1\\1&0\end{pmatrix}\quad$$ $$S_x{X_+}^{(x)}=\frac{\hbar}{2}{X_+}^{(x)}$$ How can I find the eigenvalue of $S_x$? My book says $$ \left| ...
0
votes
1answer
191 views

Eigenvectors of the angular momentum operator $S_x$ [closed]

For a spin of $\frac{1}{2}$ the angular momentum operator can be written as $\vec{S} = \frac{\hbar}{2} \vec{\sigma}$ in matrix form. Find the eigenvalues and eigenvectors of $S_x$ where $\sigma_x = ...
2
votes
1answer
97 views

Product of position eigenvectors at different times

I've been thinking about this, and it might sound like a stupid question, but I can't seem to find an answer anywhere, here goes: Whenever we calculate expecation-values between two position ...
0
votes
1answer
255 views

Harmonic Oscillator Energy to Momentum Expectation Value

If we are given a wave function written in terms of harmonic oscillator energy eigenfunctions how can we determine the maximum possible momentum expectation value? It's a combination of the first two ...
2
votes
1answer
392 views

Why are orthogonal functions and eigenvalues/functions so important in quantum mechanics?

The mathematics and physics we have studied so far at university are heavily focused around the idea of orthogonal functions, orthogonality, sets of solutions, eigenvalues and eigenfunctions. Why ...
1
vote
1answer
132 views

Matrix operations on Quantum States in a composite quantum system

Intro (you may skip this if you're an expert, I'm including this for completeness): Say I have two bases for two systems, The first is a spin-1/2 system $|+\rangle = \left(\begin{array}{c} 1\\0 ...
14
votes
6answers
1k views

Why are Only Real Things Measurable?

Why can't we measure imaginary numbers? I mean, we can take the projection of a complex wave to be the "viewable" part, so why are imaginary numbers given this immeasurable descriptor? Namely with ...
1
vote
1answer
92 views

Weird Behaviour of the act of measurement to a quantum system

I and my friend were disputing about some weird behaviour of the act of measuring some observables quantities e.g. Energy, position. But I still don't think what he said is strictly true. He said" ...
2
votes
1answer
163 views

Relationship between two eigenfunctions of the time-independent Schrödinger Equation in one dimension?

What is the relationship between two eigenfunctions of the time-independent Schrödinger Equation (in one spatial dimension) if they both have the same eigenvalue?
2
votes
2answers
198 views

Angular momentum of quantum system

Problem: A physical system is in the common eigenstate of $\hat{L^2}$ and $\hat{L_z}$. Calculate the following quantities: $\langle L_x\rangle,\langle L_y\rangle,\langle L_z\rangle,\langle L_x L_y + ...
0
votes
2answers
1k views

Expectation Values in Quantum Mechanics

Why is the expectation value what it is? Why don't you apply the operator, then multiply that by it's conjugate?
1
vote
2answers
132 views

Complex Versus Real Wave Velocities in Quantum Mechanics

There's a fantastic quote in Schrodinger's second 1926 paper1 that apparently provides some motivation for the discrete energy levels (I think) that I'm having trouble interpreting: I would not ...
2
votes
1answer
85 views

Is continuous evolution from one eigenstate of operator $O$ to another $O$-eigenstate possible?

Eigenvectors associated with distinct values of an observable are orthogonal, according to quantum mechanics. Does this entail that a quantum system cannot continuously evolve from one eigenstate ...
1
vote
1answer
236 views

Total angular momentum - single electron

I have been dealing with total angular momentum of the single electron which is outside the closed shells in which sum of the angular momentums is zero. My book says that total atomic angular ...
0
votes
0answers
192 views

Dirac Delta Potential and bound/scattered states

Why does the attractive Dirac Delta distribution (function) potential $V = \alpha\delta$(x) (for negative $\alpha$) yield both bound AND scattered states? Is this due to the definition of the Dirac ...
7
votes
2answers
612 views

Bounded and Unbounded (Scattering) States in Quantum Mechanics

I understand that bounded states in quantum mechanics imply that the total energy of the state, $E$, is less than the potential $V_0$ at + or - spatial infinity. Similarly, the scattering state ...
0
votes
2answers
976 views

Finite potential well problem - calculating the ground state

1. The problem statement, all variables and given/known data Electron of is in a 1-D potential well of depth $20eV$ width $d=0.2 nm$ in his ground state $N=1$. What is the energy of the ground ...
1
vote
2answers
967 views

The Energy Eigenvalue of a Wavefunction

I've been reading an introduction to quantum mechanics online, and while constructing the Schrodinger equation for a free particle, the equation $i\hbar \frac{d \Psi}{dt}=\hbar\omega\Psi$ is obtained. ...
2
votes
0answers
139 views

Adiabatic quantum evolution of single photon or biphoton system

The prerequisite for adiabatic quantum evolution of single photon or biphoton system is as follows. We have to prepare a single photon or biphoton quantum system which has a ground and a higher level ...
-1
votes
1answer
127 views

Wavefunction operators and the observable [closed]

So I got this from the exam I had yesterday. I couldn't really answer it other and it played on my mind through the night Show that if a wave function $\psi$ , is an eigenfunction of an operator [Q], ...
-2
votes
2answers
172 views

Determine whether the ground state is an eigenfunction of [p] and of [p^2] [closed]

Consider a particle confined in an infinite square well potential of width L, $$V(x)=\left\{ \begin{array}{ll}\infty, &{\rm for}\ (x \le 0)\vee (x \ge L) \\0, &{\rm for} \ 0 < x < L ...
3
votes
1answer
358 views

Why are eigenfunctions which correspond to discrete/continuous eigenvalue spectra guaranteed to be normalizable/non-normalizable?

These facts are taken for granted in a QM text I read. The purportedly guaranteed non-normalizability of eigenfunctions which correspond to a continuous eigenvalue spectrum is only partly justified by ...
5
votes
3answers
691 views

Momentum of particle in a box

Take a unit box, the energy eigenfunctions are $\sin(n\pi x)$ (ignoring normalization constant) inside the box and 0 outside. I have read that there is no momentum operator for a particle in a box, ...
0
votes
1answer
76 views

Eigenvalue $a_n$

Q1: In Zetilli's book page 166 (ch. "Postulates of QM", eq. 3.1) i encountered an expression $\hat{A}|\psi\rangle = a_n|\psi_n\rangle$. I know this is an eigenvalue equation, but i have seen another ...
2
votes
2answers
305 views

How do we know that $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$?

I am kind of new to this eigenvalue, eigenfunction and operator things, but I have come across this quote many times: $\psi$ is the eigenfunction of an operator $\hat{H}$ with eigenvalue $W$. ...
1
vote
1answer
172 views

Quantum graph theory: complex spectra

In quantum graph theory, what are the properties of a given graph to own complex conjugated complex eigenvalues, either finite or infinite? Spectral graph theory is as far as I know a not completely ...
1
vote
1answer
92 views

Mysterious spectra?

In my blog post Why riemannium? , I introduced the following idea. The infinite potential well in quantum mechanics, the harmonic oscillator and the Kepler (hygrogen-like) problem have energy spectra, ...
11
votes
3answers
1k views

How to tackle 'dot' product for spin matrices

I read a textbook today on quantum mechanics regarding the Pauli spin matrices for two particles, it gives the Hamiltonian as $$ H = \alpha[\sigma_z^1 + \sigma_z^2] + ...
3
votes
1answer
294 views

How does a state in quantum mechanics evolve?

I have a question about the time evolution of a state in quantum mechanics. The time-dependent Schrodinger equation is given as $$ i\hbar\frac{d}{dt}|\psi(t)\rangle = H|\psi(t)\rangle $$ I am ...
4
votes
5answers
344 views

Math of eigenvalue problem in quantum mechanics

I learned the eigenvalue problem in linear algebra before and I just find that the quantum mechanics happen to associate the Schrodinger equation with the eigenvalue problem. In linear algebra, we ...
1
vote
0answers
142 views

2D quantum well energy spectrum (analytical vs numerical)

I am trying to understand the energy spectrum difference between the analytical and the approximated solution for a quantum well. The particle is inside a box with domain $\Omega=(0,0)$X$(1,1)$. For ...
5
votes
2answers
643 views

Quantum Mechanics Notation for BRA KET

I've been given this homework problem, but I do not understand its notation. Please perform the following where the wavefunctions are the normalized eigenfunctions of the harmonic oscillator ...
4
votes
2answers
452 views

Eigenvalues of a quantum field?

Fields in classical mechanics are observables. For example, I can measure the value of the electric field at some (x,t). In quantum field theory, the classical field is promoted to an operator-valued ...
1
vote
2answers
392 views

Angular Momentum Operators Non-Degenerate

Typically one writes simultaneous eigenstates of the angular momentum operators $J_3$ and $J^2$ as $|j,m\rangle$, where $$J^2|j,m\rangle = \hbar^2 j(j+1)|j,m\rangle$$ $$J_3 |j,m\rangle = \hbar ...
2
votes
2answers
509 views

Non-Degeneracy of Eigenvalues of Number Operator for Simple Harmonic Oscillator [duplicate]

Possible Duplicate: Proof that the One-Dimensional Simple Harmonic Oscillator is Non-Degenerate? I'm trying to convince myself that the eigenvalues $n$ of the number operator ...
2
votes
1answer
175 views

Perturbation method & eigenvalues

I have a problem but I don't understand the question. It says: "Show that, to first order in energy, the eigenvalues ​​are unchanged." What does it mean? It means that if the Hamiltonian has the ...
1
vote
0answers
41 views

Random quantum systems with asymmetric Lifshitz tails?

For a quantum mechanical system with a periodic Hamiltonian (Schrödinger operator) $H$, let $N(E)$ be its integrated density of states, i.e. the fraction of eigenvalues in the spectrum $\sigma(H)$ ...
9
votes
4answers
413 views

Why are the inner products of the eigenfunctions of an operator with a discrete eigenvalue spectrum guaranteed to exist?

I was reading through a textbook, and the statement was made that the inner products are guaranteed to exist if the eigenvalue spectrum of the operator is discrete. I have come across no support for ...
2
votes
1answer
99 views

When does the “norm of quasi-eigenvectors” matter in calculations? For which physical results are these even used?

Which physical system in nonrelativistic quantum mechanics is actually described by a model, where the norm of the "position eigenstate" (i.e. the delta distribution as limit of vectors in the ...